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Hyperbranched polymer pressure-sensitive adhesive as well as preparation method and application thereof

A polymer, pressure-sensitive adhesive technology, applied in the direction of adhesives, etc., can solve the problems of reduced adhesion performance, rare, limited practical application of adhesives, etc., to achieve the effect of long stretchability

Pending Publication Date: 2022-07-26
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, traditional adhesives can only adhere to dry substrates in the air. When there is water on the surface of the substrate, its adhesion performance will be reduced or even disappear.
And many adhesives that have been reported require a certain curing time when adhering to the substrate, which will limit the practical application of the adhesive.
Pressure-sensitive adhesives have the advantage of being easy to use and can achieve immediate adhesion, but traditional pressure-sensitive adhesives can only achieve adhesion to dry and clean interfaces, but truly dry and clean interfaces are very rare in life, so , it is very important to develop a method that can achieve immediate tough adhesion to wet substrates and dust-coated surfaces.
In industrial production, in many cases, it is necessary to adhere in a low temperature environment, and most of the adhesives reported so far will lose their adhesiveness when the temperature is relatively low, and due to lowering the temperature, the bulk of the adhesive will change. Brittleness is also not conducive to achieving high-strength adhesion, so adhesives that can maintain high-strength adhesion in low temperature environments are also very important

Method used

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  • Hyperbranched polymer pressure-sensitive adhesive as well as preparation method and application thereof
  • Hyperbranched polymer pressure-sensitive adhesive as well as preparation method and application thereof
  • Hyperbranched polymer pressure-sensitive adhesive as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Weigh 0.2mol lipoic acid with a tray balance, pentaerythritol tetraacrylate is 5mol% of lipoic acid, polyethylene glycol diacrylate is 15mol% of lipoic acid and agarose is 5wt% of lipoic acid, respectively weigh the above four The components and the three-necked flask are heated to 90° C. and reacted for three hours, and the product is transferred to a tetrafluoroethylene mold for cooling and solidification to obtain a hyperbranched polymer pressure-sensitive adhesive.

[0028] like figure 1 After the heating reaction, the double bond peak of the multi-double bond monomer disappeared, indicating that the double bond participated in the free radical polymerization and interacted with the thiol radical at the end of the polylipoic acid, while the ring structure in the lipoic acid structure The peaks of 3.58-3.65 and 3.1-3.25ppm shifted to 2.93ppm, indicating that the ring-opening self-polymerization occurred.

[0029] like figure 2 shown, the lipoic acid monomer at 511...

Embodiment 2

[0041] Take by weighing 0.2mol lipoic acid with a tray balance, the mass sum of pentaerythritol tetraacrylate and polyethylene glycol diacrylate is 1 mol% of lipoic acid (the mol ratio of pentaerythritol tetraacrylate and polyethylene glycol diacrylate is 1: 2), and agarose is 5wt% of lipoic acid, respectively take by weighing above-mentioned four kinds of components and be heated to 80 ℃ in the there-necked flask and react for 4 hours, transfer the product to the tetrafluoroethylene mould and obtain overrun after cooling and solidifying. polymerized pressure-sensitive adhesive.

Embodiment 3

[0043] Take by weighing 0.2mol lipoic acid with a tray balance, the mass sum of pentaerythritol tetraacrylate and polyethylene glycol diacrylate is 2mol% of lipoic acid (the mol ratio of pentaerythritol tetraacrylate and polyethylene glycol diacrylate is 1: 3), and agarose is 5wt% of lipoic acid, take by weighing the above-mentioned four kinds of components and be heated to 95 ℃ in the there-necked flask respectively and react 3 hours after, transfer the product to the tetrafluoroethylene mould and obtain overrun after cooling and solidifying. polymerized pressure-sensitive adhesive.

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Abstract

The invention provides a hyperbranched polymer pressure-sensitive adhesive and a preparation method and application thereof.The hyperbranched polymer pressure-sensitive adhesive is obtained by taking lipoic acid, agarose and a multi-double-bond compound as monomers, mixing the lipoic acid, the agarose and the multi-double-bond compound, jointly heating the mixture to 80-100 DEG C, continuously reacting for 2-4 h and then cooling. The polymer pressure-sensitive adhesive can maintain high-strength adhesion in dry, wet, low-temperature and dust environments.

Description

technical field [0001] The invention relates to the field of polymer materials, and more particularly to a hyperbranched polymer pressure-sensitive adhesive and a preparation method and application thereof. Background technique [0002] Elastomer is a three-dimensional network composed of high molecular polymers. The interior of the elastomer does not contain any solvent, so it will not become hard and brittle due to solvent volatilization when placed in the air. Some elastomers have good biocompatibility and other excellent properties, such as: environmental responsiveness, antibacterial properties, self-healing properties, adhesion, stretchability, etc. These characteristics make elastomers have broad application prospects in biomedicine, sensors, and self-healing materials. [0003] Adhesives are very important in daily life, work and medicine, especially immediate wet adhesion is essential for hemostasis, wound healing, replacement of surgical sutures and medical conduc...

Claims

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Application Information

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IPC IPC(8): C09J187/00C08G83/00
CPCC09J187/00C08G83/005C08G2170/40Y02E60/10
Inventor 刘文广崔春燕
Owner TIANJIN UNIV
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