Steel slag auxiliary cementing material and preparation method and application thereof

A cementitious material and an auxiliary technology are applied in the field of steel slag auxiliary cementitious material and its preparation, and can solve the problems of poor abrasiveness, low hydration activity, and poor stability of steel slag.

Active Publication Date: 2021-07-06
NANJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Technical problem to be solved: Poor wearability of steel slag, low hydration activity, and potential poor stability caused by free CaO and MgO are the fundamental problems restricting steel slag from being used as auxiliary cementitious materials. The invention provides a steel slag auxiliary cement Concrete material and its preparation method and application, using a certain concentration of carbon dioxide to quickly eliminate free CaO and MgO under the catalysis of a specific admixture, and carbonize with calcium and magnesium mineral phases in steel slag to form active mineral phases, thereby improving The stability of steel slag improves the gelling performance of steel slag, and the prepared steel slag auxiliary cementitious material can be used as cement mixture and concrete admixture

Method used

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  • Steel slag auxiliary cementing material and preparation method and application thereof
  • Steel slag auxiliary cementing material and preparation method and application thereof
  • Steel slag auxiliary cementing material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A steel slag auxiliary cementitious material rapidly stabilized and activated by carbon dioxide and a preparation method thereof, comprising the following steps:

[0024] (1) Take 1200g of steel slag particles (0.02-0.6mm in particle size) after crushing and iron selection and put them into the stirring pretreatment equipment;

[0025] (2) Spray 96g of water evenly on the steel slag surface (that is, the concentration of the admixture solution is 0%), and stir evenly;

[0026] (3) placing the pretreated steel slag particles in a mill for grinding, and simultaneously introducing 99% carbon dioxide gas to grind the steel slag particles to a size smaller than 0.10 mm;

[0027] (4) Put the steel slag micropowder in the stirring reaction equipment, feed 99% carbon dioxide gas into the reaction equipment, keep it under normal pressure for 30 minutes, and obtain the stabilized and activated steel slag auxiliary cementitious material.

Embodiment 2

[0029] The steel slag and test method adopted in this embodiment are all the same as those in Embodiment 1.

[0030] The steps for preparing the finished steel slag auxiliary cementitious material in this example are different from those in Example 1 in that 240 g of water is evenly sprayed in step (2), and kept at normal pressure for 45 minutes in step (4).

Embodiment 3

[0032] The steel slag and test method adopted in this embodiment are all the same as those in Embodiment 1.

[0033] The steps of preparing the finished steel slag auxiliary cementitious material in this example are different from those in Example 1 in that the gas in steps (3) and (4) is industrial tail gas with a carbon dioxide concentration of about 20%.

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Abstract

The invention discloses a steel slag auxiliary cementing material and a preparation method and application thereof. The preparation method comprises the following steps: (1) crushing undisturbed steel slag, selecting iron, and grinding in a mill to obtain steel slag particles; (2) putting the steel slag particles into stirring pretreatment equipment, and mixing and uniformly stirring the steel slag and an additive solution; (3) grinding the pretreated steel slag particles in a grinding machine, and meanwhile, introducing carbon dioxide gas to grind the steel slag particles into steel slag micro powder with a certain particle size; and (4) putting the steel slag micro powder into stirring reaction equipment, and introducing carbon dioxide gas into the reaction equipment to obtain the stabilized and activated steel slag auxiliary cementing material. According to the method, free CaO and part of free MgO are rapidly eliminated, so that the problem of poor stability of the steel slag is solved, the gelling activity of the steel slag is improved to a great extent, it is ensured that the stability of the auxiliary gelling material of the steel slag is qualified when the auxiliary gelling material of the steel slag is doped into cement or concrete, and application of the steel slag in building materials such as cement and concrete is promoted.

Description

technical field [0001] The invention belongs to the field of preparation methods of building materials, and in particular relates to a steel slag auxiliary cementitious material rapidly stabilized and activated by carbon dioxide, a preparation method and application thereof. Background technique [0002] Cement production consumes a lot of resources and emits a lot of carbon dioxide. The cement industry is my country's third largest carbon dioxide emitter, accounting for about 14% of the country's total industrial carbon emissions. In 2020, my country's cement output will reach 2.377 billion tons, and about 1.3 billion tons of carbon dioxide will be emitted. The carbon emission reduction of the cement industry is related to the realization of the national carbon peak and carbon neutral strategic goals. To this end, the academic and industrial circles have proposed and adopted various energy-saving and emission-reduction strategies, such as reducing the amount of cement in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B7/147C04B7/42
CPCC04B7/147C04B7/428C04B7/425Y02P40/10
Inventor 莫立武刘朋
Owner NANJING UNIV OF TECH
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