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Transparent highly flexible gel-like polyurethane elastomer

A polyurethane elastomer, high-elasticity technology, applied in the field of polyurethane elastomers, can solve the problem that the performance parameters cannot meet the requirements at the same time, and achieve the effect of good elasticity and better performance

Inactive Publication Date: 2010-02-10
冯建龙
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the defect that the various performance parameters of the existing transparent high-elastic polyurethane elastomers cannot meet the requirements at the same time, and to provide a mixture of polyester or polyether polyol mixtures, isocyanate prepolymers, and plasticizers. Prepared transparent and highly elastic jelly-like polyurethane elastomer

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The raw materials are the following components:

[0026] The weight ratio of component A to component B plus component C is 1.15:1, wherein the weight ratio of component B to component C is 1:0.82, and component A is a mixture of polyester or polyether polyols. B is isocyanate prepolymer and component C is filler.

[0027] The polyester or polyether polyol mixture contains the following components by weight: (in kilograms) polyester polyol 55, polymer polyol 38, and functional polyol 7.

[0028] The isocyanate prepolymer contains the following components by weight (unit kilogram)

[0029] Diphenylmethane diisocyanate 38, polyester polyol 24, 1-6 hexane diisocyanate 38.

[0030] The filler contains the following components by weight (unit kilogram)

[0031] Dimethoxyethyl phthalate (DMEP, plasticizer, or KC988) 25, auxiliary component (dioctyl phthalate, namely DOP, or diisodecanoate phthalate, namely DIDP ) 75.

[0032] The preparation method of the present invention is:

[0033] ...

Embodiment 2

[0039] The raw materials are the following components:

[0040] The weight ratio of component A to component B plus component C is 1.18:1, and the weight ratio of component B to component C is 1:0.85. Component A is a mixture of polyester or polyether polyols, component B is isocyanate prepolymer, and component C is filler.

[0041] The polyester or polyether polyol mixture contains the following components by weight: (in kilograms) polyester polyol 60, polymer polyol 30, and functional polyol 10.

[0042] The isocyanate prepolymer contains the following components by weight (in kilograms):

[0043] Diphenylmethane diisocyanate 28, polyester polyol 30, 1-6 hexane diisocyanate 42;

[0044] The filler contains the following components by weight (unit kilogram):

[0045] Dimethoxyethyl phthalate (DMEP, plasticizer, or KC988) 100

[0046] The preparation method of Example 2 is the same as that of Example 1.

Embodiment 3

[0048] The raw materials are the following components:

[0049] The weight ratio of component A to component B plus component C is 1.2:1, and the weight ratio of component B to component C is 1:0.8. Component A is a mixture of polyester or polyether polyols, component B is isocyanate prepolymer, and component C is filler.

[0050] The polyester or polyether polyol mixture contains the following components by weight (in kilograms):

[0051] Polyester polyol 55, polymer polyol 32, functional polyol 13

[0052] The isocyanate prepolymer contains the following components by weight (in kilograms):

[0053] Diphenylmethane diisocyanate 40, polyester polyol 23, 1-6 hexane diisocyanate 37,

[0054] The filler contains the following components by weight (in kilograms):

[0055] Dimethoxyethyl phthalate (DMEP, plasticizer, or KC988) 36, auxiliary components (dioctyl phthalate, namely DOP, or diisodecanoate phthalate, namely DIDP )64.

[0056] The preparation method of Example 3 is the same as that...

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PUM

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Abstract

The invention relates to the technical field of elastomer technology, in particular to a transparent highly flexible gel-like polyurethane elastomer (EPU). The elastomer is prepared by a component A,a component B and a component C, wherein the component A is polyester or a polyether glycol mixture, the polyether glycol mixture contains at least polyether glycol, polyol and functional polyol, thecomponent B is isocyanate prepolymer containing at least diphenylmethane diisocyanate, polyester polyol, 1,6-cyclohexane diisocyanate, the component C is filler containing plasticizer, the weight ratio of the component A to the sum of the component B and the component C is 1.15-1.2:1 and the weight ratio of the component B to the component C is 1:0.8-0.85. The beneficial effect of the invention isthat all the performance parameters of the obtained polyurethane elastomer can meet the demand simultaneously, the performance is excellent, the elasticity is good, and the product is environmentallyfriendly and corresponds to the demand of industrial production.

Description

Technical field: [0001] The invention relates to the technical field of elastomers, in particular to a polyurethane elastomer (referred to as EPU). Background technique: [0002] At present, in the existing technology, the performance of transparent and highly elastic polyurethane elastomer (PU) has the following key technical items: product hydrolysis resistance, high tensile strength, high tear strength, product environmental protection, non-toxicity, etc. Can not meet the requirements at the same time (see attached table 1), can not produce practical products under the conditions of real industrialization. [0003] Schedule 1 [0004] Detection method Test items Testing Machine Standard ATXY-WJ-006 Penetration firmness Sweat resistance testing machine GT-7023 5 ATXY-WJ-032 Yellowing resistance test Yellowing resistance testing machine GT-7035-UA Level 3-4 ATXY-WJ-001 Material identification PU ATXY-WJ-032 Color change after hydrolysis Standard ligh...

Claims

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Application Information

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IPC IPC(8): C08G18/76C08G18/73C08G18/66C08G18/42C08G18/48C08K5/12
Inventor 冯建龙
Owner 冯建龙
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