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High flame resistant union fabric

a union fabric and flame-resistant technology, applied in flame-proof filament manufacturing, weaving, yarn and other directions, can solve the problems of high flame resistance, high cost of union fabric, and difficulty in passing the highest flame-resistant class m1 in the combustion test nf p 92-503, and achieve high flame-resistant effect and specific thermal behavior

Inactive Publication Date: 2005-06-16
KANEKA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention relates to a flame resistant union fabric that is made by co-weaving a compound yarn and a cellulosic fiber yarn. The compound yarn is made by combining a halogen-containing flame resistant fiber, such as an antimony compound, with an acrylic based copolymer. The compound yarn has a certain thermal behavior that makes it highly flame resistant when used as a warp or weft yarn in the fabric. The cellulosic fiber yarn can be cotton, hemp, rayon, polynosic, cupra, acetate, or triacetate. The technical effect of this invention is to provide a flame resistant fabric that can withstand high temperatures and has good flame resistance properties.

Problems solved by technology

However, in these union fabrics, uneven existence of cellulosic fibers and halogen-containing flame resistant fibers in a fabric makes it very difficult to pass a highest flame resistant class M1 in NF P 92-503 combustion test in France that requires a very high degree of flame resistance.
However, since zinc stannate compounds a have higher cost than that of antimony compounds, the fiber has a cost higher than that of conventional fibers as compared with independent addition of the antimony compounds to the halogen-containing fiber, leading to a problem of higher cost of the union fabric.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

manufacturing example 1

Manufacture of a Compound Yarn of a Halogen-Containing Flame Resistant Fiber and Cotton

[0049] Acrylonitrile 52 parts, vinylidene chloride 46.8 parts, and sodium styrenesulfonate 1.2 parts were copolymerized to obtain an acrylic based copolymer. The obtained acrylic based copolymer was dissolved in acetone to obtain a solution with a concentration of 30%. Antimony trioxide 50 parts was added to the obtained copolymer 100 parts to prepare a spinning solution. The obtained spinning solution was extruded into an aqueous solution of acetone with a concentration of 38% at 25-degree C. using a nozzle having 0.07 mm of pore size, and 33000 numbers of holes, and then after washing with water the obtained filaments were dried for 8 minutes at 120 degrees C. Then the obtained filaments were drawn 3 times at 150 degrees C., and subsequently heat-treated for 30 seconds at 175 degrees C. to obtain a halogen-containing flame resistant fiber having a size of a fiber of 3 dtex. A finishing oil for ...

manufacturing example 2

Manufacture of a Compound Yarn of a Halogen-Containing Flame Resistant Fiber and Cotton

[0050] Except for having mixed cotton 30 parts to the halogen-containing flame resistant fiber 70 parts, a similar method as in Manufacturing Example 1 was repeated to manufacture a compound yarn and then a spun yarn having a metric count of No. 17. Table 1 shows elongation percentage of obtained compound yarn.

manufacturing example 3

Manufacture of a Compound Yarn of the Halogen-Containing Flame Resistant Fiber and Cotton

[0051] Except for having mixed a cotton 40 parts to the halogen-containing flame resistant fiber 60 parts, a similar method as in Manufacturing Example 1 was repeated to manufacture a compound yarn and then a spun yarn having a metric count of No. 17. Table 1 shows elongation percentage of obtained compound yarn.

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Abstract

A fabric is provided that has high degree of flame resistance in the case of a union fabric consisting of a halogen-containing flame resistant fiber including antimony compounds (A), and a cellulosic fiber, and the fabric is classified into class M1 of NF P 92-503 combustion test in France. A flame resistant union fabric obtained by co-weaving: a compound yarn (A) 30% to 70% by weight obtained by compounding a halogen-containing flame resistant fiber (a-1) including an antimony compound 25 to 50 parts by weight in an acrylic based copolymer 100 parts by weight obtained by polymerizing a monomer mixture including acrylonitrile 30 to 70% by weight, a halogen containing vinyl based monomer 30 to 70% by weight, and a vinyl based monomer copolymerizable therewith 0 to 10% by weight, and an other fiber (a-2), the compound yarn (A) having an elongation percentage less than 5% under a condition of a load of 300 mg / metric count of No. 17, and of a temperature range of 100 degrees C. to 500 degrees C.; a cellulosic fiber yarn (B) 70 to 30% by weight.

Description

FIELD OF THE INVENTION [0001] The present invention relates to a flame resistant union fabric. Specifically, the present invention relates to a union fabric having high degree of flame resistance consisting of a compound yarn having a halogen-containing flame resistant fiber including an antimony compound as a principal component, and a cellulosic fiber. BACKGROUND ART [0002] In recent years, demand for guarantee of safety of foods, clothes and housings has become stronger, and necessity for fire-resistant materials is increasing. In such a situation, a plurality of methods to give flame resistance to a flammable yarn by compounding general-purpose flammable fibers and flame resistant fibers having high degree of flame resistance, while maintaining characteristics of the flammable yarn, have been proposed. As such a compound fiber, for example, Japanese Patent No. 2593985 specification and Japanese Patent No. 2593986 specification disclose a method of using antimony compounds as a f...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): D02G3/44D03D15/12
CPCD01F1/07D03D15/12D02G3/443D01F6/40Y10T442/3293D03D15/513
Inventor ADACHI, MASAYUKIMATSUMOTO, TAKAHARUTAMURA, MASANOBU
Owner KANEKA CORP