The invention belongs to the technical field of
sodium ion battery negative
electrode materials, and discloses a soy sauce residue-based hard carbon negative
electrode material, a preparation method and an application of the soy sauce residue-based hard carbon negative
electrode material in a
sodium ion battery. The method comprises the steps of pre-oxidation, inorganic
acid washing,
organic solvent cleaning and high-temperature
carbonization, the core technology idea of pre-oxidation driven synergistic purification is initiated, the core technology idea is organically combined with the subsequent high-temperature
carbonization process, the pretreatment
bottleneck of industrialization of preparation of hard carbon from soy sauce residues is overcome, and the method is suitable for industrial production. The high-
grease soy sauce residues are efficiently and economically purified through pre-oxidation, and a primary barrier is cleared for preparing hard carbon by utilizing the soy sauce residues on a large scale; the precise reconstruction of the
microstructure of the hard carbon material is synchronously realized, and the obtained hard carbon material has high reversible specific capacity and good initial coulombic efficiency; a high-performance product can be obtained at a relatively low
carbonization temperature due to the pure precursor, so that the
energy consumption and the production cost are reduced. The invention provides a scheme for preparing the
sodium ion battery hard carbon negative electrode with low cost and high performance.