Thermosensitive CTP thermal-induction imaging liquid taking active etherate of pyrogallol and divinylbenzene polycondensate resin as dissolution inhibitor

A technology of divinylbenzene polycondensation resin and pyrogallol, which is applied in the field of thermal CTP thermal imaging fluids, can solve the problems of poor film-forming properties of products, weak solubility-inhibiting properties of developing solutions, and small molecular weight, etc. The effect of developing and imaging performance, high sensitivity and high printing durability

Inactive Publication Date: 2010-12-29
TAIXING CITY ORIENT IND +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention provides all small molecular compound compounds as the retarding solvent. The disadvantage is that the molecular weight is too small, the film-forming performance of the product is not good, and the solvent retarding performance in the developer is also weak.

Method used

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  • Thermosensitive CTP thermal-induction imaging liquid taking active etherate of pyrogallol and divinylbenzene polycondensate resin as dissolution inhibitor
  • Thermosensitive CTP thermal-induction imaging liquid taking active etherate of pyrogallol and divinylbenzene polycondensate resin as dissolution inhibitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Take 0.3g of Japanese NK-2014 infrared absorbing dye, 0.27g of basic brilliant blue, 0.03g of crystal violet, and the acid generator is 1-p-methoxynaphthyl-3,5-bistrichloromethyl triazine, that is, Beijing Normal University 0.2g of S-triazine and 0.2g of barbituric acid produced by University Experimental Chemical Factory, 8.09g of BX-20 phenolic resin produced by Benxi Ruishida Chemical Co., Ltd.; 0.9g of the active etherified product of benzene polycondensation resin, wherein n is 8-12, and R is a methyl group; 113g of ethylene glycol monoethyl ether;

[0026] First, dissolve the infrared absorbing dye NK-2014, basic brilliant blue and crystal violet in ethylene glycol monoethyl ether, and then add phenolic resin and other components after they are completely dissolved. The filter element with a pore size of μm is subjected to three-stage filtration to obtain a heat-sensitive CTP thermal imaging liquid CTP-1.

Embodiment 2

[0028] Take 0.1 g of benzindocyanine dye, 0.4 g of basic brilliant blue, and the acid generator is 1-p-methoxynaphthyl-3,5-bistrichloromethyl triazine, which is produced by Beijing Normal University Experimental Chemical Factory. -triazine 0.2g, barbituric acid 0.2g, Shandong Weihai Economic and Technological Development Zone Tiancheng Chemical Company BTB-225 phenolic resin 4.85g, BTB-15 phenolic resin 3.24g; 0.8g of active etherified product of vinylbenzene polycondensation resin, wherein n is 8-12, R is ethyl; methyl ethyl ketone 50g;

[0029] Firstly, dissolve the infrared absorbing dye benzindocyanine dye and basic brilliant blue in methyl ethyl ketone, after completely dissolving, add phenolic resin and other components, and then use 8μm, 5μm, and 0.5μm filter elements for three-stage Filtrate to prepare thermosensitive CTP thermal imaging liquid CTP-2.

Embodiment 3

[0031] Get 0.3g of PS-102 infrared absorbing dye from Nippon Kayaku Corporation, 0.3g of crystal violet, 0.2g of tribromomethylphenylsulfone as the acid generator, 0.3g of 1,3-dimethylbarbituric acid, Weihai Economic 8.19g of BTB-26 phenolic resin of Tiancheng Chemical Company in Technology Development Zone; 0.32g of active ether compound of pyrogallol and divinylbenzene polycondensation resin with the structure of general formula II, where n is 8-12 and R is isobutyl ;Ethylene glycol monoethyl ether 64g, methyl ethyl ketone 49g;

[0032] First, dissolve the infrared absorbing dye Nippon Kayaku PS-102 and crystal violet in a mixed solvent of ethylene glycol monoethyl ether and methyl ethyl ketone. After completely dissolving, add phenolic resin and other components. , and a filter element with a pore size of 0.5 μm for three-stage filtration to obtain a thermosensitive CTP thermal imaging liquid CTP-3.

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Abstract

The invention discloses thermosensitive CTP thermal-induction imaging liquid taking an active etherate of a pyrogallol and divinylbenzene polycondensate resin as a dissolution inhibitor, belonging to the applied technology field of an optical information recording material. The imaging liquid comprises the following components: film-forming resin, dissolution inhibitor, infrared dye, coloring background dye, photoacid generator, an additive and solvent. The dissolution inhibitor is the active etherate of the pyrogallol and divinylbenzene polycondensate resin, and the dissolution inhibitor can decompose and release an alkali soluble group, namely phenolic hydroxyl under action of protonic acid generated in an exposed area so as to form great dissolution difference between the exposed area and a non-exposed area, thus enhancing developing and imaging performances of a plate. The dissolution inhibitor can obviously enhance sensitivity and ageing resistance of the thermosensitive CTP plate, improve development latitude of the thermosensitive CTP plate, and strengthen comprehensive imaging performance of the thermosensitive CTP plate.

Description

technical field [0001] The invention belongs to the technical field of application of information recording materials, and in particular relates to a thermosensitive CTP thermal imaging liquid containing active etherified compound of pyrogallol and divinylbenzene polycondensation resin as a resisting solvent. Background technique [0002] In the prior art, the Chinese patent application number CN 1490667 discloses a patent entitled "Thermosensitive Imaging Composition for Positive Thermal Computer-to-Plate Making", the patent 2,2-diphenyl-2-phenolic acid Derivatives are active ester ether compounds obtained by the addition reaction of intermediates of solvent-inhibiting and solubilizing compounds with vinyl ethers, dihydropyrans, etc., or lactone compounds containing active ethers. Solubility-inhibiting and solubilizing compounds with high solubility-resistance and high solubility-promoting properties after acidolysis, combined with novolac resins with acidolysis-solubility-...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/004
Inventor 沙栩正邹应全
Owner TAIXING CITY ORIENT IND
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