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Method for fabricating ceramics of silicon carbide toughened by Nano bars of alumina

An alumina nanometer and manufacturing method technology, applied in the field of ceramics, can solve the problems of rising production cost, high preparation cost of silicon carbide whiskers, affecting the toughening effect of silicon carbide ceramics, and the like

Inactive Publication Date: 2007-12-26
NINGBO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The introduction of silicon carbide whiskers or carbon fibers for toughening can indeed greatly improve the toughness of silicon carbide ceramics. However, the preparation cost of silicon carbide whiskers is relatively high, which brings about an increase in the production cost of the entire toughened ceramic product. In particular, the long-term Generally speaking, silicon carbide whiskers and carbon fibers with a high diameter ratio are difficult to mix evenly with other raw materials for silicon carbide ceramics production, and uneven mixing of raw materials will obviously affect the toughening effect of finished silicon carbide ceramics; similarly, using The method of adding alumina whiskers or other oxide whiskers with a high aspect ratio to toughen silicon carbide ceramics also has the problem that the toughening material and other raw materials for silicon carbide ceramics are difficult to mix uniformly.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Embodiment 1: with the C-B sintering aid of 0.5%-3.0% (weight), and the PVA of 1.0%-5.0% (weight), and, the rod-shaped aluminum oxide nanopowder of 2.0%-12.0% (weight), and, 80.0%-96.5% (weight) of silicon carbide powder is mixed by dry ball milling, molded, cured at a temperature range of 100°C-300°C, and then sintered at a temperature range of 1700°C-2100°C for 0.5-3.0 hours to form silicon carbide ceramic products.

Embodiment 2

[0018] Embodiment 2: with the C-B sintering aid of 0.5%-3.0% (weight), and the PVA of 1.0%-5.0% (weight), and, the rod-shaped aluminum oxide nanopowder of 2.0%-12.0% (weight), and, 80.0%-96.5% (weight) of silicon carbide powder, and an appropriate amount of water, made into a slurry material, mixed by wet ball milling, dried, granulated, molded, and solidified at a temperature range of 100°C-300°C, Afterwards, sintering at a temperature range of 1700°C-2100°C for 0.5-3.0 hours to form a silicon carbide ceramic product.

Embodiment 3

[0019] Embodiment 3: with the C-B sintering aid of 0.5%-3.0% (weight), and the PVA of 1.0%-5.0% (weight), and, the rod-shaped aluminum oxide nanopowder of 2.0%-12.0% (weight), and, 80.0%-96.5% (weight) of silicon carbide powder, and an appropriate amount of water, made into a slurry material, mechanically stirred and mixed, dried, granulated, molded, solidified at a temperature range of 100°C-300°C, and then , Sintering at a temperature range of 1700°C-2100°C for 0.5-3.0 hours to form a silicon carbide ceramic product.

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PUM

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Abstract

This invention provides a method for producing SiC ceramic tougnened with Al2O3 nanorods. The SiC ceramic utilizes Al2O3 nanorods with a low aspect ratio instead of whiskers or fibers with a high aspect ratio as the toughening component. The rod-like Al2O3 nanoparticles can be uniformly mixed with other raw materials, which can realize uniform toughening. Besides, the rod-like Al2O3 nanoparticles have a low cost, which can reduce the cost of the tougnened SiC ceramic. This invention also considers such advantageous toughening effects as microcrack, crack deflection, crack bridging, pullout and grain refinement.

Description

technical field [0001] The invention relates to a method for manufacturing alumina nanorod toughened silicon carbide ceramics, which belongs to the field of ceramics. Background technique [0002] The problem of brittleness is a common problem for all kinds of ceramics, and silicon carbide ceramics are no exception; how to improve the toughness of silicon carbide ceramics is an important topic of concern in this production field. The linear elastic fracture mechanics developed in the early 1950s was first applied to metal materials, and later Davidge and Wiederhorn found that the theory was equally important for ceramic materials. Since then, people have paid attention to the concept of "microstructural defects" and tried their best to eliminate the defects caused by the process, so as to improve the mechanical properties of structural ceramics. Over the next few years, Lange and Rice observed the interplay between cracks and microstructure and produced a series of highly d...

Claims

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Application Information

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IPC IPC(8): C04B35/565C04B35/622
Inventor 李榕生宋岳水淼王霞
Owner NINGBO UNIV
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