Technique for preparing hexabromocyclophosphazene trimer

A technology of hexabromocyclotripolyphosphazene and a new process is applied in the field of chemical synthesis, can solve the problems of low cost, high cost, low yield and the like, and achieves the effects of mild reaction process conditions, high success rate and high yield
CN101265276AInactive Publication Date: 2008-09-17HEBEI UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HEBEI UNIVERSITY
Publication Date
2008-09-17
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention discloses a novel process for preparing hexabromocyclotriphosphazene. The process is characterized in charging step by step and including allowing ammonium bromide, phosphorus tribromide and liquid bromine to react in chlorobenzene in the presence of high efficiency polybasic composite catalyst, and purifying the product through freeze separation. The product has a purity of greater than 98% and a yield of about 50%. Compared with the conventional method, the process has the advantages of short reaction time and high product yield.
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Description

technical field

[0001] The invention relates to a new process for preparing fine chemical intermediates, in particular to a new process for preparing hexabromocyclotrimeric phosphazene, which belongs to the field of chemical synthesis. Background technique

[0002] Phosphazene compounds are a class of linear or cyclic compounds whose skeletons are alternately arranged with phosphorus atoms and nitrogen atoms. Cyclic phosphazene compounds are a class of polycyclic ring compounds with alternating P and N atoms as the skeleton. It is an important chemical intermediate, and its structural formula is (NPR 2 )n, n=3-9, representative compounds are hexachlorocyclotrimeric phosphazene and hexabromocyclotrimeric phosphazene. Polyphosphazene compounds mainly refer to linear low-molecular or linear high polymers whose main chain is composed of alternating P and N atoms and alternating single and double bonds. The diversification of the side groups of phosphazene compounds endows the ...

Claims

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