Arylamine compound and organic electroluminescent device comprising same
A technology of aromatic amines and compounds, applied in the field of display devices, can solve problems such as development that has not been fully realized, and achieve the effects of excellent hole migration capability, increasing exciton concentration, and increasing device life.
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Embodiment 1
[0170] Embodiment 1: the synthesis of compound H11
[0171]
[0172] In the three-necked flask, under the protection of nitrogen, add 0.01mol raw material A, 0.012mol raw material B, 0.02mol sodium carbonate, mixed solvent (150ml toluene, 45ml H 2 O), then add 1×10 -4 mol tetrakis(triphenylphosphine)palladium Pd(pph 3 ) 4 , heated to 105°C, refluxed for 24 hours, sampling and pointing plate, showing no remaining iodide, the reaction was complete. Naturally cooled to room temperature, filtered, and the filtrate was subjected to vacuum rotary evaporation (-0.09MPa, 85°C), passed through a neutral silica gel column (silica gel 100-200 mesh, the eluent was chloroform:n-hexane=1:2 (volume ratio) ), to obtain intermediate M. Elemental analysis structure (molecular formula C 24 h 15 BrClN): Theoretical C 66.61; H 3.49; Cl 8.19; Br 18.46; N 3.24; Found: C 66.57; H 3.45; Cl 8.14; MS: The theoretical value is 431.01, and the measured value is 431.19.
[0173] In the three-nec...
Embodiment 1-113
[0212] Carry out according to the method of device preparation embodiment 1, difference is that the organic material in step b), c), d), f) is replaced by the organic material shown in table 3 respectively, wherein ET1:LiQ, E2: The ratios of LiQ, E5:LiQ, E12:LiQ, E16:LiQ, and E23:LiQ are all 50:50.
Embodiment 114-125
[0214] Follow the method of Device Preparation Comparative Example 23, except that the organic materials in steps b), c), d), and f) are replaced with the organic materials shown in Table 4, respectively.
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