Pigment composition contg. modified block copolymer disperser
A technology of composition and polymer, applied in the direction of pigment slurry, organic dye, application, etc., can solve the problem of reducing the antioxidant performance of polymer
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[0261] contains useful >NO-R Dispersions of Block Copolymers Prepared by Free Radical Polymerization of Initiators and coloring paint
[0262] 1.1 polymer preparation
[0263] 1.1.1 Preparation of poly(n-butyl acrylate)
[0264] 200g (1.56mol) n-butyl acrylate (Fluka purum 99%) and 9.07g (29.7mmol) initiator (prepared according to GB-A-2 335 190) was added to a 400ml reactor equipped with a mechanical stirrer. The air was removed from the flask by stirring and vacuum, and rinsed 3 times with nitrogen. The resulting clear solution was heated to 145°C in an oil bath. After allowing the polymerization to proceed for 4 hours, the reaction mixture was cooled to 60°C. The remaining monomers were removed by evacuating at high vacuum. 154 g (77%) of the initial monomer had reacted. A clear yellow viscous fluid was obtained.
[0265] GPC (THF / PS standard): Mn 5250 (calculated 5190), Mw 6500; polydispersity 1.2.
[0266] 1.1.2 Preparation of block copolymer of n-butyl a...
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