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High-toughness cast magnesium-rare earth alloy capable of being subjected to rapid high-temperature solution treatment and preparation method of high-toughness cast magnesium-rare earth alloy

A magnesium rare earth alloy and solid solution treatment technology, applied in the field of metal structural materials, can solve the problems of low plasticity at room temperature, achieve the effect of improving process efficiency and shortening high temperature solution time

Active Publication Date: 2022-07-01
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although Mg-Gd cast magnesium alloys have high strength, they have low plasticity at room temperature, which makes it difficult to meet the high plasticity requirements in the aerospace field: for example, the standard tensile strength of VW103Z cast magnesium rare earth alloy is 300MPa, and the yield strength is 200MPa. The elongation is only 2.0%; the standard tensile strength of VQ132Z cast magnesium rare earth alloy is 350MPa, the yield strength is 240MPa, and the elongation is only 1.0%.

Method used

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  • High-toughness cast magnesium-rare earth alloy capable of being subjected to rapid high-temperature solution treatment and preparation method of high-toughness cast magnesium-rare earth alloy
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Embodiment 1

[0042] This embodiment relates to a high-strength and toughness cast magnesium rare-earth alloy that can be treated by rapid high-temperature solution treatment. The components of the magnesium alloy and their mass percentages are: 8.2wt.%Gd, 2.8wt.%Y, 0.2wt.%Zn , 0.1wt.%La, 0.4wt.%Zr, the total content of impurity elements Si, Fe, Cu and Ni is less than 0.2wt.%, and the balance is Mg (wt.% means that the composition accounts for the total amount of the prepared magnesium alloy. The percentage of mass, the total mass is the mass sum of Mg, Zn and various master alloys).

[0043] This embodiment relates to the preparation method of the high-strength and toughness cast magnesium rare earth alloy capable of rapid high-temperature solution treatment as described above, wherein the melting and casting process is performed in SF 6 and CO 2 Under mixed gas protection conditions, the steps are as follows:

[0044] (1) Baking material: Preheat pure magnesium, pure zinc, Mg-Gd, Mg-Y, ...

Embodiment 2

[0052] This embodiment relates to a high-strength and toughness cast magnesium rare-earth alloy that can be treated by rapid high-temperature solution treatment. The components of the magnesium alloy and their mass percentages are: 8.2wt.%Gd, 2.8wt.%Y, 0.2wt.%Zn , 0.2wt.%La, 0.4wt.%Zr, the total content of impurity elements Si, Fe, Cu and Ni is less than 0.2wt.%, and the balance is Mg (wt.% refers to the proportion of the composition in the total prepared magnesium alloy The percentage of mass, the total mass is the mass sum of Mg, Zn and various master alloys).

[0053] This embodiment relates to the preparation method of the high-strength and toughness cast magnesium rare earth alloy capable of rapid high-temperature solution treatment as described above, wherein the melting and casting process is performed in SF 6 and CO 2 Under mixed gas protection conditions, the steps are as follows:

[0054] (1) Baking material: Preheat pure magnesium, pure zinc, Mg-Gd, Mg-Y, Mg-La, M...

Embodiment 3

[0062] This embodiment relates to a high-strength and toughness cast magnesium rare-earth alloy that can be treated by rapid high-temperature solution treatment. The components of the magnesium alloy and their mass percentages are: 8.2wt.%Gd, 2.8wt.%Y, 0.2wt.%Zn , 0.4wt.%La, 0.4wt.%Zr, the total content of impurity elements Si, Fe, Cu and Ni is less than 0.2wt.%, and the balance is Mg (wt.% means that the composition accounts for the total amount of the prepared magnesium alloy. The percentage of mass, the total mass is the mass sum of Mg, Zn and various master alloys).

[0063] This embodiment relates to the preparation method of the high-strength and toughness cast magnesium rare earth alloy capable of rapid high-temperature solution treatment as described above, wherein the melting and casting process is performed in SF 6 and CO 2 Under mixed gas protection conditions, the steps are as follows:

[0064] (1) Baking material: Preheat pure magnesium, pure zinc, Mg-Gd, Mg-Y, ...

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Abstract

The invention discloses a high-toughness cast magnesium-rare earth alloy capable of being subjected to rapid high-temperature solution treatment and a preparation method of the high-toughness cast magnesium-rare earth alloy. The magnesium alloy comprises the following components in percentage by mass: 5.6-10.8% of Gd, 2.2-3.2% of Y, 0.1-0.4% of Zn, 0.1-0.4% of La, 0.3-0.7% of Zr, less than 0.2 wt.% of impurity elements Si, Fe, Cu and Ni, and the balance of Mg. The preparation method comprises the working procedures of material drying, magnesium melting, alloy element adding, refining, casting forming, heat treatment and the like. Through La element microalloying and subsequent heat treatment process optimization, the high-toughness cast magnesium-rare earth alloy capable of being subjected to rapid high-temperature solid solution treatment is obtained, the high-temperature solid solution time can be remarkably shortened, the solid solution treatment efficiency can be improved, and meanwhile it is guaranteed that the alloy has high strength and plasticity. The invention also provides a material basis for the implementation of the online continuous solution treatment process of the high-toughness cast magnesium-rare earth alloy.

Description

technical field [0001] The invention relates to a high-strength and toughness cast magnesium rare earth alloy capable of rapid high-temperature solid solution treatment and a preparation method thereof, belonging to the technical field of metal structural materials. Background technique [0002] As the lightest metal structural material, magnesium alloy has the advantages of high specific strength, specific stiffness, and good shock absorption, and is widely used in aerospace, transportation, 3C fields, etc. The high-temperature solution treatment + low-temperature aging treatment process is a typical heat treatment process for high-strength cast magnesium alloys, referred to as T6 treatment. For example, the high-strength cast magnesium rare-earth alloy EZ30Z (Mg-Nd-Zn-Zr-Ca) disclosed in the patent of "High-strength cast magnesium alloy containing rare earth and its preparation method" (patent number: CN200510030457.8), its conventional heat treatment process is: (525~540...

Claims

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Application Information

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IPC IPC(8): C22C1/03C22C23/06C22F1/06
CPCC22C23/06C22F1/06C22F1/002C22C1/03
Inventor 付彭怀王迎新林金铭彭立明丁文江
Owner SHANGHAI JIAO TONG UNIV
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