Condensed pyridine compound
A compound, pyridine technology, applied in the directions of active ingredients of heterocyclic compounds, organic chemistry, pharmaceutical combinations, etc., can solve the problems of no implied compounds, no specific disclosed compounds, etc.
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preparation example 1
[0372] Using the corresponding raw materials, according to the Example 6 In the same way, prepare the following table 3 Preparation Examples 1-1 to 1-14 compound of.
preparation example 2
[0374] Using the corresponding raw materials, according to the Example 7 In the same way, prepare the following table 3 Preparation Examples 2-1 to 2-9 compound of.
preparation example 3
[0376] To a mixture of 4,5-dihydro-1H-pyrazole (350 mg) and 4-nitrophenyl chloroformate (1.10 g) in dioxane (3 mL) was added 4M NaHCO at room temperature 3 aqueous solution (3.7 mL), and stirred for 1 hour. After diluting the reaction solution with chloroform, the organic layer was separated and washed with anhydrous MgSO 4 dry. After the white solid was removed by filtration, it was concentrated under reduced pressure to obtain 4-nitrophenyl 4,5-dihydro-1H-pyrazole 1-carboxylate (1.12 g) as a white solid.
[0377] Using the corresponding raw materials, according to the Preparation example 3 In the same way, prepare the following table 3 Preparation Examples 3-1 to 3-7 compound of.
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