Image forming apparatus, image forming method and process cartridge

An image and developing device technology, applied in the direction of corona discharge device, electric recording process using charge pattern, electric recording process using charge pattern, etc. Sexual variation and other issues

Active Publication Date: 2011-03-23
RICOH KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0018] However, in the method of blending a low-molecular-weight resin and a high-molecular-weight resin in the above-mentioned Japanese Patent Application Laid-Open No. 2-82267, there is a disadvantage that the presence of a high-molecular-weight component causes pulverization in the resin production process, or the use of The crushability of the binder resin in the production process of the crushed toner is deteriorated
On the other hand, in the method of using only low-molecular-weight resin, not only the offset resistance and storability are poor, but also the pulverization is too good, so there is a problem that the resin is fused during the pulverization, which worsens the productivity.
[0019] On the other hand, if the softening point of the binder resin for toner is lowered in order to improve the low-temperature fixability, it will inevitably be accompanied by a lowering of the glass transition temperature, so that the toner will be aggregated, and as a result, the storability will be deteriorated.
[0020] In addition, although the rosins used in the above-mentioned JP-A-4-70765 and JP-A-4-307557 are effective for improving low-temperature fixing properties, they also have the disadvantage of easily generating an odor depending on the type of rosin.

Method used

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  • Image forming apparatus, image forming method and process cartridge
  • Image forming apparatus, image forming method and process cartridge
  • Image forming apparatus, image forming method and process cartridge

Examples

Experimental program
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Effect test

Embodiment

[0611] Hereinafter, examples of the present invention will be described, but the present invention is not limited by the following examples.

[0612] In the following examples and comparative examples, "softening point of polyester resin", "glass transition temperature (Tg) of polyester resin", "softening point of rosin", "acid value of polyester resin and rosin" , "hydroxyl value of polyester resin", "content of low molecular weight components with a molecular weight of 500 or less", "SP value of rosin" and "degree of modification of (meth)acrylic acid of rosin" were measured by the following methods.

[0613]

[0614] Using a flow tester (manufactured by Shimadzu Corporation, CFT-500D), 1 g of each polyester-based adhesive resin as a sample was heated at a temperature increase rate of 6° C. / min, and a load of 1.96 MPa was applied from a plunger at the same time. Extrude it from a nozzle with a diameter of 1mm and a length of 1mm, make a curve of the plunger drop of...

Synthetic example 1

[0644] -Refinement of Rosin-

[0645] Add 1,000g of tall oil rosin to a 2,000mL distillation flask equipped with a fractionating tube, reflux condenser, and receiving vessel, and carry out distillation under a reduced pressure of 1kPa, collecting distilled components at 195°C to 250°C as the main fraction . Hereinafter, tall oil rosin used for purification is referred to as unrefined rosin, and rosin collected as a main fraction is referred to as refined rosin.

[0646] Using a coffee grinder (National MK-61M), each 20 g of rosin was pulverized for 5 seconds, and 0.5 g of what passed through a 1 mm sieve was metered into a vial (20 mL) for headspace. Headspace gas was sampled, and impurities in unrefined rosin and refined rosin were analyzed by headspace GC-MS in the following manner. The results are shown in Table 1A.

[0647]

[0648] A. Headspace sampler (manufactured by Agilent, HP7694)

[0649] ·Sample temperature: 200℃

[0650] ·Ring temperature: 200...

Synthetic example 2

[0680] -Synthesis of Acrylic Modified Rosin A-

[0681] 6084g (18mol) of refined rosin (SP value: 76.8°C) and 907.9g (12.6mol) of acrylic acid were added to a 10L volumetric flask equipped with a fractionation tube, a reflux condenser and a receiving vessel, and within 8 hours the temperature was reduced from Raise the temperature from 160°C to 220°C, react at 220°C for 2 hours, and then distill under a reduced pressure of 5.3kPa to obtain acrylic acid-modified rosin A. The SP value of the obtained acrylic-modified rosin A was 110.4° C., and the degree of acrylic modification was 100.

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Abstract

Provided are image forming apparatuses, image forming methods, and process cartridges using a toner that is excellent in low temperature fixing ability, hot offset resistance, and storage stability, and also generate less odor, and thus that can provide high quality images with superior fixing ability, far from tone change with time, and less likely to occur abnormal images such as density-drop and background smear. The image forming apparatuses comprise a latent electrostatic image bearing member, a charging unit, an exposing unit, a developing unit, a transfer unit, and a fixing unit, wherein the toner comprises a binder resin and a colorant, the binder resin comprises a polyester resin prepared by condensation polymerization between an alcohol component that contains an aliphatic polyvalent alcohol and a carboxylic acid component that contains (meth)acrylic acid-modified rosin.

Description

technical field [0001] The present invention relates to image forming apparatuses, image forming methods, and process cartridges of electrophotographic methods such as copiers, electrostatic printing, printers, facsimile machines, and electrostatic recording. Background technique [0002] At present, various methods are known for image formation by electrophotography. Generally, the surface of an electrostatic latent image carrier (hereinafter also referred to as "photoreceptor", "electrophotographic photoreceptor", or "image carrier") is charged, and then The surface of the charged latent electrostatic image carrier is exposed to form an electrostatic latent image. Next, the latent electrostatic image is developed with toner to form a visible image on the latent electrostatic image carrier. The visible image is transferred directly or through an intermediate transfer body to a recording medium, and then the transferred transfer image is fixed by heat, pressure, or both, th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03G15/00G03G9/09G03G9/087G03G9/08G03G15/02G03G15/08G03G15/16G03G15/20G03G13/00G03G21/18
Inventor 岩本康敬渡辺阳一郎设乐泰祯
Owner RICOH KK
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