Method for testing electrochemical performance of polar plate anode based on novel material PPTC

A new type of material and testing method technology, applied in the direction of material electrochemical variables, analysis materials, measuring devices, etc., can solve the problems of low accuracy of button batteries, cumbersome production, complicated operation methods, etc., and improve the electrochemical detection rate Effect

Pending Publication Date: 2020-11-17
ZHAOQING LEOCH BATTERY TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The improvement of battery performance largely depends on the performance improvement and development of positive and negative electrodes. In order to meet the development requirements of batteries, the modification and performance upgrade of positive and negative electrode materials are constantly being carried out in the battery material market, which urgently needs a A method that can quickly and accurately test positive and negative electrode materials. However, for the detection methods of positive and negative electrode materials, the most widely used detection methods are button batteries and assembled into complete full batteries. The accuracy of button batteries is not high, and Assembling a complete full battery is not only a long period of time, but also cumbersome to manufacture and complicated operation methods. Another defect is that the current detection method cannot comprehensively and quickly compare the electrochemical performance of the PPTC material plate anode and the traditional plate anode.

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  • Method for testing electrochemical performance of polar plate anode based on novel material PPTC
  • Method for testing electrochemical performance of polar plate anode based on novel material PPTC
  • Method for testing electrochemical performance of polar plate anode based on novel material PPTC

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Embodiment 1

[0053] Such as figure 1 , the characterization method in the step (5) is electrochemical impedance spectroscopy (EIS), wherein the applied potential is the open circuit potential of the plate anode obtained in the step (1), and the measured frequency range is 0.01 Hz~10 4 Hz, AC disturbance voltage amplitude of 5mV.

[0054] According to the second aspect of the present invention, the present invention also proposes the application of the testing method of the electrode plate anode electrochemical performance based on the novel material PPTC of the preceding embodiment, according to an embodiment of the present invention, the application includes:

[0055] The electrochemical performance of the anode plate based on the polymer semiconductor material PPTC and the anode material of the traditional Pb-Ca-Sn alloy plate was analyzed by the method of the previous embodiment.

[0056] Figure 5 , at 25 o Electrochemical AC impedance spectroscopy (Nyquist diagram) of Pb-Ca-Sn allo...

Embodiment 2

[0062] Such as figure 2 , the characterization method in step (5) is anodic polarization curve analysis (LSV), wherein, the setting of step (4) sets the parameters of the electrochemical workstation to be: the initial potential is 1.4V, the termination potential is 2.3V, and the scan rate is 10mV·s -1 , the current / voltage sensitivity is set to 1×10 -2 .

[0063] According to the second aspect of the present invention, the present invention also proposes the application of the testing method of the electrode plate anode electrochemical performance based on the novel material PPTC of the preceding embodiment, according to an embodiment of the present invention, the application includes:

[0064] The electrochemical performance of the anode plate based on the polymer semiconductor material PPTC and the anode material of the traditional Pb-Ca-Sn alloy plate was analyzed by the method of the previous embodiment.

[0065] Such as Figure 8 As shown, the anodic polarization cur...

Embodiment 3

[0070] Such as image 3 As shown, the characterization method in step (5) is the Tafel curve analysis (Tafel) of overpotential analysis, wherein the parameters in step (4) are: the potential interval is the open circuit potential ± 0.05V, and the scan rate is 0.1mV s -1 .

[0071] The characterization method in step (5) is Mott-Schottky curve analysis (mott-schottky) of flat-band potential analysis, wherein the parameters in step (4) are: the potential range is -0.50V~5.0V.

[0072] According to the second aspect of the present invention, the present invention also proposes the application of the test method for the electrochemical performance of the plate anode based on the novel material PPTC of the previous embodiment. According to an embodiment of the present invention, the application includes:

[0073] The electrochemical performance of the anode plate based on the polymer semiconductor material PPTC and the anode material of the traditional Pb-Ca-Sn alloy plate was ana...

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Abstract

The embodiment of the invention discloses a method for testing the electrochemical performance of a polar plate anode based on a novel material PPTC, and the method comprises the following steps: pretreatment: carrying out the ultrasonic cleaning of a PPTC polar plate anode sample through employing absolute ethyl alcohol, and then carrying out the blow-drying at room temperature, thereby obtaininga to-be-tested polar plate anode of a PPTC material; providing an electrochemical workstation, wherein the workstation adopts three electrodes and an electrolyte; connecting the anode of the polar plate to be detected to an electrochemical workstation; setting parameters of an electrochemical workstation; carrying out an electrochemical performance test on an electrode through an electrochemicalperformance characterization method, wherein the characterization method comprises one or more of electrochemical alternating-current impedance spectroscopy (EIS) analysis, anodic polarization curve analysis (LSV), Tafel curve analysis of overpotential analysis or Mott-schakus curve analysis of flat potential analysis; and evaluating the electrochemical performance. The method has the characteristics of simplicity in operation, high detection rate and the like.

Description

technical field [0001] The embodiments of the present invention relate to the technical field of lead-acid batteries, and in particular to a method for testing the electrochemical performance of plate anodes based on the new material PPTC. Background technique [0002] Energy is the basis for human survival and development. Due to the industrial revolution of nearly a hundred years, non-renewable energy sources such as oil and natural gas, which are widely used in large quantities, are facing exhaustion, prompting various forms of adjustments in the energy structure of various countries, and the search for green and renewable new energy sources and energy conversion technologies has become an important issue today. the focus of international attention. Therefore, vigorously developing new energy sources and improving traditional chemical power sources are important issues that urgently need to be overcome in the development of the 21st century. [0003] Lead-acid battery i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N17/00G01N27/26
CPCG01N17/00G01N27/26
Inventor 高士元蔡伟波高芳开
Owner ZHAOQING LEOCH BATTERY TECH
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