Ion-exchange process technique of hexavalent chrome-containing waste water

An ion exchange method and treatment process technology, applied in the field of wastewater treatment technology, can solve the problems of low degree of automation, complex resin regeneration and maintenance operations, resin pollution, etc., and achieve high degree of automation, good wastewater treatment effect, and good treatment effect. Effect

Inactive Publication Date: 2009-02-04
SURFACE & INTERFACE CHEM ENG TECH RES CENT NANJING UNIV
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

Ion exchange method is one of the effective methods to treat chromium-containing wastewater. Compared with other treatment methods, it has the advantages of low treatment cost and recyclable hexavalent chromium. However, the current treatment system and process have low degree of automation, resin regeneration and maintenance operations. Complex, not suitable for large-scale wastewater treatment, especially the existence of trivalent chromium in wastewater, the serious pollution of resin has no effective solution
Therefore, the treatment of chromium-containing wastewater by ion exchange cannot be widely and large-scale applied at present.

Method used

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  • Ion-exchange process technique of hexavalent chrome-containing waste water

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Embodiment 1

[0030] The water quality of chromium-containing wastewater in an electroplating plant is shown in Table 1:

[0031] Table 1 The maximum concentration of pollutants in chromium-containing wastewater mg / L

[0032] Wastewater type

Water volume (m 3 / d)

pH

Cr 6+

Cr 3+

Cu 2+

Ni 2+

Zn 2+

CN -

Chromium-containing wastewater

100

0.5-0.7

150

30

10

8

6

5

[0033] The effluent after the process of the present invention is required to reach Cr 6+ Concentration <0.5mg / L, the specific equipment and operation are as follows:

[0034] 1. Equipment:

[0035] Chromium removal column: according to the design of three columns, the resin volume of a single column is 2m 3 , the resin is D301 / D301T, the material of the exchange column is glass fiber reinforced plastic, and the height of the resin accounts for 2 / 3 of the height of the whole column. A cyanide online monitor...

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Abstract

The invention discloses an ion exchange treatment technology of wastewater containing hexavalent chromium, the ion exchange treatment technology combines the regulation of pH value of the wastewater, the absorption, the regeneration, the maintenance and the recovery of Cr<6+> ions, thereby realizing the automatic treatment of the Cr<6+> ions in the wastewater containing the chromium; the technology of the invention has high degree of automation and good treatment effect and can be applied in the large-scale water treatment; chromium removing columns are designed to three columns or multiple columns, intermediate tanks which can regulate the pH value are arranged among various ion exchange columns, when two columns or multiple columns are connected in series for working, the pH value can be regulated during the intermediate process, thereby ensuring the wastewater treatment effect to be better and being capable of overcoming the problem that the pH is changed due to the change of the concentration of the ions during the conventional ion exchange process, thereby causing the decrease of the absorption ability of the ions by the resin; the outlet water quality can stably maintain the Cr<6+> to be less than 0.5mg/L; ion exchange resin can be effectively maintained and be stably worked for a long time; regenerated liquid can be recovered, thereby saving resources.

Description

technical field [0001] The invention relates to a wastewater treatment process, in particular to an ion exchange treatment process for wastewater containing hexavalent chromium. Background technique [0002] Wastewater containing hexavalent chromium widely exists in the fields of electroplating and metallurgical production, which not only causes the loss of resources, but also causes serious environmental pollution. Therefore, the discharge of wastewater containing hexavalent chromium is strictly controlled. Ion exchange method is one of the effective methods to treat chromium-containing wastewater. Compared with other treatment methods, it has the advantages of low treatment cost and recyclable hexavalent chromium. However, the current treatment system and process have low degree of automation, resin regeneration and maintenance operations. Complex, not suitable for large-scale wastewater treatment, especially the presence of trivalent chromium in the wastewater, the serio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/42C02F1/62C02F101/22B01J47/02B01J47/14
Inventor 郑宏
Owner SURFACE & INTERFACE CHEM ENG TECH RES CENT NANJING UNIV
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