Method for reducing sulfur content of catalytically cracked gasoline

A technology for catalytically cracking gasoline and catalytic cracking units, which is applied in the petroleum industry, hydrocarbon oil treatment, hydrotreating processes, etc., can solve the problems of limited reduction of olefin content and increased energy consumption of the unit.

Active Publication Date: 2008-10-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In this method, heavy naphtha is subjected to secondary hydrogenation, which increases the energy consumption of the device, and at the same time reduces the olefin content to a limited extent

Method used

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  • Method for reducing sulfur content of catalytically cracked gasoline
  • Method for reducing sulfur content of catalytically cracked gasoline
  • Method for reducing sulfur content of catalytically cracked gasoline

Examples

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Comparison scheme
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Embodiment 1

[0056] This embodiment adopts the technical scheme 1 of the present invention, and the raw materials and reaction conditions used in the catalytic cracking unit are the same as those of Comparative Example 1, and the fraction of catalytic cracking reaction oil gas <250 ° C is fractionated into three fractions through graded cooling, wherein the light gasoline fraction is <65°C fraction; medium gasoline fraction is 65-120°C fraction; heavy gasoline fraction is 120-250°C fraction.

[0057] The light gasoline fraction is absorbed by the catalytic cracking absorption stabilization system and then enters the alkali washing deodorization device for deodorization. The medium gasoline fraction enters the first hydrogenation reaction zone and reacts with the hydrogenation catalyst RSDS-1. The hydrogenated medium gasoline fraction enters the alkali washing deodorization device for deodorization treatment. The medium gasoline fraction and its hydrogenation product properties and the first...

Embodiment 2

[0062] This embodiment adopts the technical scheme 2 of the present invention, and the raw materials and reaction conditions used in the catalytic cracking unit are the same as those of Comparative Example 2, and the fraction <250°C at the top of the catalytic cracking main fractionation tower is fractionated into three strands through the stabilizing tower of the absorption stabilizing system Fractions, of which the light gasoline fraction is the fraction <80°C; the medium gasoline fraction is the fraction of 80-120°C; the heavy gasoline fraction is the fraction of 120-250°C.

[0063] The light gasoline fraction enters the alkali washing deodorization device for deodorization. The medium gasoline fraction enters the first hydrogenation reaction zone and reacts with the hydrogenation catalyst RSDS-1. The hydrogenated medium gasoline fraction enters the alkali washing deodorization device for deodorization treatment. The medium gasoline fraction and its hydrogenation product pro...

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Abstract

The present invention provides a method of reducing sulfur content in fcc gasoline, the fraction below 250 DEG C from the main fractionator top of the catalytic cracking unit is stepped cooled to obtain a light gasoline fraction, a middle gasoline fraction and a heavy gasoline fraction, the light gasoline fraction enters in an alkali washing sweetening unit by a absorption and stabilization system of the catalytic cracking unit; the middle gasoline fraction processes selective hydrodesulfurization in a first hydrogenation region, the obtained hydrogenation middle gasoline fraction enters in the alkali washing sweetening unit to process deodorization; the heavy gasoline fraction processes hydrodesulfurization and octane number recovery reaction in a second hydrogenation region, the hydrodesulfurization heavy gasoline fraction is mixed with the light gasoline fraction after deodorized and the hydrodesulfurization middle gasoline fraction, a clean gasoline product is obtained. The method of the invention greatly reduces the sulfur content and the alkene content in fcc gasoline, the sulfur content of the product meets the need of sulfur in Europe IV discharging standard, the device has less investment, lower energy consumption because of the simple process of fcc gasoline hydrogenation.

Description

technical field [0001] The invention belongs to a method for refining hydrocarbon oil in the presence of hydrogen, more specifically, a method for reducing the sulfur content of catalytic cracking gasoline and producing clean gasoline products with low sulfur and olefins. Background technique [0002] With the rapid development of the automobile industry, the pollution of automobile exhaust to the environment is becoming more and more serious. In order to protect the environment, countries around the world have put forward stricter restrictions on the composition of motor gasoline to reduce the emission of harmful substances in automobile exhaust. The content of sulfur and olefins in gasoline can effectively reduce the emission of harmful substances in automobile exhaust. The United States requires that the sulfur content in gasoline be reduced to below 30 μg / g in 2006, and the olefin content is less than 14% by volume. In 2005, Europe began to implement gasoline specificat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G65/04
Inventor 习远兵胡云剑屈锦华李明丰聂红
Owner CHINA PETROLEUM & CHEM CORP
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