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High-strength, high-toughness and corrosion-resistant iron-nickel-based high-temperature alloy and preparation method thereof

A high-temperature alloy, high-strength and high-toughness technology, applied in the field of high-temperature metal structural materials, can solve the problems of high energy consumption, low power generation efficiency of thermal power units, etc., to reduce the grain boundary interface energy, improve the resistance to flue gas corrosion, and improve the toughness of the alloy. Effect

Pending Publication Date: 2021-07-09
HUANENG POWER INT INC +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] Coal-fired thermal power units provide more than 70% of my country's electricity. It is expected that for a long time in the future, the situation dominated by coal power will be difficult to change. However, the average power generation efficiency of thermal power units in my country is low and energy consumption is relatively high. Sulfur dioxide, nitrogen oxides, NOx major sources of emissions of carbon dioxide and mercury

Method used

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  • High-strength, high-toughness and corrosion-resistant iron-nickel-based high-temperature alloy and preparation method thereof
  • High-strength, high-toughness and corrosion-resistant iron-nickel-based high-temperature alloy and preparation method thereof
  • High-strength, high-toughness and corrosion-resistant iron-nickel-based high-temperature alloy and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0028] 1. Alloy composition

[0029] Table 1 provided the chemical composition of Example 1 of the present invention. Test alloy 1# is the iron-nickel base superalloy of embodiment 1 of the present invention, in order to compare with the highest austenitic heat-resistant steel Sanicro25 alloy (Sweden Sandvik company development) with the present temperature bearing capacity, also listed Sanicro25 in the table ingredients.

[0030] Table 1 Chemical composition (% by weight, balance being Ni) of embodiment 1 of the present invention and comparative example (Sanicro25)

[0031]

[0032]

[0033] 2. Alloy melting and thermal deformation

[0034] Fe 32%, Cr 19%, Mo 0.1%, W 0.6%, Ti 1.9%, Al 1.5%, Mn 0.1%, Nb 0.05%, Si 0.05%, C 0.06%, B 0.003%, Zr by weight percentage 0.01-0.04%, P≤0.01%, the balance is Ni, the weight percentage of Ti+Al is 3.4%, and the ratio of Ti / Al is 1.27%. It is melted in a vacuum induction furnace and cast into an alloy ingot.

[0035] After the all...

Embodiment 2-8

[0056] On the basis of Example 1, the composition of the iron-nickel-based superalloy is replaced to obtain an alloy with the same adaptability.

[0057]

[0058]

Embodiment 9-16

[0060] On the basis of Examples 1-8, the heat treatment conditions of the iron-nickel-based superalloy are replaced to obtain an alloy with the same adaptability.

[0061]

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Abstract

The invention discloses a high-strength, high-toughness and corrosion-resistant iron-nickel-based high-temperature alloy and a preparation method thereof. The iron-nickel-based high-temperature alloy is prepared from the components including, by weight, 30%-35% of Fe, 16%-22% of Cr, less than or equal to 0.8% of Mo, 0.1%-0.8% of W, 1.5%-2.3% of Ti, 1.2%-2.2% of Al, less than or equal to 1.0% of Mn, less than or equal to 0.2% of Nb, less than or equal to 0.1% of Si, 0.03%-0.10% of C, 0.001%-0.005% of B, 0.01%-0.04% of Zr, less than or equal to 0.01% of P and the balance Ni, the weight percentage of Ti and Al is 2.8%-4%, and the ratio of Ti to Al is 1%-1.5%. The iron-nickel-based high-temperature alloy is high in endurance strength, high in impact toughness and good in corrosion resistance; a gamma' phase and M23C6 are main strengthening phases; compared with the prior art, the alloy has the advantages of equivalent processing performance, lower material cost and more excellent structure stability, high-temperature strength, impact toughness and corrosion resistance, and can be used for manufacturing high-temperature components such as high-temperature superheaters and reheaters of ultra-supercritical thermal power generating units at the temperature of 650 DEG C or above, main steam pipelines, headers, blades, fasteners and the like.

Description

technical field [0001] The invention relates to the technical field of high-temperature metal structural materials, in particular to a high-strength, high-toughness, corrosion-resistant iron-nickel-based superalloy and a preparation method thereof. Background technique [0002] Coal-fired thermal power units provide more than 70% of my country's electricity. It is expected that for a long time in the future, the situation dominated by coal power will be difficult to change. However, the average power generation efficiency of thermal power units in my country is low and energy consumption is relatively high. Sulfur dioxide, nitrogen oxides, NOx major sources of emissions of carbon dioxide and mercury. The Chinese government promises to reduce carbon dioxide emissions per unit of GDP by 40-45% on the basis of 2005 by 2020, and to achieve carbon neutrality by 2060. In the field of coal power, adopting high-parameter and large-capacity thermal power units is one of the most dire...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/05C22C30/00C22C1/02C22F1/10
CPCC22C19/056C22C19/055C22C30/00C22C1/023C22F1/10
Inventor 袁勇严靖博杨珍张鹏周永莉尹宏飞党莹樱黄锦阳鲁金涛谷月峰
Owner HUANENG POWER INT INC