Photocuring resin for investment casting in laser fast molding
A technology of laser rapid prototyping and investment casting, which is applied in the direction of casting molding equipment, etc. It can solve the problems of ceramic mold shell cracking, high residual carbon content, high thermal decomposition temperature, etc., and achieve uniform gas generation, low carbon residual content and high viscosity. low effect
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Embodiment 1
[0010] A photocurable resin for investment casting in laser rapid prototyping, comprising 52% by mass of unsaturated polyester, 23% by mass of epoxy resin, 21% by mass of active diluent, and The percentage content is 4% photoinitiator, the unsaturated polyester is a mixture of aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester acrylate, aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester The mass ratio of acrylate is 1:1; the epoxy resin is 3,4-epoxycyclohexyl-3',4'-epoxycyclohexyl carboxylate (UVR-6105); the reactive diluent is trimethylol Propane triacrylate; the photoinitiator is composed of free radical photoinitiator and cationic photoinitiator mixed, the mass ratio of free radical photoinitiator and cationic photoinitiator is 3:2, and the free radical photoinitiator is benzoin dimethyl ether (commercial name 651), the cationic photoinitiator is triaryl hexafluoroantimonate sulfonium salt (commercial name TPS-SbF 6 ).
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Embodiment 2
[0014] A photocurable resin for investment casting in laser rapid prototyping, comprising 40% by mass of unsaturated polyester, 35% by mass of epoxy resin, 21% by mass of active diluent, and The percentage content is 4% photoinitiator, the unsaturated polyester is a mixture of aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester acrylate, aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester The mass ratio of acrylate is 3:1; the epoxy resin is 3,4-epoxycyclohexyl-3',4'-epoxycyclohexyl carboxylate (UVR-6105) and bis-(3,4-cyclo Oxycyclohexyl) adipate (UVR-6128), the mass ratio of the two is 6: 1; the active diluent is pentaerythritol penta(hexa) acrylate; the photoinitiator is composed of free radical photoinitiator and cationic photoinitiator Mixed composition, the mass ratio of free radical photoinitiator and cationic photoinitiator is 2: 3, free radical photoinitiator is 2-hydroxyl-2-methyl-1-phenylacetone (commercial name is 1173...
Embodiment 3
[0018] A photocurable resin for investment casting in laser rapid prototyping, comprising 35% by mass of unsaturated polyester, 33% by mass of epoxy resin, 28% by mass of active diluent, and The percentage content is 4% photoinitiator, the unsaturated polyester is a mixture of aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester acrylate, aromatic chlorinated polyester acrylate and aliphatic chlorinated polyester The mass ratio of acrylate is 2:1; the epoxy resin is 3,4-epoxycyclohexyl-3',4'-epoxycyclohexyl carboxylate (UVR-6105) and bis-(3,4-cyclo Oxycyclohexyl) adipate (UVR-6128), the mass ratio of the two is 2:1; the reactive diluent is 1,6-hexanediol diacrylate and trimethylolpropane triacrylate, the two The mass ratio of the photoinitiator is 2:5; the photoinitiator is composed of a free radical photoinitiator and a cationic photoinitiator, the mass ratio of the free radical photoinitiator and the cationic photoinitiator is 3:2, and the free radical...
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