Dental impression material utilizing ruthenium catalyst
A catalyst and dental imprinting technology, applied in dental impression materials, dentistry, compression molding cups, etc., can solve the problems of platinum-based catalyst deactivation, increased time and work, expensive silicon-containing oligomers, etc.
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[0017] Synthesis of norbornyl-terminated telechelic polydimethylsiloxane was performed according to the following scheme:
[0018] Equipped with mechanical stirrer, condenser and N 2 360.0 g of polydimethylsiloxane-terminated silanol (DMS-S27, n=243 from Gelest Corp.) and 4.85 g of 1% 4-(N , Triethylamine of N-dimethyl)aminopyridine. 9.02 g of 2-(5-norborn-2-enyl)-ethyl-dimethylchlorosilane was added dropwise to the flask with stirring. After the addition, the reaction temperature was raised to 70°C and stirring was continued at this temperature for 4 hours. Then, 2 mL of methanol was added to the mixture and stirring was continued for 1 more hour. The reaction mixture was then diluted with 500 mL of hexane and filtered to remove white salts. The hexane solution was washed three times with 1% hydrochloric acid and three times with deionized water. Then use Na 2 SO 4 Dry the solution. After evaporation of the solvent in vacuo, the product was obtained as a clear liqui...
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