Photocuring resin for investment casting in laser fast molding

A technology of laser rapid prototyping and investment casting, applied in casting and molding equipment, etc., can solve the problems of ceramic shell bursting, high residual carbon content, high thermal decomposition temperature, and achieve uniform gas generation, low residual carbon content and viscosity. low effect

Active Publication Date: 2011-01-26
湖南西交智造科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Referring to these requirements, a resin formula specially used for investment casting was prepared, in which bisphenol A epoxy resin is the most important component in the resin system, which affects the mechanical properties of the entire resin, but its benzene ring structure leads to During the corrosion process, the thermal decomposition temperature is high and the amount of residual carbon is high. Therefore, using it as the main resin cannot solve the defects of the ceramic shell bursting in the high temperature stage.
During the ablation process, the thermal expansion coefficients of the resin and ceramics differ by an order of magnitude, and if the thermal weight loss occurs in a narrow temperature range, a large amount of gas is generated at this time, which can easily cause the ceramic shell to burst.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] A photocurable resin for investment casting in laser rapid prototyping, comprising 52% by mass of unsaturated polyester, 23% by mass of epoxy resin, 21% by mass of active diluent, and The percentage content is 4% photoinitiator, the unsaturated polyester is a mixture of aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester acrylate, aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester The mass ratio of acrylate is 1:1; the epoxy resin is 3,4-epoxycyclohexyl-3',4'-epoxycyclohexyl carboxylate (UVR-6105); the reactive diluent is trimethylol Propane triacrylate; the photoinitiator is composed of free radical photoinitiator and cationic photoinitiator mixed, the mass ratio of free radical photoinitiator and cationic photoinitiator is 3:2, and the free radical photoinitiator is benzoin dimethyl ether (commercial name 651), the cationic photoinitiator is triaryl hexafluoroantimonate sulfonium salt (commercial name TPS-SbF 6 ).

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Embodiment 2

[0014] A photocurable resin for investment casting in laser rapid prototyping, comprising 40% by mass of unsaturated polyester, 35% by mass of epoxy resin, 21% by mass of active diluent, and The percentage content is 4% photoinitiator, the unsaturated polyester is a mixture of aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester acrylate, aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester The mass ratio of acrylate is 3:1; the epoxy resin is 3,4-epoxycyclohexyl-3',4'-epoxycyclohexyl carboxylate (UVR-6105) and bis-(3,4-cyclo Oxycyclohexyl) adipate (UVR-6128), the mass ratio of the two is 6: 1; the active diluent is pentaerythritol penta(hexa) acrylate; the photoinitiator is composed of free radical photoinitiator and cationic photoinitiator Mixed composition, the mass ratio of free radical photoinitiator and cationic photoinitiator is 2: 3, free radical photoinitiator is 2-hydroxyl-2-methyl-1-phenylacetone (commercial name is 1173...

Embodiment 3

[0018] A photocurable resin for investment casting in laser rapid prototyping, comprising 35% by mass of unsaturated polyester, 33% by mass of epoxy resin, 28% by mass of active diluent, and The percentage content is 4% photoinitiator, the unsaturated polyester is a mixture of aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester acrylate, aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester The mass ratio of acrylate is 2:1; the epoxy resin is 3,4-epoxycyclohexyl-3',4'-epoxycyclohexyl carboxylate (UVR-6105) and bis-(3,4-cyclo Oxycyclohexyl) adipate (UVR-6128), the mass ratio of the two is 2:1; the reactive diluent is 1,6-hexanediol diacrylate and trimethylolpropane triacrylate, the two The mass ratio of the photoinitiator is 2:5; the photoinitiator is composed of a free radical photoinitiator and a cationic photoinitiator, the mass ratio of the free radical photoinitiator and the cationic photoinitiator is 3:2, and the free radical...

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PUM

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Abstract

The invention discloses a photocuring resin for investment casting in laser fast molding. The resin comprises the following materials in percentage by mass: 30 to 55 percent of unsaturated polyester, 20 to 35 percent of epoxy resin, 20 to 40 percent of active diluent and 1 to 6 percent of light initiator. A preparation process for the resin comprises the following steps of: adding the light initiator into the active diluent, dissolving in a water bath of 40 to 60 DEG C until the light initiator is transparent, adding the unsaturated polyester and the epoxy resin, and stirring and mixing for 1 to 2 hours. The resin has low viscosity, a mold shell does not crack during roasting, the thermogravimetric curve is flat in a roasting process, the gas evolution is uniform and the carbon residue is low.

Description

technical field [0001] The invention relates to the technical field of photocurable resins, in particular to a photocurable resin for investment casting in laser rapid prototyping. technical background [0002] Since the rise of laser rapid prototyping technology in the 1980s, light-curing resins suitable for different fields have been developed at home and abroad. For investment casting, to be suitable for its molding process, the resin must be slowly ablated during the ablation process. The gas output is stable and the carbon residue is low. Referring to these requirements, a resin formula specially used for investment casting was prepared, in which bisphenol A epoxy resin is the most important component in the resin system, which affects the mechanical properties of the entire resin, but its benzene ring structure leads to In the corrosion process, the thermal decomposition temperature is high and the carbon residue is high. Therefore, using it as the main resin cannot s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/08C08F283/01C08K5/1515B22C7/02
Inventor 段玉岗李涤尘康小青张莹莹
Owner 湖南西交智造科技有限公司
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