High-modulus glass fiber with excellent alkali resistance and preparation method ofhigh-modulus glass fiber

A technology of glass fiber and alkali resistance, which is applied in the field of high modulus glass fiber and its manufacturing, and can solve the problems of insufficient alkali resistance of glass fiber

Active Publication Date: 2020-12-25
滨州信泰节能科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the solution is to reduce or even eliminate the use of ZrO 2 To

Method used

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  • High-modulus glass fiber with excellent alkali resistance and preparation method ofhigh-modulus glass fiber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-7

[0037] Table 1 shows the specific components and corresponding properties of Examples 1-7 listed in the present invention. Wherein, No.1-No.3, No.5-No.6 are preferred embodiments of the present invention, and No.4 and No.7 are comparative examples for comparison. In the performance test, the liquidus temperature, elastic modulus, alkali resistance and water resistance of the glass fiber composition and the glass fiber prepared by it were mainly tested, as well as the set suitable spinning temperature and the corresponding spinning temperature The temperature difference from the liquidus temperature.

[0038] Table 1

[0039]

[0040] It can be seen from Table 1 that in the present invention, YSZ is used to replace zirconia, which can effectively reduce the liquidus temperature of the glass fiber composition, thereby reducing the required suitable spinning temperature. At the same time, the substitution between YSZ and zirconia did not affect the alkali resistance of glass...

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Abstract

The invention provides a high-modulus glass fiber with excellent alkali resistance and a preparation method of the high-modulus glass fiber. The glass fiber comprises the following raw materials of: 55-60% of SiO2, 15-20% of Al2O3, 12-18% of YSZ, 0.5-2% of Y2O3+Nd2O3+CeO2, 5-8% of CaO +MgO, less than or equal to 2% of Li2O+Na2O+K2O, less than or equal to 1% of Fe3O4 and less than or equal to 1% ofTiO2. By replacing traditional zirconium oxide with YSZ and combining a small amount of rare earth oxide and other components, the high-modulus glass fiber with excellent alkali resistance can be prepared at a low spinning temperature.

Description

technical field [0001] The invention relates to the field of glass fiber manufacturing, in particular to a high-modulus glass fiber with excellent alkali resistance and a manufacturing method thereof. Background technique [0002] High-modulus glass fiber is a composite inorganic fiber material with excellent performance, which is widely used in various fields such as aerospace, automobile manufacturing, and electronic equipment. [0003] SiO 2 -Al 2 o 3 -ZrO 2 Fiberglass is the most commonly used high modulus glass fiber. Among such high modulus glass fibers, SiO 2 As the main body of the skeleton structure, with Al 2 o 3 Al in 3+ The tetrahedral and octahedral coordination structures of SiO 2 The skeleton structure is connected, which increases the high-temperature viscosity and chemical stability of the glass. ZrO 2 It is an essential ingredient to improve the alkali resistance of glass fiber and ensure high modulus, hardness, viscosity and other properties. ...

Claims

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Application Information

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IPC IPC(8): C03C13/00C03B37/022
CPCC03B37/022C03C13/002
Inventor 孙庆云
Owner 滨州信泰节能科技有限公司
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