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38results about How to "Improve the level of comprehensive recycling" patented technology

Comprehensive recovery method for platinum and palladium in silver anode slime

The invention discloses a comprehensive recovery method for platinum and palladium in silver anode slime. The method comprises the steps that the silver anode slime generated through silver electrolysis is subjected to nitric acid leaching in a reaction still for silver separating; the leaching conditions comprise that the mass concentration of a nitric acid solution is 30-40%, the liquid-solid ratio is 3-8:1, the temperature is 40-80 DEG C, and the time is 2-6 h; filtration is conducted after leaching, and silver separating solution and leaching residues are obtained; hydrochloric acid or sodium chloride is added into the silver separating solution for silver sedimentation, the reaction endpoint is reached when no white sediment exists, and silver chloride sediments and a silver sedimentation solution are obtained after filtration; a sedimentation agent is added into the silver sedimentation solution, platinum and palladium in the solution and a small amount of silver, lead, bismuth and copper are precipitated and recycled, and platinum and palladium concentrates and a platinum and palladium sedimentation solution are obtained after filtration. The leaching residues are chloridized for gold separating, a gold separating solution and gold separating slags are obtained, the gold separating solution is subjected to bismuth removal, a gold stock solution and bismuth sedimentation slags are obtained, and gold powder, a gold sedimentation solution and valuable metal such as associated silver, associated lead, associated bismuth and associated copper are further obtained. According to the method, the platinum and palladium in the silver anode slime can be recycled effectively through the sedimentation agent under the ambient temperature condition, and the platinum and palladium concentrates are obtained; meanwhile, the valuable metal such as associated gold, associated silver, associated lead, associated bismuth and associated copper are enriched and recycled, the comprehensive recycling of resources is achieved, the recycling level of the resources is improved, and the economic benefits are remarkable.
Owner:YUNNAN TIN

Process for using specific desulphurization mixed bacterium for high sulfur coal mine biological desulfurization

ActiveCN104745497AEfficient removalSolve the problem of low removal efficiencyBacteriaMicroorganism based processesGas compositionSulfur
A process for using specific desulphurization mixed bacterium for high sulfur coal mine biological desulfurization is as follows: ore is crushed to-25mm for heap construction, the heap height is 8-10m, temperature and gas composition induction devices are embedded during heap construction; then spray operation is performed, the spraying intensity is 10-15L / (M<2>.H), the spray solution contains 107-108cfu / mL of specific desulphurization mixed bacterium CGMCC NO.8336, the oxidation reduction potential of the spray solution is more than 700mV (SCE), the spray operation is performed according to the mode of spraying for 7 days and resting for 5 days or spraying for 7 days and resting for 7 days, the in-heap temperature is controlled at 45 to 60 DEG C, and the leaching system pH value is 1.5 to 1.8. The process has the advantages of short process, simple equipment, small investment, low cost, no pollution, larger or smaller production scale, and capability of processing high sulfur coal mine resources which cannot be processed by traditional mineral processing and metallurgical technology, and can expand the resource utilization scope and improve the comprehensive recovery level of the coal mine resources.
Owner:有研资源环境技术研究院(北京)有限公司

High-arsenic high-carbon micro-fine particle refractory gold ore biological gold extraction technology and microorganism used in technology

The invention provides a microorganism used in high-arsenic high-carbon micro-fine particle refractory gold ore biological gold extraction technology, and the technology utilizing the microorganism to extract gold from high-arsenic high-carbon micro-fine particle refractory gold ore. The method comprises the following steps: after grinding and size mixing ore, adding the microorganism, and performing air agitation for pre-oxidation, wherein the period of pre-oxidation is 5 to 7 days; performing solid-liquid separation on the pre-oxidized ore pulp, adding lime into a supernatant liquor for neutralization, then decreasing arsenic in the neutralized supernatant liquor, and reusing the liquor for ore mixing; adding water into a bottom liquor to regulate the concentration of the ore pulp, and adding lime into the liquor to keep the pH within 11 and 12; and finally, extracting gold by adding sodium cyanide into the liquor with the pH ranging from 11 to 12, so as to obtain a gold-containing valuable liquor. The technology provided by the invention can fully utilizes the low-grade multiple refractory gold ore, improves the comprehensive utilization level of an ore mine, saves the cost, improves the profit, and facilitates development of low carbon economy of the metallurgical industry. The technology and the microorganism are particularly suitable for being applied to development of high-arsenic high-carbon Carlin-type gold deposits in golden triangle areas in Yunnan Province, Guizhou Province and Guangxi Province of China.
Owner:有研资源环境技术研究院(北京)有限公司

Recycling method for mineral processing waste water with high leaching residue content in zinc hydrometallurgy

The invention discloses a recycling method for mineral processing waste water with high leaching residue content in zinc hydrometallurgy. In the recycling method, a P204 extract phase is used to extract zinc-bearing solution; waste electrolyte in a zinc-metallurgical electrolysis system is used to reextract a P204 organic extraction phase to allow zinc in the P204 organic extraction phase to enter the waste electrolyte; and reextraction solution returns to a zinc hydrometallurgy leaching system after deoiling. In the recycling method, zinc sulphide concentrate is added to the mineral processing waste water with mineral processing reagent content exceeding 200mg/L after filtration treatment to be mixed for primary adsorption; and the zinc sulphide concentrate can effectively absorb aerofloat in the mineral processing waste water and remove excessive mineral processing reagent from the mineral processing waste water. The zinc recycled by the recycle method can be conveniently applied to the existing facility; the reextraction solution can directly return to the zinc hydrometallurgy leaching system after the deoiling; the process produces no pollution; the recyclable zinc metallicity can be increased; and better economic benefit is achieved.
Owner:CHIFENG ZHONGSE ZINC IND CO LTD +2

Method for preparing ammonium tetramolybdate by treating molybdenum-rich wastewater and waste slag

The invention discloses a method for preparing ammonium tetramolybdate by treating molybdenum-rich wastewater and waste slag, which comprises the following steps: 1. washing a molybdenum roasted product with water, concentrating wastewater, and uniformly mixing with an acid precipitation crystal mother solution in an ammonium molybdate production process, thereby obtaining a mixed solution; 2. adding a molybdenum roasted product into water-washed molybdenum roasted product ammonia leaching waste slag, adding into the mixed solution, regulating the pH value, magnetizing, and stirring to react to obtain a solid-liquid mixed slurry; 3. carrying out solid-liquid separation, and carrying out ammonia leaching on the filter cake; 4. carrying out solid-liquid separation to obtain an ammonia leaching solution and ammonia leaching slag; 5. carrying out ammonia leaching on the ammonia leaching slag; and 6. removing impurities from the ammonia leaching solution, purifying, carrying out acid precipitation, and filtering to obtain the solid ammonium tetramolybdate. The molybdenum roasted product-doped molybdenum roasted product ammonia leaching waste slag is added into the wastewater and acid precipitation mother solution, and liquid-phase magnetization is carried out to efficiently utilize the molybdenum resources in the wastewater and waste slag, thereby greatly lowering the treatment cost for molybdenum-containing waste slag and wastewater, being energy-saving and environment-friendly, and effectively enhancing the molybdenum resource utilization ratio in molybdenum roasted product water-washing concentrated wastewater and ammonia leaching waste slag.
Owner:JINDUICHENG MOLYBDENUM CO LTD

Fertilizer-pesticide double-effect double-chelated multi-element multi-functional medical stone liquid fertilizer and preparation method thereof

The invention discloses a fertilizer-pesticide double-effect double-chelated multi-element multi-functional medical stone liquid fertilizer and a preparation method thereof. The liquid fertilizer is prepared by compounding and mixing raw powder of medical stones, soluble silicon, limestone, compound amino acid, ammonium phosphate, urea, potassium oxide, magnesium sulfate, ferrous sulfate, manganese sulfate, copper sulfate, boracic acid, zinc sulfate, ammonium molybdate, selenium powder, poly(potassium aspartate) and the like, a botanical pesticide composition agent prepared from ricin, veratrine, herba asari volatile oil, rotenone, clausena dunniana essential oil, coptis chinensis alkaloid and glycyrrhizic acid, an amino-oligosaccharin bacteriostatic agent, gibberellin, alum, DA-6, EDTA, hydrochloric acid, ethyl alcohol and the like. The preparation method of the liquid fertilizer comprises the steps that the raw materials are mixed and compounded to generate a hot-melting reaction with aqueous diluted hydrochloric acid, the materials and urea are added with water, mixed dissolving is conducted by increasing the temperature to 100 DEG C, then the reactants and the botanical pesticide composition agent are diluted, mixed, compounded and foamed to be mixed with synergistic liquid, the materials are heated until the temperature is 80 DEG C to 120 DEG C and dissolved and mixed, solid-liquid separation is conducted to remove residues, the obtained liquid is delivered into the reaction kettle to be subjected to secondary chelation with EDTA and DA-6, and then the high-concentration suspension type liquid fertilizer is prepared in a mixed mode.
Owner:QIQIHAER JINDINGFENG MEDICAL STONE FERTILIZER IND CO LTD

Thermal management system of large-scale hydrogen production equipment

The invention belongs to the technical field of chemical hydrogen production, and particularly discloses a thermal management system of large-scale hydrogen production equipment. The system comprisesa water tank, wherein a heat exchange tube is arranged at the bottom in the water tank, one end of the heat exchange tube communicates with an outlet of a waste liquid device, the other end of the heat exchange tube communicates with an inlet of a water collector, an inlet of the waste liquid device is connected with a reactor, and an outlet of the water collector is connected with a dryer; a circulating water pump and a radiator are further arranged outside the water tank, and the circulating water pump is used for pumping water in the water tank into the radiator for heat dissipation and returning the water to the water tank; and the heat exchange tube is a multi-pass U-shaped tube, a coil tube or a plurality of heat exchange calandria tubes. According to the system, heat generated by hydrogen production is used for supplying heat to low-temperature water, the heat exchange effect is good, power consumption is effectively saved, and liquid water supply required by a chemical hydrogenproduction reaction in a field low-temperature environment below 0 DEG C can be maintained; the long-term stability of the heat exchange effect can be ensured; and the regional water temperature difference can be reduced, and the influence on the hydrogen production reaction is avoided.
Owner:浙江高成绿能科技有限公司

Method for preparing ammonium tetramolybdate by treating molybdenum-rich wastewater and waste slag

The invention discloses a method for preparing ammonium tetramolybdate by treating molybdenum-rich wastewater and waste slag, which comprises the following steps: 1. washing a molybdenum roasted product with water, concentrating wastewater, and uniformly mixing with an acid precipitation crystal mother solution in an ammonium molybdate production process, thereby obtaining a mixed solution; 2. adding a molybdenum roasted product into water-washed molybdenum roasted product ammonia leaching waste slag, adding into the mixed solution, regulating the pH value, magnetizing, and stirring to react to obtain a solid-liquid mixed slurry; 3. carrying out solid-liquid separation, and carrying out ammonia leaching on the filter cake; 4. carrying out solid-liquid separation to obtain an ammonia leaching solution and ammonia leaching slag; 5. carrying out ammonia leaching on the ammonia leaching slag; and 6. removing impurities from the ammonia leaching solution, purifying, carrying out acid precipitation, and filtering to obtain the solid ammonium tetramolybdate. The molybdenum roasted product-doped molybdenum roasted product ammonia leaching waste slag is added into the wastewater and acid precipitation mother solution, and liquid-phase magnetization is carried out to efficiently utilize the molybdenum resources in the wastewater and waste slag, thereby greatly lowering the treatment cost for molybdenum-containing waste slag and wastewater, being energy-saving and environment-friendly, and effectively enhancing the molybdenum resource utilization ratio in molybdenum roasted product water-washing concentrated wastewater and ammonia leaching waste slag.
Owner:JINDUICHENG MOLYBDENUM CO LTD
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