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Multi-bed catalytic converter

A catalytic converter and multi-bed technology, applied in chemical instruments and methods, ammonia compounds, inorganic chemistry, etc., can solve expensive and other problems

Active Publication Date: 2020-08-04
CASALE SA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, add-on based retrofits (i.e., installation of new equipment) are usually expensive

Method used

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  • Multi-bed catalytic converter

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Table 1 below relates to a multi-bed catalytic converter of an ammonia plant with an ammonia production of 1850 metric tons per day (MTD) and an inert content of 11% at the inlet of the converter. The converter comprises three serially insulated beds containing iron-based catalyst. The volume of the first bed is 5m 3 , the volume of the second bed is 8m 3 , the volume of the third bed is 31m 3 . Table 1 compares the pressure drop values ​​and conversions for the following converter configurations, taking into account their impact in the synthesis loop:

[0051] 1.1 A prior art converter in which all beds contain relatively coarse catalyst. Each bed contained catalyst particles varying in size from 1.5mm to 3mm.

[0052] 1.2 A converter according to the invention, wherein the first bed and the second bed contain catalysts with particles of 1.5 mm to 3 mm, and the third bed contains fine catalysts with particles of 1 mm to 2 mm, i.e. the third bed does not contain mo...

Embodiment 2

[0061] Table 2 below lists the multi-bed catalytic converter of the ammonia plant, which has an ammonia production of 1935 metric tons per day (MTD), an inert content of 15.5% at the converter inlet, and an inlet pressure of 248.5 bar.

[0062] Table 2 compares the pressure drop values ​​and conversions for the following converter configurations:

[0063] 2.1 A prior art converter comprising three adiabatically insulated beds, all containing relatively coarse catalyst, and each bed containing particles varying from 1.5mm to 3mm.

[0064] 2.2 The converter according to the invention comprises three adiabatic beds, wherein the first and second beds contain coarse catalyst and the third bed contains fine catalyst with particles from 1 mm to 2 mm.

[0065] 2.3 The converter according to the invention comprises a first isothermal bed layer and a second adiabatic bed layer, wherein the first isothermal bed layer contains substantially the same catalyst volume as the first two adiaba...

Embodiment 3

[0073] Table 3 below shows the multi-bed catalytic converter of the ammonia plant with a daily ammonia production of 1935 metric tons (MTD), an inert content of 15.5% at the inlet of the converter, and an inlet pressure of 248.5 bar.

[0074] The converter contained three adiabatic beds in series, and Table 3 compares the pressure drop values ​​and conversions for the following configurations:

[0075] 3.1 Converter with shell-and-tube interbed heat exchanger.

[0076] 3.2 Converter with plate interbed heat exchanger.

[0077]

[0078] table 3

[0079] The table shows that the pressure drop is much lower and the conversion is significantly higher for configuration 3.2 with a plate interbed heat exchanger compared to configuration 3.1 with a shell and tube interbed heat exchanger.

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Abstract

A multi-bed catalytic converter comprising: a plurality of catalytic beds (4, 5, 6) which are traversed in series by a process gas, sequentially from a first catalytic bed (4) to a last catalytic bed(6) of said plurality, and at least one inter-bed heat exchanger (7) positioned between a first catalytic bed (4) and a second catalytic bed (5) of said plurality, wherein at least the last catalyticbed (6) of said plurality is adiabatic and is made of fine catalyst with a particle size not greater than 2 mm.

Description

technical field [0001] The invention relates to the technical field of multi-bed catalytic converters. In particular, the present invention relates to an intercooled multi-bed converter and a retrofit method thereof. Background technique [0002] A multi-bed catalytic converter of the type described herein comprises: a plurality of adiabatic catalytic beds arranged in series with radial or axial-radial flow such that the effluents of the beds are further reacted in subsequent beds, arranged An interbed heat exchanger between successive beds for cooling the effluent from a bed before entering a subsequent bed, and optionally providing a bottom after the last catalytic bed of a plurality of catalytic beds heat exchanger. [0003] This type of converter is widely used, for example, for the synthesis of ammonia from make-up synthesis gas comprising hydrogen and nitrogen. The conversion of make-up gas to ammonia shows the highest performance over iron-based catalysts. Alterna...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J8/04C01C1/04
CPCB01J8/0496B01J8/0415C01C1/0405B01J2208/00168B01J2208/00672B01J2208/025B01J2219/00024B01J2208/00159Y02P20/52B01J8/0492B01J2208/00212B01J2208/00938B01J2208/024C01C1/0411C01C1/0417
Inventor 弗朗西斯科·巴拉托皮耶尔多梅尼科·比亚西达维德·卡拉拉塞尔吉奥·潘扎
Owner CASALE SA