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Sulfurized hydrogenation catalyst, prepn. method

A hydrogenation catalyst and catalyst technology, applied in the direction of catalyst activation/preparation, physical/chemical process catalysts, chemical instruments and methods, etc., can solve problems such as uncombined

Active Publication Date: 2008-01-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above catalyst preparation process only adds some additives to the active metal impregnation solution to improve the performance of the catalyst to a certain extent, but it does not directly combine the catalyst preparation process with the presulfurization process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Hydrogenation catalyst A: γ-alumina as the carrier, active metal composition: Mo content is MoO 3 The weight percentage is 23.7%, the Co content is 4.5% by weight CoO, and the P content is P 2 O 5 The percentage by weight is 3.1%. (Excluding the composition of vulcanizing agent)

[0020] The preparation process of the above-mentioned composition catalyst containing vulcanizing agent:

[0021] Take 1000 grams of γ-alumina carrier, the specific surface area of ​​the carrier is 296m 2 / g, pore volume 0.87ml / g, make 900ml aqueous solution with 129g molybdenum trioxide, 56g cobalt carbonate, 30.6g 85% phosphoric acid and appropriate amount of water, impregnate the above-mentioned carrier, and dry the impregnated sample at 340℃ for 4 hours , The catalyst intermediate is prepared, the Mo content is MoO 3 The weight percentage is 10%, the Co content is 2% by weight CoO, and the P content is P 2 O 5 The percentage by weight is 1.5%. A mixed solvent of 91.2 grams of lactic acid and 5...

Embodiment 2

[0023] Hydrogenation catalyst B: γ-alumina as the carrier, active metal composition: Mo content is MoO 3 The weight percentage is 25.8%, the Co content is 4.9% by weight CoO, and the P content is P 2 O 5 The percentage by weight is 3.5%. (Excluding the composition of the curing agent)

[0024] The preparation process of the above-mentioned composition catalyst containing vulcanizing agent:

[0025] Take 1000 grams of γ-alumina carrier, the specific surface area of ​​the carrier is 296m 2 / g, pore volume 0.87ml / g, use 129g molybdenum trioxide, 56g cobalt carbonate, 30.6g 85% phosphoric acid and appropriate amount of water to make 1300ml aqueous solution, impregnate the above-mentioned carrier, and dry the impregnated sample at 340℃ for 4 hours , The catalyst intermediate is prepared, the Mo content is MoO 3 8.9% by weight, Co content is 1.7% by weight based on CoO, and P content is based on P 2 O 5The percentage by weight is 1.1%. Disperse elemental sulfur powder in a solvent with ...

Embodiment 3

[0027] According to the method of Example 1, the active metal content in the catalyst intermediate was reduced to 15% by weight of the final catalyst active metal content, and the amount of elemental sulfur used was 80% of the theoretical required amount. Others, according to the method of Example 1, to obtain catalyst C .

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PUM

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Abstract

A process for preparing the sulfurizing hydrocatalyst used for the hydrodesulfurizing and hydrodenitrifying reactions of light fractional oil and the hydrosaturating of arylhydrocarbon includes such steps as carrying a certain part of the precursor compound of the metal in VI and VIII families, introducing sulfur to it, heat treating, introducing the rest of said precursor compound, and drying.

Description

Technical field [0001] The invention relates to a preparation method of a high-activity hydrocarbon oil hydroprocessing catalyst to meet the needs of clean light distillate oil production. Background technique [0002] Hydrogenation catalysts are used to treat hydrocarbon oils for hydrodesulfurization, hydrodenitrogenation, hydrogenation saturation and hydrocracking reactions in the presence of hydrogen. Hydrogenation catalysts are used to adsorb inorganic oxides with strong adsorption capacity such as alumina, Titanium oxide, silicon oxide, and composites of aluminum oxide and silicon oxide are used as the carrier. The group VI of the periodic table includes metals such as Mo and / or W, and metals such as Co and / or Ni of group VIII. These metals are oxides Form exists. Oxide form catalysts have low activity, and they are usually converted into corresponding metal sulfides to have high activity. Therefore, the catalyst must be pre-sulfided after it is loaded into the hydrogenation...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J37/20C10G45/04
Inventor 发明人请求不公布姓名
Owner CHINA PETROLEUM & CHEM CORP
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