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Colored alkali aluminosilicate glass articles

Inactive Publication Date: 2013-05-30
CORNING INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent text describes a method for making colored glass articles that have a compressive stress on their surface and a depth of layer of at least 15 μm. The method involves exchanging ions in the glass with preselected metal containing dopants to impart a preselected color. The resulting glass has a unique color and is stable over time. The method can involve using specific salts or formulations of salts to strengthen the glass. The technical effects of this patent include the ability to make colored glass articles that have a stable color and a compressive stress on their surface, as well as the ability to make such articles with preselected colors and depth of layer.

Problems solved by technology

However, new potential applications relating to product color(s) and / or aesthetics as not addressed by clear alkali aluminosilicate glasses.

Method used

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  • Colored alkali aluminosilicate glass articles
  • Colored alkali aluminosilicate glass articles
  • Colored alkali aluminosilicate glass articles

Examples

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examples

Example Glasses A-F

[0087]Example glasses A-F described in the following were batched with Si as sand, Al as alumina, Na as both soda ash and sodium nitrate, B as boric acid, and P as aluminum metaphosphate. For example glasses A-F, six distinct compositions were formulated so that each had a different colorant including one or more metal containing dopants formulated to impart a different preselected color added to the batch with iron (Fe) added as Fe2O3, vanadium (V) added as V2O5, chromium (Cr) added as Cr2O3, cobalt (Co) added as Co3O4, copper (Cu) added as CuO, and gold (Au) added as Au. The batch materials were melted at 1600° C. for four hours and then poured and annealed between 550° C. and 650° C. The compositions of example glasses A-F were analyzed by inductively coupled plasma and / or atomic absorption and / or X-ray fluorescence (XRF) techniques to determine the mol % of the constituent materials in each. The specific compositions for each of example glasses A-F are reporte...

example glass

G

[0106]For Example glass G described in the following, 25 distinct batches were prepared with Si as sand, Al as alumina, Na as both soda ash and sodium nitrate, B as boric acid, and P as aluminum metaphosphate. Each of the 25 distinct batches of example glass G was formulated without metal containing dopants. Each of the 25 distinct batches was melted at 1600° C. for four hours and then poured and annealed between 550° C. and 650° C. The composition each example glass G corresponding one of the 25 distinct batches was analyzed by inductively coupled plasma and / or atomic absorption and / or X-ray fluorescence (XRF) techniques to determine the mol % of the constituent materials in each. The range of compositions of example glass G is reported in Table XI.

TABLE XIExample Glass G Composition in Mole Percent [Mol %]SiO2Al2O3Na2OK2OMgOCaOSnO2ZrO2Fe2O3Range68.07.012.00.15.00.00.10.00.071.09.515.02.07.41.00.20.00.0

Samples 37-61

[0107]For each bath of example glass G, as-made substrates were co...

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Abstract

A glass article including at least about 40 mol % SiO2 and, optionally, a colorant imparting a preselected color is disclosed. In general, the glass includes, in mol %, from about 40-70 SiO2, 0-25 Al2O3, 0-10 B2O3; 5-35 Na2O, 0-2.5 K2O, 0-8.5 MgO, 0-2 ZnO, 0-10% P2O5 and 0-1.5 CaO. As a result of ion exchange, the glass includes a compressive stress (σs) at at least one surface and, optionally, a color. In one method, communicating a colored glass with an ion exchange bath imparts σs while in another; communicating imparts σs and a preselected color. In the former, a colorant is part of the glass batch while in the latter; it is part of the bath. In each, the colorant includes one or more metal containing dopants formulated to impart to a preselected color. Examples of one or more metal containing dopants include one or more transition and / or rare earth metals.

Description

[0001]This application claims the benefit of priority under 35 U.S.C. §119 of U.S. Provisional Application Ser. No. 61 / 565,196 filed on Nov. 30, 2011 the content of which is relied upon and incorporated herein by reference in its entirety.BACKGROUND[0002]1. Field[0003]Aspects of embodiments and / or embodiments of this disclosure generally relate to the field of glass materials technology and more specifically to the field of alkali aluminosilicate glass materials technology. Also, aspects of embodiments and / or embodiments of this disclosure are directed to one or more of: an ion exchangeable colored glass composition that substantially maintains its original color following an ion exchange treatment; an ion exchangeable, colorable glass composition to which a preselected color can be imparted by an ion exchange treatment; an ion exchanged (IOX) colored glass composition; an article or machine or equipment of or including an IOX colored glass composition; and one or more processes for...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C03C4/02C03C21/00
CPCC03C4/02C03C21/002Y10T428/315C03C3/11C03C3/087
Inventor MAURO, JOHN CHRISTOPHERPOTUZAK, MARCEL
Owner CORNING INC
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