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Method for enhancing thermal shock resistance of low-carbon magnesium-carbon material

A technology of thermal shock resistance and magnesium carbon, which is applied in the field of high-temperature materials, can solve problems such as deterioration of thermal shock resistance, achieve the effect of improving thermal shock resistance and saving raw material costs

Inactive Publication Date: 2020-06-30
营口石兴耐火材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims to solve the defect that the thermal shock resistance of the magnesium-carbon material deteriorates after low carbonization

Method used

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  • Method for enhancing thermal shock resistance of low-carbon magnesium-carbon material

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A method for enhancing the strength of a low-carbon magnesia-carbon material, the specific steps mainly including grinding and mixing, molding and heat treatment. First in the following order (mass fraction): 20% 5~3 mm sintered magnesia → 45% 3~1 mm sintered magnesia → 3% pitch and phenolic resin → 22% silicon carbide ceramic waste → 6% carbon → 4 % Al-Mg alloys are added at various levels and mixed uniformly in the mixer. Then the sample was pressed into a cylindrical sample with a size of 50 × 50 mm, and finally heat-treated at 200 °C for 8 h to obtain an unburned low-carbon magnesia-carbon material.

[0023] Among them, the chemical composition of silicon carbide ceramic waste is SiC (85%), SiO 2 (10%), impurities (5%). The secondary molding pressures were 30 MPa and 300 MPa, respectively.

[0024] The thermal shock resistance index of this embodiment is as follows:

[0025] Heating-water cooling method: 6 times; heating-air cooling method: 32 times; strength re...

Embodiment 2

[0027] A method for enhancing the strength of a low-carbon magnesia-carbon material, the specific steps mainly including grinding and mixing, molding and heat treatment. First follow the following order (mass fraction): 25% 5~3 mm sintered magnesia → 40% 3~1 mm sintered magnesia → 4% pitch and phenolic resin → 20% silicon carbide ceramic waste → 8% carbon → 3 % Al-Mg alloys are added at various levels and mixed uniformly in the mixer. Then the sample was pressed into a cylindrical sample with a size of 50 × 50 mm, and finally heat-treated at 200 °C for 8 h to obtain an unburned low-carbon magnesia-carbon material.

[0028] Among them, the chemical composition of silicon carbide ceramic waste is SiC (87%), SiO 2 (10%), impurities (3%). The secondary molding pressures were 40 MPa and 300 MPa, respectively.

[0029] The thermal shock resistance index of this embodiment is as follows:

[0030] Heating-water cooling method: 6 times; Heating-air cooling method: 30 times; Strengt...

Embodiment 3

[0032] A method for enhancing the strength of a low-carbon magnesia-carbon material, the specific steps mainly including grinding and mixing, molding and heat treatment. First in the following order (mass fraction): 21% 5~3 mm sintered magnesia → 40% 3~1 mm sintered magnesia → 5% pitch and phenolic resin → 25% silicon carbide ceramic waste → 6% carbon → 3 % Al-Mg alloys are added at various levels and mixed uniformly in the mixer. Then the sample was pressed into a cylindrical sample with a size of 50 × 50 mm, and finally heat-treated at 200 °C for 8 h to obtain an unburned low-carbon magnesia-carbon material.

[0033] Among them, the chemical composition of silicon carbide ceramic waste is SiC (90%), SiO 2 (5%), impurities (5%). The secondary molding pressures were 50 MPa and 300 MPa, respectively.

[0034] The thermal shock resistance index of this embodiment is as follows:

[0035] Heating-water cooling method: 8 times; Heating-air cooling method: 36 times; Strength ret...

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Abstract

The invention discloses a method for enhancing thermal shock resistance of a low-carbon magnesium-carbon material. The method is characterized in that silicon carbide ceramic waste is used for replacing magnesia fine powder when the low-carbon magnesium-carbon material is prepared, and the thermal shock resistance of the low-carbon magnesium-carbon material is enhanced through valuable componentsin the waste. The specific preparation process is similar to that of a traditional magnesium-carbon material, and no extra complex process or new cost is needed. Silicon carbide also belongs to a high-melting-point compound, so that the high-temperature performance of the magnesium-carbon material is not influenced while the thermal shock resistance is improved. Meanwhile, because the cost is lowand the method is simple, the method is very suitable for industrial production, and has a certain economic value.

Description

technical field [0001] The invention belongs to the field of high-temperature materials, and in particular relates to a method for enhancing the thermal shock resistance of low-carbon magnesium-carbon materials. Background technique: [0002] Refractory materials are in a high-temperature environment for a long time, and they are in a non-equilibrium state, so they will be impacted by temperature changes inside during actual service. This kind of shock caused by temperature difference is usually called thermal shock or thermal shock, such as thermal stress, thermal expansion and other behaviors. Therefore, in order to describe and quantify the ability of refractory materials to resist thermal shock, the thermal shock resistance of refractory materials is formed. Thermal shock resistance is a very important performance to evaluate the high temperature performance of refractory materials, which represents the ability of refractory materials to resist high temperature damage. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/043C04B35/634C04B35/81
CPCC04B35/043C04B35/63496C04B35/63476C04B2235/3826C04B2235/422C04B2235/40C04B2235/3418
Inventor 马北越任鑫明石明东高陟
Owner 营口石兴耐火材料科技有限公司