Aluminum foil manufacturing method and aluminum electrolytic capacitor negative electrode foil
A manufacturing method and technology of aluminum foil, which is applied in the field of aluminum foil, can solve the problems of low bending strength of negative electrode foil, poor distribution of corrosion hole shape, etc., achieve high specific capacitance, improve bending strength, and suppress poor slitting and fragmentation Effect
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Embodiment 1
[0048] In this embodiment, a high-purity 1090 hard aluminum foil with a thickness of 48 u and a purity of more than 99.9% is used as a raw material, and its tensile strength is 187 MPa, which meets the requirement of greater than 130 MPa. At the same time, for comparison, 1090 soft aluminum foil with a tensile strength of 71MPa was also selected as the raw material.
[0049] The annealing heat treatment is carried out according to the conditions in Table 1.
[0050] In this embodiment, after the annealing treatment, electrochemical etching is used to enlarge the surface area.
[0051] Specifically, after immersing in a 6N / L hydrochloric acid-sulfuric acid solution at 50°C for 2 seconds, the same solution was energized with 2560 coulombs of 50 Hz AC power for electrochemical corrosion.
[0052]In the chemical cleaning treatment, soak in 1.3N / L sulfuric acid solution at 60°C for 16 seconds, soak in 0.4N / L nitric acid solution at 60°C for 16 seconds, and finally soak in 0.2N / L p...
Embodiment 2
[0059] In this embodiment, a 1050 pure aluminum-based foil with a thickness of 41 u is used as a raw material. The corroded foil produced by this kind of aluminum foil is generally used as the negative electrode foil of low-voltage aluminum electrolytic capacitors with high electrostatic capacity per unit area. Specifically, a hard foil with a tensile strength of 268MPa and a soft foil with a tensile strength of 85MPa are selected.
[0060] The annealing heat treatment is carried out according to the conditions in Table 2.
[0061] In this embodiment, chemical etching is used to enlarge the surface area after the annealing treatment.
[0062] Specifically, soak in 8% NaOH solution at 50°C for 5 seconds, and soak in 7N / L hydrochloric acid solution at 105°C for 15 seconds.
[0063] In the chemical cleaning treatment, soak in 1.3N / L sulfuric acid solution at 60°C for 16 seconds, soak in 0.4N / L nitric acid solution at 60°C for 16 seconds, and soak in 0.2N / L phosphoric acid solut...
Embodiment 3
[0070] In this embodiment, a 3003 aluminum alloy foil with a thickness of 21u is used as the raw material. The corroded foil produced by this kind of aluminum foil is generally used as the negative electrode foil of medium and high voltage aluminum electrolytic capacitors that do not require high capacitance per unit area. Specifically, a hard foil with a tensile strength of 285MPa and a soft foil with a tensile strength of 117MPa are selected.
[0071] The annealing heat treatment is carried out according to the conditions in Table 3.
[0072] In this embodiment, chemical etching is used to enlarge the surface area after the annealing treatment.
[0073] Specifically, soak in 8% NaOH solution at 50°C for 5 seconds, and soak in 6.7N / L hydrochloric acid at 100°C for 9 seconds.
[0074] In the chemical cleaning treatment, soak in 1.3N / L sulfuric acid solution at 60°C for 16 seconds, soak in 0.4N / L nitric acid solution at 60°C for 16 seconds, and soak in 0.2N / L phosphoric acid ...
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Abstract
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