Colored image-forming composition containing phthalocyanine compound, inks, inkjet inks, inkjet recording method and method of improving tolerance to decoloration due to ozone gas
A technology of compounds and inks, applied in temperature recording methods, chemical instruments and methods, copying/marking methods, etc., can solve the problems of incompatibility of color and resistance to light and oxidizing gas, and the lack of cyan ink products, etc.
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Embodiment I-1
[0617] (preparation of sample A)
[0618] A phthalocyanine compound (exemplary compound I-101, an oil-soluble dye) (5.3 g) and 7.04 g of dioctyl sodium sulfosuccinate were dissolved in 4.22 g of the following high-boiling organic solvent (s-2) at 70°C , 5.63g of the following high boiling point organic solvent (s-11) and 50mL of ethyl acetate. To this solution was added 500 mL of deionized water while stirring with a magnetic stirrer to prepare an oil-in-water type crude dispersion. Next, the crude dispersion was passed through a microfluidizer (MICROFLUIDEX INC) 5 times under a pressure of 600 bar, thereby forming fine particles. Furthermore, the resulting emulsion was desolventized by a rotary evaporator until the odor of ethyl acetate disappeared. To the thus obtained fine emulsion of the hydrophobic dye, 140 g of diethylene glycol, 50 g of glycerin, 7 g of SURFYNOL 465 (manufactured by Air Products & Chemicals) and 900 mL of deionized water were added to prepare an ink. ...
Embodiment I-2
[0674] Using the same prepared cartridge as in Example I-1, the image was printed on the wax photo paper EX manufactured by Fuji Photo Film by the same equipment as in Example I-1, and then the same as in Example I-1 way of evaluation. Results Similar results to Example I-1 were obtained.
Embodiment I-3
[0676] The same ink prepared in Example I-1 was packaged in a cartridge of an inkjet printer BJ-F850 (manufactured by CANON). Using this cartridge, images were printed onto inkjet paper glossy photo paper GP-301 by the same equipment, and then evaluated in the same manner as in Example I-1. Results Similar results to Example I-1 were obtained.
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