Moisture-permeable waterproof film, composite material, and processes for producing these
一种透湿防水、制造方法的技术,应用在薄料处理、化学仪器和方法、纺织品和造纸等方向,能够解决耐久性没有、膜强度降低、没有发现实用性能等问题
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Embodiment 1
[0167] Using "Lezamin D2060" (trade name manufactured by Dainichi Seika Co., Ltd.) whose main component is self-emulsifying polyurethane and a water-soluble resin whose main component is water-soluble polyurethane containing a silanol group as a crosslinkable terminal functional group, These were respectively mixed in an equal weight of solid content to prepare a mixed resin having a solid content of 27 wt%. Among them, the water-soluble resin with water-soluble polyurethane as the main component uses 4,4'-methylene bis(cyclohexyl isocyanate) as the polyisocyanate component, and uses 0.248mmol / g as the dihydroxyalkyl fatty acid relative to the solid content of the resin. 2,2-Dimethylolpropionic acid, synthesized by using polyethylene glycol with a number average molecular weight of 1000 at a ratio of 67.2 wt% to the resin solid content as a polyalkylene glycol component, and self-emulsifying polyurethane "Lezamin D2060" as the main component uses 4,4'-methylene bis(cyclohexyl ...
Embodiment 2
[0173] Using a resin whose main component is self-emulsifying polyurethane and a water-soluble resin whose main component is water-soluble polyurethane containing a silanol group as a crosslinkable terminal functional group, they are respectively mixed with equal weights of solid components to prepare A mixed resin with a solid content of 27 wt%, in which the water-soluble resin containing water-soluble polyurethane as the main component uses 4,4'-methylene bis(cyclohexyl isocyanate) as the polyisocyanate component, and the solid content of the resin is 0.248mmol 2,2-Dimethylolpropionic acid / g was synthesized as a dihydroxyalkyl fatty acid, and polyethylene glycol having a number average molecular weight of 1000 as a polyalkylene glycol component was 67.2% by weight relative to the resin solid content. The resin mainly composed of self-emulsifying polyurethane is 2,2-dihydroxy Methylbutyric acid was synthesized as a dihydroxyalkyl fatty acid, poly(1,4-butylene glycol) having a...
Embodiment 3
[0179] Except that no crosslinking agent was added, the same operation as in Example 1 was carried out to obtain the film of the present invention. The film thickness was 20 μm.
[0180] As shown in Tables 1 and 2, because the water-based resin has good moisture permeability and water resistance, it is a moisture-permeable waterproof film with less organic solvent discharge and less environmental pollution than the existing technology.
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