Heavy metal polluted soil using chelant reinforced mushroom

A technology that pollutes soil and heavy metals. It is applied in the field of resources and environment. It can solve the problems that mushroom restoration is difficult to achieve the best effect, the plant growth cycle is long, and subsequent treatment is troublesome. Effect

Inactive Publication Date: 2009-07-29
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Advantages of phytoremediation: easy planting, large enrichment, heavy metals in the soil can be removed; disadvantages of phytoremediation: long plant growth cycle (1 year for herbs, 3-5 years for woody plants, seriously affecting agricultural production), troublesome follow-up treatment (incineration It is the main technology, but it pollutes the air) and the plants are not easy to rot, so that the existing phytoremediation technology actually only plays a role in enriching and concentrating heavy metal ions in the soil. After the heavy metal ions are absorbed and transported from the soil to the plant, although the soil However, the heavy metal ions have not been completely removed from the environment, and they still exist in the plants in the environment. Whether it is burned or decayed, the heavy metal ions enriched in the plants will return to the environment or soil. The role of pollution transport to other areas
For those polluting elements that are extremely difficult to move, such as Pb, Cu, and Au, without adding chelating agents to release the metals in the solid phase for absorption by mushroom hyphae, it is difficult to achieve the best effect in mushroom restoration.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] In this example, Agaricus bisporus is planted on contaminated soil containing cadmium (Cd), lead (Pb), and copper (Cu), and the chelating agent EDTA (ethylenediaminetetraacetic acid) is combined to strengthen the in-situ enrichment soil There are three heavy metal ions in cadmium (Cd), lead (Pb), and copper (Cu).

[0026] Restoration process: preparation of Agaricus bisporus culture medium → fermentation of base material → preparation of Agaricus bisporus strains → laying the fermentation base material in the soil → sowing Agaricus bisporus strains in contaminated soil → covering soil of Agaricus bisporus → in the mushroom Apply chelating agent EDTA on the soil where the mycelium grows→Agaricus bisporus grows and enriches heavy metals→Mushroom harvesting→Agaricus bisporus cells are put into biogas digesters for anaerobic digester reduction treatment→Formation of biogas enriched in heavy metals Biogas slurry and biogas residue → chemical precipitation or chelation precip...

Embodiment 2

[0050] In this example, Tricholomagiganteum Massee was planted on the polluted soil containing copper (Cu) and zinc (Zn), and the chemical chelating agent EDDS (ethylenediamine disuccinic acid) was combined to induce the enrichment of heavy metals Cu and Zn. Cultivated according to general conditions, the yield of fresh mushrooms per mu can reach 3200kg.

[0051] The cultivation process of Jinfu mushroom in this case: preparation of compost (straw raw material) → grass soaking and pre-stacking → pile fermentation → bagging and sterilization → inoculation of bacteria → removal of bags and covering with soil → application of chelating agent EDDS → fruiting after 25-30 days , Harvest. Jinfu mushroom is a high-temperature mushroom, so it is generally selected to be sown in March-May, and fruited in May-October.

[0052] In this example, the subsequent processing is the same as that in Embodiment 1.

[0053] In this example, the average Cu enrichment amount of Jinfu mushroom can...

Embodiment 3

[0055] This example is to plant Stropharlarrugoso-annulata on the polluted soil containing chromium (Cr) and lead (Pb), and at the same time combine the induction and strengthening function of small molecule organic acid citric acid to enrich the metal ion chromium in the soil (Cr) and lead (Pb). After 2-3 months of planting, the stropharia stropharia is mature, cultivated according to general conditions, and the yield of fresh mushrooms per mu is 2800kg. Harvest the stropharia and put it into the biogas digester for anaerobic reduction fermentation treatment.

[0056] The cultivation process of Stropharia stropharius in this example: preparation of compost (straw raw material) → grass soaking and pre-pile → pile-up seeding and fungus management → 30 days after sowing, cover with soil → apply chelating agent citric acid → 15-20 days after mushrooming, Harvest. Stropharia is a medium-low temperature mushroom, suitable for planting in autumn and spring.

[0057] In this exampl...

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PUM

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Abstract

The invention belongs to technology for remediating heavy metal polluted soil by chelon strengthened mushrooms in the technical field of resource and environment. The technology is to plant the mushrooms on the polluted soil and apply chelon after the mushrooms are covered with earth so as to strengthen the adsorption rate and capacity of the mushrooms to the heavy metals in the soil. The ripe mushrooms are adopted and put into a marsh gas tank for decrement treatment; marsh gas sewage and marsh gas residue are obtained after decrement; the heavy metals are precipitated from the marsh gas sewage by chemical precipitation or chelation precipitation (specifically referring to passivating the chelon); and the precipitated marsh gas sewage can be drained after being detected to reach the standard, and heavy metal precipitation and the marsh gas residue are concentratedly buried in a controllable mode. The technology takes the mushrooms as a biological concentration machine, fully utilizes the characteristics of strong capacity of enriching heavy metal ions and short growth cycle of the mushrooms, and combines the powerful function of the chelon to activate the heavy metals so as to achieve higher-efficiency remediation effect. The post-treatment adopts the methods such as the chemical precipitation, the chelation precipitation and the like to radically remove the heavy metal ions, and the annual heavy metal pollution clearance rate for a plough horizon can reach 10 to 20 percent.

Description

Technical field: [0001] The invention belongs to the technical field of resources and environment, and in particular relates to a technology for strengthening mushrooms with chelating agents to restore heavy metal-contaminated soil. Background technique: [0002] Soil is an important natural resource for human beings to survive, and it is also an important component of the human living environment. However, with the sustained and rapid development of my country's social economy, the problem of soil heavy metal pollution has become increasingly serious, including cadmium (Cd), lead (Pb), chromium (Cr), copper (Cu), zinc (Zn), mercury (Hg), arsenic ( As), nickel (Ni) and so on are more common heavy metal pollution. On average, 3.4 million tons of Cu, 5 million tons of Pb, about 15,000 tons of Hg, 15 million tons of Mn, and 1 million tons of Ni are discharged every year in the world. The massive discharge of these heavy metals seriously pollutes the environment. In my country,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09C1/10C12P5/02C12R1/645
CPCY02E50/343Y02E50/30
Inventor 徐恒陈兰辜文博戴九洲田秀丽王德胜敬小兵
Owner SICHUAN UNIV
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