Coal and gas exploitation integrated permeability-increasing enhancer as well as preparation method and application thereof

A technology for strengthening agent and gas, applied in the fields of mining fluids, chemical instruments and methods, and earthwork drilling, etc., can solve the problems of small permeability enhancement range, small coal seam porosity, and poor coal wettability, etc., to reduce the gas-liquid surface Tension, mineral content reduction, calorific-increasing effects

Active Publication Date: 2021-02-09
SHANDONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) Underground coal seam occurrence and mining conditions are complex, with low coal seam permeability, poor wettability, large mining pollution and low efficiency
[0006] (2) Due to the limitations of these inherent properties, there are low coal seam water injection rate, poor coal wetting performance and heavy pollution in the process of mining and use.
[0008] In recent years, the mining depth of my country's coal mines has continued to increase, and the level of mechanized and automated mining has gradually increased. 92% of my country's coal production is underground mining, and the average depth has reached 660m. The coal deposit and mining conditions are complex, and there are problems such as small coal seam porosity, low permeability, and poor water injection efficiency. During the production process of coal mines, coal and gas outbursts, roof accidents, and pneumoconiosis and other natural disasters are constantly escalating, resulting in a large number of losses in manpower and material resources.
At present, all kinds of coal mines in my country have more or less adopted some measures to improve the coal body structure and improve high-efficiency and safe production efficiency, such as hydraulic fracturing, hydraulic slotting, pre-splitting blasting, thermal displacement and other anti-reflection technologies; but from From the perspective of application effect, the effect is not very ideal, such as hydraulic fracturing (there are problems such as small anti-permeability range, fast crack closure, water lock effect, etc.), split water seam blasting (there are problems of consuming a lot of manpower and material resources, and there are dangers) ; Coal seam water injection (low water injection efficiency, poor coal mine application benefits, etc.), heat injection method to coal seam (water or steam heat injection method not only has low efficiency, high energy consumption, but also aggravates the water lock effect), therefore, it is urgent to explore A new type of integrated anti-reflection enhancer and preparation method for coal and gas mining to achieve efficient coal and gas extraction and efficient use of existing resources

Method used

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  • Coal and gas exploitation integrated permeability-increasing enhancer as well as preparation method and application thereof
  • Coal and gas exploitation integrated permeability-increasing enhancer as well as preparation method and application thereof
  • Coal and gas exploitation integrated permeability-increasing enhancer as well as preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0057] Add 150ml of mine water to the empty beaker A, and then measure a certain volume of concentrated HNO 3 (20mol / l) into the beaker, stir with a glass rod, oscillate evenly to obtain the first solution; then take an empty beaker, add 30ml of mine water, code B, and weigh a certain amount of N-lauroyl sarcosine Sodium, pour it into beaker B, set the temperature of the constant temperature stirrer at 25-35°C and stir, so that the sodium N-lauroyl sarcosinate is completely dissolved and the solution is uniform; then weigh a certain amount of 1-butyl -3-Methylimidazolium chloride ([Bmim]Cl) was poured into B, and the temperature of the constant temperature stirrer was set at 50-60°C and stirred to completely dissolve 1-butyl-3-methylimidazolium chloride, The solution is uniform to obtain the second solution; the second solution is poured into the first solution, and stirred continuously with a glass rod to make it react evenly, so that the final HNO 3 The concentration is 6%:...

Embodiment 2

[0059] Add 150ml of mine water to the empty beaker A, and then measure a certain volume of concentrated HNO 3 (20mol / l) into the beaker, stir with a glass rod, oscillate evenly to obtain the first solution; then take an empty beaker, add 30ml of mine water, code B, and weigh a certain amount of N-lauroyl sarcosine Sodium, pour it into beaker B, set the temperature of the constant temperature stirrer at 25-35°C and stir, so that the sodium N-lauroyl sarcosinate is completely dissolved and the solution is uniform; then weigh a certain amount of 1-butyl -3-Methylimidazolium chloride ([Bmim]Cl) was poured into B, and the temperature of the constant temperature stirrer was set at 50-60°C and stirred to completely dissolve 1-butyl-3-methylimidazolium chloride, The solution is uniform to obtain the second solution; the second solution is poured into the first solution, and stirred continuously with a glass rod to make it react evenly, so that the final HNO 3 The concentration is 6%:...

Embodiment 3

[0061] Add 150ml of mine water to the empty beaker A, and then measure a certain volume of concentrated HNO 3 (20mol / l) into the beaker, stir with a glass rod, oscillate evenly to obtain the first solution; then take an empty beaker, add 30ml of mine water, code B, and weigh a certain amount of N-lauroyl sarcosine Sodium, pour it into beaker B, set the temperature of the constant temperature stirrer at 25-35°C and stir, so that the sodium N-lauroyl sarcosinate is completely dissolved and the solution is uniform; then weigh a certain amount of 1-butyl -3-Methylimidazolium chloride ([Bmim]Cl) was poured into B, and the temperature of the constant temperature stirrer was set at 50-60°C and stirred to completely dissolve 1-butyl-3-methylimidazolium chloride, The solution is uniform to obtain the second solution; the second solution is poured into the first solution, and stirred continuously with a glass rod to make it react evenly, so that the final HNO 3 The concentration is 6%:...

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Abstract

The invention belongs to the technical field of efficient and safe production of mines, and discloses a coal and gas exploitation integrated permeability-increasing enhancer as well as a preparation method and application thereof. The coal and gas exploitation integrated permeability-increasing enhancer is composed of, by mass, 6%-10% of 20mol/l concentrated nitric acid, 1%-5% of N-lauroyl creatine sodium, 2%-6% of 1-butyl-3-methylimidazolium chloride and mine dustproof water. The coal and gas exploitation integrated enhancer provided by the invention can improve the wettability of a coal bodyby physicochemical modification of the coal body, inhibit and reduce the generation of dust in a coal seam exploitation process, greatly improve the permeability of the coal body, improve the coal seam occurrence and exploitation conditions, facilitate efficient development and utilization of coal seam gas, improve coal bed gas exploitation, relieve energy shortage, prevent gas disasters of underground coal mines, reduce greenhouse gas emission, facilitate efficient co-exploitation of coal and coal bed gas, and improve the safe and efficient production level of coal mines in China.

Description

technical field [0001] The invention belongs to the technical field of high-efficiency and safe production in mines, and in particular relates to an integrated anti-reflection enhancer for coal and gas mining, a preparation method and an application. Background technique [0002] At present, coal is a strategic resource in my country, accounting for 65% and 60.3% of China's primary energy production and consumption structure respectively. 92% of coal production in my country is mined underground, and the average depth has reached 660m. Underground coal seam occurrence and mining conditions are complex, and there are problems such as low coal seam permeability, poor wettability, large mining pollution, and low efficiency. Due to the limitations of these inherent properties, there are problems such as low coal seam water injection rate, poor coal wetting performance and large pollution in the process of mining and use. Coal seam water injection technology plays an important r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/60C09K8/74E21B43/26
CPCC09K8/602C09K8/74E21B43/26E21B43/006Y02P90/70
Inventor 周刚李帅龙王凯丽杨阳王勇梅段晋杰贺敏姜文静王存民
Owner SHANDONG UNIV OF SCI & TECH
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