Red mud dealkalization method at normal pressure by Bayer process

A technology of Bayer process red mud and Bayer process, which is applied to the purification of alumina/aluminum hydroxide, aluminate/aluminum oxide/aluminum hydroxide, etc. It can solve the problems of not being able to meet the requirements of red mud and affecting the effect of the process, and achieve The effect of improving productivity

Inactive Publication Date: 2005-03-16
GUIZHOU BRANCH CHINA ALUMINUM IND
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, after the dissolution slurry in the Bayer process system of Shanxi Branch is diluted and separated by settling, the bottom flow of the settling tank is washed with red mud by the second reverse washing process. Under the existing production conditions, the water content in the filter cake of the red mud filter It is about 40% and

Method used

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  • Red mud dealkalization method at normal pressure by Bayer process

Examples

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Comparison scheme
Effect test

Embodiment 1

[0014] Bayer process red mud N / S0.3, after adding [CaO f ] / [Na 2 o 赤 ] After lime with a molar ratio of 1.2, keep the dealkalization temperature at 70°C and the material L / S1.5, and stir dealkalization for 2 hours. After the low-alkali red mud slurry is washed, filtered and dried, the Bayer process red mud The N / S can be reduced to 0.09.

Embodiment 2

[0016] Bayer process red mud N / S0.35, after adding [CaO f ] / [Na 2 o 赤 ] After lime with a molar ratio of 1.5, keep the dealkalization temperature at 70°C and the material L / S1.8, and stir dealkalization for 2.5 hours. After the low-alkali red mud slurry is washed, filtered and dried, the Bayer process red mud The N / S can be reduced to 0.06.

Embodiment 3

[0018] Bayer process red mud N / S0.35, after adding [CaO f ] / [Na 2 o 赤 ] After lime with a molar ratio of 2.5, keep the dealkalization temperature at 70°C and the material L / S1.5, and stir dealkalization for 1.0 hour. After the low-alkali red mud slurry is washed, filtered and dried, the Bayer process red mud The N / S can be reduced to 0.08.

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Abstract

The invention discloses a red mud dealkalization method at normal pressure by Bayer process, wherein the dealkalizing step consists of, washing and filtering the red mud, charging lime cream into the red mud filter cake, mixing for dealkalizing reaction, subjecting the reaction slip to washing, filtering, drying and discharging.

Description

technical field [0001] The invention relates to a Bayer method red mud dealkalization method under normal pressure, which relates to the treatment of red mud in the process of producing alumina by Bayer method or mixed method. technical background [0002] my country's alumina production mainly uses insoluble diaspore bauxite as raw material. According to statistics, the ore with A / S>10 accounts for 10%, the ore with A / S of 7-10 accounts for 20%, and the ore with A / S>10 accounts for 20%. The ore whose S is 4-7 accounts for more than 60%, and the ore whose A / S is 2.6-4 accounts for 10%. Due to the use of bauxite with high aluminum, high silicon, and low aluminum-silicon ratio as raw materials, most alumina plants mostly adopt the hybrid production process, and the sintering part provides the Bayer process system with seed steaming mother liquor to make up alkali, and the Bayer process part Red mud is also provided as raw material to the sintering system. The two systems...

Claims

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Application Information

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IPC IPC(8): C01F7/02C01F7/46
Inventor 李少康梁春来李光柱赵培生卜天梅郭晋梅杨金妮李文化尹成王浩吕鲜翠孙玉萍
Owner GUIZHOU BRANCH CHINA ALUMINUM IND
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