Selective bioleaching process of high-sulphur/copper ratio secondary copper sulphide ore
A copper sulfide ore and biological leaching technology, applied in the direction of improving process efficiency, can solve problems affecting extraction, electrowinning efficiency, high S/Cu ratio of ore, low alkaline gangue content, etc., and achieve short process flow, The effect of high recovery rate and simple equipment
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[0028] The new process is applied to a low-grade secondary copper sulfide ore in China. The copper metal minerals in the ore are mainly copper blue and chalcocite, and other main minerals are alunite (5.0-6.0%), pyrite (4.0-4.5%) ), followed by limonite (0.2-0.3%), and the gangue minerals are mainly quartz.
[0029] In 90ml of Leather medium, inoculate 10ml of the acidic pit water sample collected from the mine, and cultivate in a constant temperature water bath in a shaker, with the temperature controlled at 30°C. The rotation speed of the shaker was controlled at 160 rpm, and the oxidation-reduction potential, pH value and cell density in the liquid phase were regularly measured. Add 3.0mol / L H 2 SO 4 , keep the pH of the culture solution around 1.5, and the added nutrients are: (NH 4 ) 2 SO4 0.3g, KH 2 PO 4 3~4g, CaCl 2 (anhydrous) [anhydrous] 0.25g, MgSO 4 ·7H 2 O0.5g, FeSO 4 ·7H 2 O 0.001g; then add ore powder with particle size less than 0.074mm, the slurry c...
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