Slurry chromizing compositions

Abstract

Slurry coating composition for selectively enriching surface regions of a metal-based substrate, for example, the under-platform regions of a turbine blade, with chromium. The slurry coating composition contains metallic chromium, optionally metallic aluminum in a lesser amount by weight than chromium, and optionally other constituents. The composition further includes colloidal silica, and may also include one or more additional constituents, though in any event the composition is substantially free of hexavalent chromium and sources thereof. The coating composition can be used in a process that entails applying the coating composition to a surface region to form a slurry coating, and then heating the coating to remove any volatile components of the coating composition and thereafter cause diffusion of chromium from the coating into the surface region to form a chromium-rich diffusion coating.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This is a continuation-in-part patent application of co-pending U.S. patent application Ser. No. 10 / 633,888, filed Aug. 4, 2003, the contents of which are incorporated herein by reference.BACKGROUND OF THE INVENTION[0002]The present invention generally relates to protective coating systems suitable for components exposed to high temperatures, such as the hostile thermal environment of a gas turbine engine. More particularly, this invention relates to slurry coating compositions and processes for selectively enriching surface regions of a component, for example, the under-platform regions on a turbine blade, with corrosion-resistant metals such as chromium.[0003]Components of turbine engines, such as the blades and vanes (nozzles) within the turbine section of a gas turbine engine, are often formed of an iron, nickel, or cobalt-base superalloy. A turbine blade has an airfoil against which hot combustion gases are directed during operation ...

AI Technical Summary

Benefits of technology

[0012]Notable advantages associated with the slurry coating composition of this invention include its effectiveness in chromizing a metal substrate, the ease with which the composition can be economically prepared, and the ease with which the content of the coating species in the composition can be readily adjusted to meet the requirements for a particular substrate. Moreover, the slurry coating composition of this invention exhibits highly desirable stability characteristics while being free of chromate compounds, including hexavalent chromium, and free of phosphoric acid. Furthermore, the slurry coating composition can be applied by a number of different techniques, and its wetting ability promotes the formation of a relatively uniform coating.

Problems solved by technology

A turbine blade has an airfoil against which hot combustion gases are directed during operation of the gas turbine engine, and whose surface is therefore subjected to severe attack by oxidation, corrosion and erosion.

However, during engine operation the under-platform regions of the blade can become corroded.

However, masking is time-consuming, expensive, and not always effective.

A drawback of slurry compositions of the type taught by Allen is the reliance on the presence of chromates, which are considered toxic.

When compositions containing this form of chromium are used (e.g., in spray booths), special handling procedures closely followed to satisfy health and safety regulations can result in increased costs and decreased productivity.

However, chromate-free slurry compositions can have various disadvantages, such as instability over the course of several hours (or even minutes), and generation of unsuitable levels of gases such as hydrogen.

Furthermore, chromate-free slurry compositions have been known to thicken or partially solidify, rendering them very difficult to apply to a substrate by spray techniques.

Moreover, the use of phosphoric acid in the compositions may also contribute to instability, especially if chromate compounds are not present since the latter apparently passivates the surfaces of the aluminum particles.

In the absence of chromates, phosphoric acid may attack the metallic aluminum particles in the slurry composition, rendering the composition thermally and physically unstable.

At best, such a slurry composition will be difficult to store and apply to a substrate.

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