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Lithium ion battery composite positive electrode slurry, positive electrode plate and lithium ion battery

A technology for lithium-ion batteries and composite positive electrodes, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of poor low-temperature performance of lithium iron phosphate, achieve good thermal stability, avoid loss of active materials, and have long cycle life Effect

Pending Publication Date: 2022-07-05
南通赛得能源有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] For this reason, the technical problem to be solved by the present invention is the problem of poor low-temperature performance of the existing lithium iron phosphate, thereby providing a lithium-ion battery composite positive electrode slurry, positive electrode sheet and lithium-ion battery

Method used

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  • Lithium ion battery composite positive electrode slurry, positive electrode plate and lithium ion battery
  • Lithium ion battery composite positive electrode slurry, positive electrode plate and lithium ion battery

Examples

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Embodiment 1

[0053] This embodiment provides a lithium-ion battery composite positive electrode slurry, and the specific preparation method is as follows.

[0054] (1) First prepare the carbon-iodine complex:

[0055] Disperse the activated carbon in deionized water, add iodine, then add NaOH solution to make the solution alkaline, stir at room temperature for 3 days, then add hydrochloric acid to make the solution pH 2, wash with water until the solution is neutral, and dry to obtain the carbon Iodine complex. The content of iodine in the carbon-iodine complex is 80 wt.%.

[0056] (2) Then prepare the lithium-ion battery composite cathode slurry:

[0057]Take 20g carbon-iodine complex, 70g lithium iron phosphate, 2g Ketjen Black, 2g dispersant CMC, add deionized water and stir at 2500rpm for 4 hours, then add 15g aqueous binder SBR emulsion (SBR content 40wt.%), to The positive electrode slurry was obtained by stirring at 300 rpm for 30 minutes, and the solid content of the slurry was ...

Embodiment 2

[0066] This embodiment provides a lithium-ion battery composite positive electrode slurry, and the specific preparation method is as follows:

[0067] (1) First prepare the carbon-iodine complex:

[0068] Disperse the activated carbon in deionized water, add iodine, then add NaOH solution to make the solution alkaline, stir at room temperature for 3 days, then add hydrochloric acid to make the solution pH 2, wash with water until the solution is neutral, and dry to obtain the carbon Iodine complex. The content of iodine in the carbon-iodine complex is 80 wt.%.

[0069] (2) Then prepare the lithium-ion battery composite cathode slurry:

[0070] Take 12g carbon-iodine composite, 78g lithium iron phosphate, 2g Ketjen black, 8g oily binder PVDF, add N-methylpyrrolidone and stir at 2000rpm for 4 hours to obtain the positive electrode slurry, the solid content of the slurry is 35wt .%.

[0071] This embodiment also provides a lithium-ion battery positive pole piece, and the prep...

Embodiment 3

[0079] This embodiment provides a lithium-ion battery composite positive electrode slurry, and the specific preparation method is as follows:

[0080] (1) First prepare the carbon-iodine complex:

[0081] Disperse the activated carbon in deionized water, add iodine, then add NaOH solution to make the solution alkaline, stir at room temperature for 3 days, then add hydrochloric acid to make the solution pH 2, wash with water until the solution is neutral, and dry to obtain the carbon Iodine complex. The content of iodine in the carbon-iodine complex is 80 wt.%.

[0082] (2) Then prepare the lithium-ion battery composite cathode slurry:

[0083] The first slurry: take 12g carbon-iodine composite, 78g lithium iron phosphate, 3g acetylene black, 7g oily binder PVDF, add N-methylpyrrolidone and stir at 2000rpm for 5 hours to obtain the positive electrode slurry, the slurry The solids content was 35 wt.%.

[0084] The second slurry: take 90g carbon-iodine complex, 2g Ketjen Blac...

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Abstract

The invention discloses a lithium ion battery composite positive electrode slurry, which comprises a first slurry, the first slurry comprises a carbon-iodine compound, lithium iron phosphate and conductive carbon in specific parts by mass, and the carbon-iodine compound is a compound obtained by adsorbing elemental iodine by activated carbon; the positive electrode slurry further comprises an optional second slurry. The invention also provides a preparation method of the positive electrode slurry, and a positive electrode plate and a lithium ion battery which are obtained by adopting the positive electrode slurry. The lithium ion battery composite positive electrode slurry provided by the invention adopts the carbon-iodine compound and the lithium iron phosphate as the positive electrode material, has the characteristics of both lithium iodide and lithium iron phosphate at the same time, maintains the characteristic of long cycle life under the condition of low-temperature performance, and on the other hand, the gram volume of the positive electrode material is greatly improved after the carbon-iodine compound and the lithium iron phosphate are compounded.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a lithium ion battery composite positive electrode slurry, a positive electrode pole piece and a lithium ion battery. Background technique [0002] With the proposed carbon neutrality goal, the demand for energy storage or power battery products represented by lithium-ion batteries is increasing, and its application scenarios are becoming more and more extensive. While people pay attention to the energy density, cycle life, and safety of lithium-ion batteries, they also put forward higher requirements for their applications in special environments. Lithium iron phosphate batteries have been widely used due to their long cycle life, good battery safety, and low cost. However, lithium iron phosphate batteries have problems such as low capacity, fast decay, and poor cycle rate in low temperature environments. These disadvantages limit their application expansion in sp...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/58H01M4/38H01M4/62H01M4/1397H01M4/136H01M10/0525
CPCH01M4/364H01M4/5825H01M4/381H01M4/625H01M4/1397H01M4/136H01M10/0525H01M2004/028Y02E60/10
Inventor 周行韩振朱文俊周浩
Owner 南通赛得能源有限公司