Spirofluorene compound and organic electroluminescent device containing same
A compound, spirofluorene technology, applied in the direction of electric solid devices, electrical components, organic chemistry, etc., can solve the problems of development that has not been fully realized, and achieve the effects of excellent film phase stability, excellent life, and excellent hole migration ability.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0161] Embodiment 1: the synthesis of compound 1
[0162]
[0163] In a 250ml three-neck flask, under a nitrogen atmosphere, add 0.01mol raw material A-1, 0.012mol raw material B-1, 0.03mol potassium tert-butoxide, 1×10 -4 mol Tris(dibenzylideneacetone)dipalladium Pd 2 (dba) 3 , 1×10 -4 mol of triphenylphosphine, 150ml of toluene, heated to reflux for 12 hours, sampling point plate, showing that the reaction is complete. Natural cooling, filtration, rotary evaporation of the filtrate, passing through a silica gel column (silica gel 100-200 mesh, eluent: chloroform: n-hexane = 30:70 (volume ratio)) to obtain intermediate A-1. Elemental analysis structure (molecular formula C 31 h 21 N): Theoretical C 91.37; H 5.19; N 3.44; Tested: C 91.34; H 5.21; N 3.45. MS (m / z) (M+): theoretical value 407.17, found value 407.34.
[0164] In a 250ml three-neck flask, under nitrogen atmosphere, add 0.01mol raw material C-1, 0.024mol intermediate A-1, 0.03mol potassium tert-butoxide, ...
Embodiment 2
[0166] Embodiment 2: the synthesis of compound 85
[0167]
[0168] In a 250ml three-neck flask, under a nitrogen atmosphere, add 0.01mol raw material A-1, 0.012mol raw material B-1, 0.03mol potassium tert-butoxide, 1×10 -4 mol Tris(dibenzylideneacetone)dipalladium Pd 2 (dba) 3 , 1×10 -4 mol of triphenylphosphine, 150ml of toluene, heated to reflux for 12 hours, sampling point plate, showing that the reaction is complete. Natural cooling, filtration, rotary evaporation of the filtrate, passing through a silica gel column (silica gel 100-200 mesh, eluent: chloroform: n-hexane = 30:70 (volume ratio)) to obtain intermediate A-1. Elemental analysis structure (molecular formula C 31 h 21 N): Theoretical C 91.37; H 5.19; N 3.44; Tested: C 91.34; H 5.21; N 3.45. MS (m / z) (M+): theoretical value 407.17, found value 407.34.
[0169] In a 250ml three-necked flask, under the protection of nitrogen, add 0.01mol raw material C-2, 0.012mol raw material D-1, 0.02mol sodium carbonat...
Embodiment 3
[0172] Embodiment 3: the synthesis of compound 14
[0173]
[0174] In a 250ml three-neck flask, under an atmosphere of nitrogen gas, add 0.01mol raw material A-1, 0.012mol raw material B-3, 0.03mol potassium tert-butoxide, 1×10 -4 mol Tris(dibenzylideneacetone)dipalladium Pd 2 (dba) 3 , 1×10 -4 mol of triphenylphosphine, 150ml of toluene, heated to reflux for 12 hours, sampling point plate, showing that the reaction is complete. Natural cooling, filtration, rotary evaporation of the filtrate, passing through a silica gel column (silica gel 100-200 mesh, eluent: chloroform: n-hexane = 30:70 (volume ratio)) to obtain intermediate A-3. Elemental analysis structure (molecular formula C 37 h 28 NBO 2 ): theoretical value C84.26; H 4.97; N 2.66; test value: C84.31; H 4.96; N 2.63. MS (m / z) (M+): theoretical value 527.21, found value 527.37.
[0175] In a 250ml three-necked flask, add 0.01mol raw material A-1, 0.012mol raw material C-2, 0.03mol potassium tert-butoxide, 1×...
PUM
Property | Measurement | Unit |
---|---|---|
Thickness | aaaaa | aaaaa |
Thickness | aaaaa | aaaaa |
Thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com