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Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof

An in-situ generation, calendering technology, applied in coating and other directions, can solve problems such as discomfort, high production cost, aging cracks in brighteners, etc.

Active Publication Date: 2012-04-18
JIHUA 3537 SHOE MAKING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the brightness of the rubber shoes produced by this method makes people feel unnatural and uncomfortable. At the same time, this production method has complicated processes, high production costs, and low product competitiveness. The product brightness is greatly affected by the quality of the liquid brightener. The aging crack of the brightener on the surface of the rubber part will be caused by the quality change of the brightener, which will affect the product image and the qualified rate of product production
Another method is to add a large dose of brightener to the rubber in the form of raw materials to increase the surface brightness of vulcanized rubber products. In this method, due to the high cost of the brightener, and the need to add a large dose to meet the brightness requirements, so Product cost is relatively high and competitiveness is low

Method used

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  • Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof
  • Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof
  • Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046]Embodiment 1 of the present invention: Calendering type in situ generates the formula of high-gloss shoe edge rubber, calculated in parts by weight, it includes 80 parts of natural rubber, 20 parts of styrene-butadiene rubber, 2.0 parts of sulfur, accelerator M 1.5 accelerator DM 1.8 0.7 parts of accelerator D, 2.0 parts of active zinc oxide, 1.5 parts of stearic acid, 0.9 parts of anti-aging agent CD, 0.9 parts of anti-aging agent KY-405L, 0.2 parts of salicylic acid, 11 parts of pine tar, RX-80 II 7 parts of toluene resin, 58 parts of light calcium carbonate, 72 parts of clay and 10.1 parts of color masterbatch.

[0047] Calendering-type in-situ production of high-gloss shoe edge rubber preparation method, according to the above-mentioned ratio of parts by weight, natural rubber, styrene-butadiene rubber and color masterbatch are mixed to obtain product A; Accelerator M, Accelerator DM, Accelerator Agent D, active zinc oxide, stearic acid, anti-aging agent CD, anti-agi...

Embodiment 2

[0048] Embodiment 2 of the present invention: Calendering type in situ generates the formula of high-gloss shoe edge rubber, calculated in parts by weight, it includes 100 parts of natural rubber, 1.7 parts of sulfur, 1.0 parts of accelerator M, 1.3 parts of accelerator DM, and 0.3 parts of accelerator D 2.5 parts of activated zinc oxide, 1.2 parts of stearic acid, 0.6 parts of anti-aging agent CD, 0.3 parts of anti-aging agent KY-405, 6 parts of pine tar, 4 parts of RX-80 xylene resin, 36 parts of light calcium carbonate, clay 44 parts and 9.5 parts of color masterbatch.

[0049] Calendering-type in-situ production of high-gloss shoe edge rubber preparation method, according to the above-mentioned ratio of parts by weight, natural rubber and color masterbatch are mixed to obtain product A; Accelerator M, Accelerator DM, Accelerator D, active Zinc oxide, stearic acid, anti-aging agent CD and anti-aging agent KY-405 are mixed to obtain product B; products A and B are put into a...

Embodiment 3

[0050] Embodiment 3 of the present invention: Calendering type in situ generates the formula of high-gloss shoe edge rubber, calculated in parts by weight, it includes 75 parts of natural rubber, 25 parts of styrene-butadiene rubber, 2.5 parts of sulfur, accelerator M 2.0 accelerator DM 2.5 1.0 parts of accelerator D, 2.8 parts of active zinc oxide, 2.2 parts of stearic acid, 1.2 parts of anti-aging agent CD, 1.3 parts of anti-aging agent KY-405, 0.3 parts of salicylic acid, 16 parts of pine tar, RX-80 xylene 10 parts of resin, 70 parts of light calcium carbonate, 90 parts of clay and 11 parts of color masterbatch.

[0051] Calendering-type in-situ production of high-gloss shoe edge rubber preparation method, according to the above-mentioned ratio of parts by weight, natural rubber, styrene-butadiene rubber and color masterbatch are mixed to obtain product A; Accelerator M, Accelerator DM, Accelerator Agent D, active zinc oxide, stearic acid, anti-aging agent CD, anti-aging ag...

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Abstract

The invention discloses a formula for in situ preparing rolled high brightness shoe side rubber and a preparation method thereof. By parts by weight, the formula comprises 75-100 parts of natural rubber, 0-25 parts of synthetic rubber, 1.7-2.5 part of vulcanizer, 2.6-5.5 parts of vulcanization accelerator, 3.0-5.0 parts of vulcanization activating agent, 10-26 parts of softening system, 80-160 parts of reinforcing rubber and 9.5-11.0 parts of colour masterbatch. The product prepared by the invention is high brightness rubber prepared by high temperature vulcanization. The method utilizes molecular action of compounding agent instead of special brightener, in situ preparing is adopted to prepare high brightness rubber, and the method has the characteristics of simple operation, safe process and low production cost. The obtained product has good properties, thus fully meeting the requirement of consumer.

Description

technical field [0001] The invention relates to a rubber processing technology, in particular to a formula and a preparation method for calendering in-situ high-gloss shoe edge rubber. Background technique [0002] The shiny rubber parts of rubber shoes products is a demand trend. The higher the brightness of the rubber parts of shoes, the more they are favored by consumers. Among the rubber shoes products with the same internal performance, the higher the brightness of the rubber material, it represents the product quality. higher. Under normal circumstances, the brightness of the outsole of rubber shoes of model products can meet the high brightness requirements by polishing the pattern surface of the mould. However, rubber shoes produced by calendering process have a semi-bright or dull appearance of the rubber parts, which gives people a rigid and dull appearance. obsolete. In order to obtain higher brightness, one method is to apply a layer of liquid brightener on the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L7/00C08L9/06C08K13/02B29C41/24B29C41/52B29C35/04
Inventor 晋齐怀陈松雄周川泉杜江田杰王永生王春桥彭德彪
Owner JIHUA 3537 SHOE MAKING