Fireproof thermosetting resin composition
A thermosetting resin and thermosetting technology, which is applied in the manufacture of electrical components, circuits, semiconductors/solid-state devices, etc., can solve the problems of inability to improve the flame retardant properties of resin compositions and reduce the addition ratio, and achieve excellent flame retardant effects And heat resistance, heat resistance improvement, flame resistance and excellent reliability
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Synthetic example 1
[0086] [Synthesis example 1] Preparation of titanium compound copolymer complex coated with resin
[0087] Put the titanium compound copolymer complex and epoxy resin or phenolic resin in the ratio of 2:1 by weight in a container, stir thoroughly with a stirrer, and then fully knead with a twin-shaft roller or a twin-shaft extruder at 95°C After that, it is cooled and pulverized to obtain the titanium compound copolymer composite coated with epoxy resin and the titanium compound copolymer composite coated with phenolic resin respectively.
[0088] [Example and Comparative Example]
Embodiment 1
[0089] Example 1 - Preparation of Thermosetting Flame Retardant Epoxy Resin Composition.
[0090] Prepare flame retardant thermosetting epoxy resin composition of the present invention according to the composition listed in Table 1:
[0091] Epoxy resin (a) 15.4 parts by weight
[0092] Hardener (a) 7.80 parts by weight
[0093] Hardening accelerator (a) 0.3 parts by weight
[0094] Titanium compound copolymer complex 5.00 parts by weight
[0095] Silane coupling agent 0.50 parts by weight
[0096] Silicon dioxide 70.00 parts by weight
[0097] Carbon black 0.40 parts by weight
[0098] Carnauba wax 0.60 parts by weight
[0099] The above ingredients are placed in a container, fully stirred by a stirrer, fully kneaded by a 95°C biaxial roller, and then cooled and pulverized to obtain an epoxy resin composition that can be used for semiconductor packaging.
Embodiment 2 to 10 and comparative example 1 to 6
[0101] According to the components and ratios shown in Table 1, the epoxy resin compositions of Examples 2-9 and Comparative Examples 1-5 and the phenolic resin compositions of Example 10 and Comparative Example 6 were prepared in the same manner as described in Example 1.
[0102] Table 1
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Example 2
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Example 3
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Example 4
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Example 5
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Example 6
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Example 7
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Example 8
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Example 9
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Example 10
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example 1
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Example 2
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Example 3
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Example 4
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Example 5
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Example 6
epoxy resin
a
-
10.8
-
10.2
15.8
15.8
15.8
-
15.8
15.8
15.8
15.8
15.8
-
epoxy resin
b
15.8-
-
-
-
-
-
- ...
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