Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Foaming agent for highly mineralized water containing barium-strontium ions and gas condensate and preparation method thereof

A technology with high salinity and strontium ions, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of foaming agents such as poor anti-condensate oil, clogging, and precipitation, and achieve excellent foaming performance and the effect of liquid-carrying capacity

Inactive Publication Date: 2011-04-27
SUINING HUANING CHEM
View PDF3 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the foam drainage gas recovery process is mostly used in the production of water-filled gas reservoirs in China. Although these foaming agents have achieved certain results in field application, they have the following shortcomings: (1) Due to the current impact of these foaming agents on barium-strontium-containing The medium with high salinity of ions is not highly targeted, and the foaming agent and barium and strontium ions form insoluble precipitates, which cause fouling or blockage of the tubing
(2) The foaming agent has poor ability to resist condensate oil, and oil-water emulsification occurs with condensate oil. On the one hand, the performance of the foaming agent is reduced, and the emulsion may block the oil pipe

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Foaming agent for highly mineralized water containing barium-strontium ions and gas condensate and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The formula is: 500kg zwitterionic surfactant; 200kg nonionic surfactant; 100kg barium strontium ion inhibitor; 50kg pH regulator; 150kg solvent. Wherein, zwitterionic surfactant refers to alkyl amidopropyl betaine, and general chemical formula is: R 1 CONH(CH 2 ) 3 N + (CH 3 ) 2 CH 2 COONa, where R 1 It is an alkyl group containing 12-14 carbons. Nonionic surfactants are alkylphenol polyoxyethylene ethers whose general chemical formula is R 2 C 6 h 4 O(CH 2 CH 2 O)nH, wherein, R 2 It is an alkyl group containing 9-12 carbons, n=4-6. The barium strontium ion inhibitor refers to polyaspartic acid. The pH adjuster refers to triethanolamine. The solvent is soft water.

[0033] The preparation process is as follows: according to the formula ratio, add 500kg of zwitterionic surfactant and 200kg of nonionic surfactant into a stainless steel reaction kettle, heat to about 50°C, stir for 20min to 25min, then add 150kg of solvent, stir for 20min to 30min, and fin...

Embodiment 2

[0035] The formula is: 400kg zwitterionic surfactant; 100kg nonionic surfactant; 50kg barium strontium ion inhibitor; 30kg pH regulator; 420kg solvent. Wherein, zwitterionic surfactant refers to alkyl amidopropyl betaine, and general chemical formula is: R 1 CONH(CH 2 ) 3 N + (CH 3 ) 2 CH 2 COONa, where R 1 It is an alkyl group containing 12-14 carbons. Nonionic surfactants are alkylphenol polyoxyethylene ethers whose general chemical formula is R 2 C 6 h 4 O(CH 2 CH 2 O)nH, wherein, R 2 It is an alkyl group containing 9-12 carbons, n=4-6. The barium strontium ion inhibitor refers to polyaspartic acid. The pH adjuster refers to triethanolamine. The solvent is soft water.

[0036]The preparation process is as follows: according to the formula ratio, add 400kg of zwitterionic surfactant and 100kg of nonionic surfactant into a stainless steel reaction kettle, heat to about 60°C, stir for 20min-25min, then add 420kg of solvent, stir for 20min-30min, and finally Ad...

Embodiment 3

[0038] The formula is: 450kg zwitterionic surfactant; 150kg nonionic surfactant; 70kg barium strontium ion inhibitor; 40kg pH regulator; 290kg solvent. Wherein, zwitterionic surfactant refers to alkyl amidopropyl betaine, and general chemical formula is: R 1 CONH(CH 2 ) 3 N + (CH 3 ) 2 CH 2 COONa, where R 1 It is an alkyl group containing 12-14 carbons. Nonionic surfactants are alkylphenol polyoxyethylene ethers whose general chemical formula is R 2 C 6 h 4 O(CH 2 CH 2 O)nH, wherein, R 2 It is an alkyl group containing 9-12 carbons, n=4-6. The barium strontium ion inhibitor refers to polyaspartic acid. The pH adjuster refers to triethanolamine. The solvent is soft water.

[0039] The preparation process is as follows: according to the formula ratio, add 450kg of zwitterionic surfactant and 150kg of nonionic surfactant into a stainless steel reaction kettle, heat to about 55°C, stir for 20min to 25min, then add 290kg of solvent, stir for 20min to 30min, and fina...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a foaming agent for highly mineralized water containing barium-strontium ions and gas condensate and a preparation method thereof. The foaming agent contains the following components in mass percentage: 40%-50% of amphoteric surfactants, 10%-20% of nonionic surfactants, 5%-10% of barium-strontium ion inhibitors, 3%-5% of pH regulators and 15%-42% of solvents. The preparation method comprises the following steps of: A, adding the amphoteric surfactants and the nonionic surfactants into a stainless steel reactor by the proportions in a formula, heating to 50-60 DEG C, and then stirring for 20 min-50 min; B, adding the solvents and stirring for 20 min-30 min; and C, finally adding the barium-strontium ion inhibitors and the pH regulators, and continuously stirring for20 min-30 min. The foaming agent can have good foaming performance and liquid-carrying capacity in a formation water medium which contains 1000 mg / L-3000 mg / L of barium-strontium ions and has the gascondensate of not more than 30% and the total mineralization degree of not more than 250 g / L. In experiments, when the addition amount of the foaming agent is 3 g / L, the foaming height is greater than 150 mm, and the liquid-carrying amount is greater than 150 ml / 15 min.

Description

technical field [0001] The invention relates to the technical field of natural gas well exploitation, in particular to a foaming agent for high salinity water containing barium and strontium ions and condensate oil and a preparation method thereof. technical background [0002] During the production of gas reservoirs with water, with the production of natural gas, formation water with high salinity and condensate oil containing various ions continuously enters the wellbore along with the natural gas. If the gas has enough energy, it can absorb the The liquid is brought to the surface, and there is no effusion at the bottom of the well. In the middle and late stage of natural gas exploitation, the formation water is becoming more and more serious, and the formation energy is also seriously insufficient, so the gas cannot completely bring water and condensate oil to the ground. If it is not discharged in time, the gas well will be flooded due to the deposition in the downhole...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09K8/584C09K8/588
Inventor 向伟李礼侯裕民
Owner SUINING HUANING CHEM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products