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Printable hot stamping layer and preparation method thereof

A technology of hot stamping layer and anodized aluminum, applied in printing, printing device and other directions, can solve the problems of low surface tension of hot stamping layer, difficult to print, etc., and achieve good printing effect.

Active Publication Date: 2010-06-02
莫国平 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ordinary anodized aluminum hot stamping film uses a wax-based release agent, so the surface tension of the hot stamping layer is too small and it is difficult to print

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The polymer material of the printable anodized aluminum hot stamping layer according to the present invention has the following components, prepared according to the following weight ratio: 15 parts of modified polyurethane resin, 3 parts of furfural polyketone resin, 10 parts of thermoplastic acrylic resin, cellulose nitrate 1 part, 2 parts of cellulose resin, 1 part of polyvinyl butyral, 30 parts of butanone, 5 parts of ethyl acetate, 5 parts of n-propyl ester, 1 part of reaction initiator, and 0.5 part of reaction terminator.

[0029] Said modified polyurethane resin is selected from acrylic modified polyurethane resin and epoxy resin modified polyurethane resin.

[0030] Said thermoplastic acrylic resin can be selected Rohm and Haas thermoplastic acrylic resin A-11, B66.

[0031] The preparation method of the polymer material of the described printable hot stamping layer of anodized aluminum, the method is:

[0032] 1) Put all the solvents into the reaction kettle ...

Embodiment 2

[0038] The polymer material of the printable anodized aluminum hot stamping layer according to the present invention has the following components, prepared according to the following weight ratio: 25 parts of modified polyurethane resin, 10 parts of furfural polyketone resin, 20 parts of thermoplastic acrylic resin, cellulose nitrate 12 parts, 5 parts of cellulose resin, 10 parts of polyvinyl butyral, 60 parts of butanone, 10 parts of ethyl acetate, 10 parts of n-propyl ester, 2 parts of reaction initiator, and 1 part of reaction terminator.

[0039] Said modified polyurethane resin is selected from acrylic modified polyurethane resin.

[0040] Said thermoplastic acrylic resin can be selected Rohm and Haas thermoplastic acrylic resin, B-67, B-72.

[0041] Said cellulose resin is selected from cellulose acetate butyrate.

[0042] The preparation method of the polymer material of the described printable hot stamping layer of anodized aluminum, the method is:

[0043] 1) Put al...

Embodiment 3

[0049] The following polymer materials of the printable anodized aluminum hot stamping layer according to the present invention are prepared according to the following weight ratio: 20 parts of modified polyurethane resin, 7 parts of furfural polyketone resin, 15 parts of thermoplastic acrylic resin, cellulose nitrate 6 parts, 3 parts of cellulose resin, 5 parts of polyvinyl butyral, 50 parts of butanone, 7 parts of ethyl acetate, 8 parts of n-propyl ester, 1.5 parts of reaction initiator, and 0.6 part of reaction terminator.

[0050] Said modified polyurethane resin is selected from acrylic modified polyurethane resin and unsaturated polyester resin modified polyurethane resin.

[0051] Said thermoplastic acrylic resin can be selected Rohm and Haas thermoplastic acrylic resin A-11B-82.

[0052] Said cellulose resin is selected from cellulose acetate, cellulose acetate propionate, and cellulose acetate butyrate.

[0053] The preparation method of the polymer material of the d...

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PUM

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Abstract

The invention relates to a printable hot stamping layer and a preparation method thereof, and the printable hot stamping layer adopts the following components and is prepared according to the following parts by weight: 15-25 parts of modified polyurethane resin, 3-10 parts of furfural polyketone resin, 10-20 parts of thermoplastic acrylic resin, 1-12 parts of cellulose nitrate, 2-5 parts of cellulose resin, 0-10 parts of polyvinyl butyral, 30-60 parts of butanone, 5-10 parts of ethyl acetate, 5-10 parts of n-propyl ester, 1-2 parts of reaction initiator and 0.5-1 part of reaction terminator. The method comprises the following steps: 1) firstly pouring all solvents into a reaction kettle according to the requirements of the formula, heating to 50-80 DEG C and stirring; 2) keeping stirring, sequentially pouring polyurethane resin, furfural polyketone resin, modified acrylic resin, cellulose nitrate, cellulose resin and polyvinyl butyral into the reaction kettle, dripping the reaction initiator into the reaction kettle within 1 hour, and continuously stirring for 2.0-3.0 hours; 3) detecting the infrared spectrum and adding the reaction terminator; 4) measuring the solid content, and adjusting to the theoretical value; and 5) slowly stirring and cooling to 20 DEG C. The printable hot stamping layer is characterized by good printing effect after hot stamping, environmental protection and the like.

Description

technical field [0001] The invention relates to a printable anodized aluminum hot stamping layer and a preparation method thereof. The anodized aluminum hot stamping layer is a special polymer material, in particular to a polymer of a printable anodized aluminum hot stamping layer for packaging anti-counterfeiting Materials and preparation methods. Background technique [0002] Nowadays, the printing industry has higher and higher requirements on the appearance of printed products, and post-iron printing is a top technology, and the substrates used have specific requirements. Ordinary anodized aluminum hot stamping film uses a wax-based release agent, so the surface tension of the hot stamping layer is too small, making it difficult to print. The use of printable anodized aluminum hot stamping layer polymer materials to produce anodized aluminum hot stamping film does not require the use of wax-based release agents, and the surface tension of the hot stamping layer of the p...

Claims

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Application Information

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IPC IPC(8): C08L75/04C08L75/14C08L33/00C08L1/18C08L1/14C08L29/14B41M1/28
Inventor 莫国平陈建华周晋
Owner 莫国平
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