Negative ion cellulose/alginate composite fiber and its preparing method

Abstract

The present invention discloses a kind of composite negative ion cellulose / alginate fiber and its preparation process. Technologically, the present invention features that viscous sodium alginate solution prepared in certain technological condition, functional finishing agent slurry of negative ion generating material and cellulose xanthate in certain weight proportion are mixed to form the spinning solution, and the through further spinning and refining steps, the composite negative ion cellulose / alginate fiber is prepared. The composite fiber consists of cellulose 76-99.6 weight portions, sodium alginate 0.02-15 weight portions and negative ion generating material 0.02-9 weight portions. The composite fiber may be used in weaving fabric with the functions of killing bacteria, protecting skin, promoting wound healing, generating negative ion, etc. and is suitable for use in medical field and in making various kinds of high grade underwear, etc.

Description

Technical field

[0001] The invention relates to man-made cellulose fibers, in particular to a negative ion cellulose / alginate composite fiber, and also relates to a preparation method of the composite fiber. Background technique

[0002] Air anion is a substance that is very beneficial to human health. Inhaling a certain concentration of anion air can regulate the function of the nervous system, promote blood circulation, improve myocardial function, enhance myocardial nutrition and cell metabolism, improve immunity and promote health. Negative ions can make people energetic, healthy and long-lived. In addition, they can also get rid of asthma, high blood pressure, neurasthenia, emphysema, coronary heart disease and other diseases. The main component of tourmaline is a silicate material with a ring structure of aluminum, sodium, iron, magnesium, and lithium characterized by boron. Tourmaline has pyroelectricity and piezoelectricity, and can effectively generate negative ions. [...

Examples

Embodiment 1

[0021] Dissolve sodium alginate with a degree of polymerization of 579 in demineralized water at a weight ratio of 1:50 at 60°C, add 0.02mol / l NaCl solution at a ratio of 0.3% relative to sodium alginate, and add a mass percentage of 1 % (Relative to sodium alginate) was added to the aloe vera gel, and after 12 hours of continuous stirring, a viscous solution with a viscosity of 10 Pa·S was obtained.

[0022] At 35°C, cotton pulp with a degree of polymerization of 600 is alkalized with 238g / l NaOH solution for 2 hours to form alkali cellulose, and aged at 30°C for 5 hours to obtain alkali cellulose with 29% cellulose. Add 46% (relative to cellulose) CS 2 React for 4 hours to obtain cellulose xanthate.

[0023] Take a quantitative tourmaline powder with an average diameter of 0.25 μm at room temperature, add 1 to 2% sodium tripolyphosphate alkali solution (mass percentage), stir and dissolve for about 4 hours, and make a 15-25% mass percentage concentration Tourmaline functional fi...

Embodiment 2

[0028] At 50 ℃, according to the weight ratio of 1:60, dissolve sodium alginate with a degree of polymerization of 548 in demineralized water, add 0.015mol / l NaCl solution at a ratio of 0.3% relative to sodium alginate, and press 0.6% (relative to Aloe vera gel was added in the ratio of sodium alginate), and after 16 hours of continuous stirring, a viscous solution with a viscosity of 9.8 Pa·S was obtained.

[0029] At 38°C, wood pulp with a degree of polymerization of 690 is alkalized with 24% NaOH solution for 3 hours to form alkali cellulose, and aged at 28°C for 4 hours to obtain alkali cellulose with 29% cellulose, and then added 46% (relative to cellulose) CS 2 After reacting for 5 hours, cellulose xanthate was obtained.

[0030] Take a quantitative tourmaline powder with an average diameter of 0.25μm at room temperature, add 1 to 2% sodium tripolyphosphate alkali solution (mass percentage), stir and dissolve for about 4 hours, and make a 15-25% mass percentage electric Ston...

Embodiment 3

[0035] At 49℃, according to the weight ratio of 1:50, dissolve sodium alginate with a degree of polymerization of 568 in demineralized water, add 0.02mol / l KCl solution at a ratio of 0.3% relative to sodium alginate, and press 0.3% ( Aloe vera gel was added in a ratio relative to sodium alginate), and after 9 hours of continuous stirring, a viscous solution with a viscosity of 10.6 Pa·S was obtained.

[0036] At 39°C, bamboo pulp with a degree of polymerization of 690 is alkalized with 24% NaOH solution for 4 hours to form alkali cellulose. After aging at 30°C for 2 hours, a 29.6% cellulose-containing alkali cellulose is obtained, and then 40 is added. % (Relative to cellulose) CS 2 After reacting for 5 hours, cellulose xanthate was obtained.

[0037] Take a quantitative tourmaline powder with an average diameter of 0.25μm at room temperature, add 1 to 2% sodium tripolyphosphate alkali solution (mass percentage), stir and dissolve for about 4 hours, and make a 15-25% mass percenta...

Technical field

[0001] The invention relates to man-made cellulose fibers, in particular to a negative ion cellulose / alginate composite fiber, and also relates to a preparation method of the composite fiber. Background technique

[0002] Air anion is a substance that is very beneficial to human health. Inhaling a certain concentration of anion air can regulate the function of the nervous system, promote blood circulation, improve myocardial function, enhance myocardial nutrition and cell metabolism, improve immunity and promote health. Negative ions can make people energetic, healthy and long-lived. In addition, they can also get rid of asthma, high blood pressure, neurasthenia, emphysema, coronary heart disease and other diseases. The main component of tourmaline is a silicate material with a ring structure of aluminum, sodium, iron, magnesium, and lithium characterized by boron. Tourmaline has pyroelectricity and piezoelectricity, and can effectively generate negative ions. [...

Examples

Embodiment 1

[0021] Dissolve sodium alginate with a degree of polymerization of 579 in demineralized water at a weight ratio of 1:50 at 60°C, add 0.02mol / l NaCl solution at a ratio of 0.3% relative to sodium alginate, and add a mass percentage of 1 % (Relative to sodium alginate) was added to the aloe vera gel, and after 12 hours of continuous stirring, a viscous solution with a viscosity of 10 Pa·S was obtained.

[0022] At 35°C, cotton pulp with a degree of polymerization of 600 is alkalized with 238g / l NaOH solution for 2 hours to form alkali cellulose, and aged at 30°C for 5 hours to obtain alkali cellulose with 29% cellulose. Add 46% (relative to cellulose) CS 2 React for 4 hours to obtain cellulose xanthate.

[0023] Take a quantitative tourmaline powder with an average diameter of 0.25 μm at room temperature, add 1 to 2% sodium tripolyphosphate alkali solution (mass percentage), stir and dissolve for about 4 hours, and make a 15-25% mass percentage concentration Tourmaline functional fi...

Embodiment 2

[0028] At 50 ℃, according to the weight ratio of 1:60, dissolve sodium alginate with a degree of polymerization of 548 in demineralized water, add 0.015mol / l NaCl solution at a ratio of 0.3% relative to sodium alginate, and press 0.6% (relative to Aloe vera gel was added in the ratio of sodium alginate), and after 16 hours of continuous stirring, a viscous solution with a viscosity of 9.8 Pa·S was obtained.

[0029] At 38°C, wood pulp with a degree of polymerization of 690 is alkalized with 24% NaOH solution for 3 hours to form alkali cellulose, and aged at 28°C for 4 hours to obtain alkali cellulose with 29% cellulose, and then added 46% (relative to cellulose) CS 2 After reacting for 5 hours, cellulose xanthate was obtained.

[0030] Take a quantitative tourmaline powder with an average diameter of 0.25μm at room temperature, add 1 to 2% sodium tripolyphosphate alkali solution (mass percentage), stir and dissolve for about 4 hours, and make a 15-25% mass percentage electric Ston...

Embodiment 3

[0035] At 49℃, according to the weight ratio of 1:50, dissolve sodium alginate with a degree of polymerization of 568 in demineralized water, add 0.02mol / l KCl solution at a ratio of 0.3% relative to sodium alginate, and press 0.3% ( Aloe vera gel was added in a ratio relative to sodium alginate), and after 9 hours of continuous stirring, a viscous solution with a viscosity of 10.6 Pa·S was obtained.

[0036] At 39°C, bamboo pulp with a degree of polymerization of 690 is alkalized with 24% NaOH solution for 4 hours to form alkali cellulose. After aging at 30°C for 2 hours, a 29.6% cellulose-containing alkali cellulose is obtained, and then 40 is added. % (Relative to cellulose) CS 2 After reacting for 5 hours, cellulose xanthate was obtained.

[0037] Take a quantitative tourmaline powder with an average diameter of 0.25μm at room temperature, add 1 to 2% sodium tripolyphosphate alkali solution (mass percentage), stir and dissolve for about 4 hours, and make a 15-25% mass percenta...