High-fine surface material for display, high-fine display and high-fine touch screen having the same
A display, high-precision technology, applied in the direction of instruments, light guides, optics, etc., can solve the problems of reduced visibility of displayed images that cannot improve the display
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manufacture example 1
[0113] (preparation of polycyclohexyl methacrylate)
[0114] In three 300ml flasks with stirrers, 75g of methyl isobutyl ketone was added, and the temperature was raised to 70° C. under the condition of purging with nitrogen. After reaching 70° C., 25 g of cyclohexyl methacrylate and 0.81 g of a polymerization initiator PERBUTYLPV (manufactured by NOF Co., Ltd., 71% Shellsol dilution) were added dropwise in three portions each over an hour. After completion of the dropwise addition, polymerization was further carried out at 70° C. for 3 hours, then the temperature was raised to 80° C., and polymerization was continued for 3 hours. After cooling, the polymerization is terminated. Then, it was added dropwise to methanol and reprecipitated to obtain polycyclohexyl methacrylate. As a result of gel permeation chromatography (GPC) measurement, the mass average molecular weight was 26,000, and the number average molecular weight was 9,000.
Embodiment 1
[0116] (composition for forming antiglare layer)
[0117] Hexafunctional Acrylic Urethane
[0118] (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., Purple Light UV-7600B) 60 parts by mass
[0119] 10 parts by mass of trimethylolpropane triacrylate
[0120] 30 parts by mass of cyclohexyl methacrylate of Manufacturing Example 1
[0121] Cross-linked polystyrene microparticles
[0122] (manufactured by Soken Chemical Co., Ltd., SX-130H; average particle size: 1.3 μm) 3 parts by mass
[0123] 3 parts by mass of 1-hydroxycyclohexyl phenyl ketone
[0124] 150 parts by mass of methyl isobutyl ketone
[0125] The composition for forming the anti-glare layer was applied as a transparent substrate on a PET film with a thickness of 100 μm by a roll coater, and dried at 80° C. for 2 minutes so that the dry film thickness was 5 μm . Thereafter, it was cured by irradiating ultraviolet light (cumulative light intensity: 400mJ / cm2) with a 120W high-pressure mercury lamp (...
Embodiment 2
[0128] A surface material for a display was produced in the same manner as in Example 1 except that 5 parts by mass of cross-linked polystyrene was used as the composition for forming the antiglare layer. The Sm of the obtained antiglare layer was 150 μm, Ra was 0.16 μm, Rz was 1.2 μm, the 60-degree gloss value was 89%, and the haze value of the surface material for a display was 9.0%.
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