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Production method of low-phosphorous ferrovanadium

A production method, phosphorus and vanadium technology, applied in the field of metallurgy, can solve problems such as no major breakthroughs

Inactive Publication Date: 2010-10-20
郸城财鑫特种金属有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Metallurgists at home and abroad have done a lot of work on the development of phosphorus reduction by ferrovanadium, but there is no great breakthrough
For example, Li Min used calcium-silicon alloy to reduce phosphorus in smelting, but it can only reach about 0.07% (Li Min, The dephosphorization practice of calcium-silicon in ferrovanadium smelting, Sichuan Metallurgy, 1993, the fourth issue)

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] (1) First-stage reduction: mix 220 parts by weight of steel shavings, 80 parts by weight of ferrosilicon, 60 parts by weight of vanadium pentoxide and 250 parts by weight of white ash, and then add them to the furnace. The voltage is adjusted to 175V and the current is 2650A. After the physical and chemical materials are cleared, adjust the alkalinity of the slag to 2.5. If the alkalinity is low, add an appropriate amount of white ash, if the alkalinity is high, add slag to reduce the alkalinity of the material. Adjust the temperature to 1600 degrees, then add 60 parts by weight of ferrosilicon to reduce, take the sticky slag sample to observe, when the slag color is light yellow, the reaction is sufficient, then add 12 parts by weight of aluminum block to reduce, reduce to low vanadium pentoxide content in the lean slag Pour out the lean residue at 0.5%.

[0016] (2) Second-stage reduction: add 160 parts by weight of vanadium pentoxide and 320 parts by weight of white ash...

Embodiment 2

[0021] (1) First-stage reduction: weigh 110 parts by weight of steel shavings, 46 parts by weight of ferrosilicon, 40 parts by weight of vanadium pentoxide and 145 parts by weight of white ash, and then add them into the furnace. The voltage is adjusted to 165V and the current It is 2550A. After the material is cleared, adjust the slag alkalinity to 2.0. If the alkalinity is low, add an appropriate amount of white ash, if the alkalinity is high, add slag to reduce the alkalinity of the material. Adjust the temperature to 1550 degrees, then add 34 parts by weight of ferrosilicon to reduce, take the sticky slag sample to observe, when the slag color is light yellow, the reaction is full, add 7 parts by weight of aluminum block to reduce, reduce to the vanadium pentoxide content in the lean slag Pour out lean residue at 0.5%;

[0022] (2) Second-stage reduction: add 96 parts by weight of vanadium pentoxide and 190 parts by weight of white ash into the furnace, adjust the voltage to ...

Embodiment 3

[0028] (1) First-stage reduction: weigh 59 parts by weight of steel shavings, 59 parts by weight of ferrosilicon, 50 parts by weight of vanadium pentoxide and 186 parts by weight of white ash, and then add them into the furnace. The voltage is adjusted to 170V and the current After the material is cleared, adjust the basicity of the slag to 2.3 and the temperature to 1585 degrees, and then add 42 parts by weight of ferrosilicon for reduction. After the reaction is complete, add 9 parts by weight of aluminum block to reduce and reduce to the lean slag pentoxide When the vanadium content is less than 0.5%, the lean slag is poured;

[0029] (2) Second-stage reduction: add 112 parts by weight of vanadium pentoxide and 248 parts by weight of white ash into the furnace, adjust the voltage to 170V, and the current to 2600A. After the materials are cleared, adjust the slag basicity to 2.3 and the temperature to 1590 degrees. , Then add 59 parts by weight of ferrosilicon to reduce, after ...

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PUM

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Abstract

The invention relates to a production method of low-phosphorous ferrovanadium. A ferrovanadium product is obtained through reduction and refining in a basic electric arc, with vanadium pentoxide as a raw material and ferrosilicon and aluminum as reducing agents. In the production method, the materials are added into a steel-making arc furnace through five batches, four batches for reduction and one batch for refining. During the reduction, the slag basicity is adjusted to be 2.0-2.5, and the temperature is 1550-1660 DEG C. The impurity content of the low-phosphorous ferrovanadium produced in the method is far lower than national standards for FeV50. Therefore, the low-phosphorous ferrovanadium produced in the method is more suitable for production of fine and extra-fine steel.

Description

Technical field [0001] The invention belongs to the field of metallurgy, and particularly relates to a production method of low-phosphorus ferro-vanadium. technical background [0002] Vanadium is an essential raw material for high-strength, low-alloy steel, microalloyed steel and other special steels. Vanadium can improve the strength, toughness, wear resistance and impact load resistance of steel. FeV50 has been used in steelmaking for many years in the steel industry, but the phosphorus content of the product is the biggest problem affecting the quality of steel. The phosphorus content of its products will all enter the steel, and the high phosphorus content of steel will cause cold brittleness. Therefore, the phosphorus content of ferrovanadium must be controlled first. Raising product grades and effectively improving steel quality are of great strategic significance. [0003] Metallurgical workers at home and abroad have done a lot of work on the development of phosphorus r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B4/06C22B5/04
CPCY02P10/20
Inventor 仵树仁李霄峰叶新友胡永熙周钦堂朱瑞青徐其民李富强
Owner 郸城财鑫特种金属有限责任公司