In an embodiment, the present disclosure pertains to a method of forming a self-assembled
monolayer coating on a surface of a substrate. In general, the method includes
polishing the substrate, cleaning the substrate, and creating a plurality of bonding sites on the surface of the substrate for head groups of an organofunctional
silane molecule to bond. In some embodiments, the creating includes at least one of a liquid-phase
chemistry process or a dry
plasma chemistry process. In some embodiments, the method further includes
coating the substrate with a
silane coating solution. In some embodiments, the coating is performed in a controlled environment. In some embodiments, the controlled environment includes an
anhydrous environment free of at least one of water or
moisture. In a further embodiment, the present disclosure pertains to a
heat transfer composition having a coating thereon applied via the methods of the present disclosure.