Sulfurized hydrogenation catalyst, prepn. method
A hydrogenation catalyst and catalyst technology, applied in the direction of catalyst activation/preparation, physical/chemical process catalysts, chemical instruments and methods, etc., can solve problems such as uncombined
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Embodiment 1
[0019] Hydrogenation catalyst A: γ-alumina as the carrier, active metal composition: Mo content is MoO 3 The weight percentage is 23.7%, the Co content is 4.5% by weight CoO, and the P content is P 2 O 5 The percentage by weight is 3.1%. (Excluding the composition of vulcanizing agent)
[0020] The preparation process of the above-mentioned composition catalyst containing vulcanizing agent:
[0021] Take 1000 grams of γ-alumina carrier, the specific surface area of the carrier is 296m 2 / g, pore volume 0.87ml / g, make 900ml aqueous solution with 129g molybdenum trioxide, 56g cobalt carbonate, 30.6g 85% phosphoric acid and appropriate amount of water, impregnate the above-mentioned carrier, and dry the impregnated sample at 340℃ for 4 hours , The catalyst intermediate is prepared, the Mo content is MoO 3 The weight percentage is 10%, the Co content is 2% by weight CoO, and the P content is P 2 O 5 The percentage by weight is 1.5%. A mixed solvent of 91.2 grams of lactic acid and 5...
Embodiment 2
[0023] Hydrogenation catalyst B: γ-alumina as the carrier, active metal composition: Mo content is MoO 3 The weight percentage is 25.8%, the Co content is 4.9% by weight CoO, and the P content is P 2 O 5 The percentage by weight is 3.5%. (Excluding the composition of the curing agent)
[0024] The preparation process of the above-mentioned composition catalyst containing vulcanizing agent:
[0025] Take 1000 grams of γ-alumina carrier, the specific surface area of the carrier is 296m 2 / g, pore volume 0.87ml / g, use 129g molybdenum trioxide, 56g cobalt carbonate, 30.6g 85% phosphoric acid and appropriate amount of water to make 1300ml aqueous solution, impregnate the above-mentioned carrier, and dry the impregnated sample at 340℃ for 4 hours , The catalyst intermediate is prepared, the Mo content is MoO 3 8.9% by weight, Co content is 1.7% by weight based on CoO, and P content is based on P 2 O 5The percentage by weight is 1.1%. Disperse elemental sulfur powder in a solvent with ...
Embodiment 3
[0027] According to the method of Example 1, the active metal content in the catalyst intermediate was reduced to 15% by weight of the final catalyst active metal content, and the amount of elemental sulfur used was 80% of the theoretical required amount. Others, according to the method of Example 1, to obtain catalyst C .
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