Self-hardening sand bonding agent for casting and preparation method and using method thereof

A binder and self-hardening sand technology, used in casting equipment, molds, manufacturing tools, etc., can solve problems such as the inability to meet the requirements of large-scale steel castings, the long time required for final strength, and the inability of the mold to solidify as a whole. , to achieve the effects of easy control of process conditions, fast gas generation, and stable core/shape dimensions

Active Publication Date: 2013-01-16
NINGXIA UNIVERSITY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, the binder system has problems such as short usable time, inability to solidify the mold as a whole, and a long time to reach the final strength. It can only be used for small and medium-sized steel casting sand molds, and cannot meet the use requirements of large steel castings. Moreover, during the production process, the existing adhesives will release defects such as toxic gases that are harmful to the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0017] Preparation of resin:

[0018] Alcoholysis of castor oil: In a reactor with a stirrer, add 100 parts of castor oil and 60 parts of glycerin, heat up while stirring and feed N 2 for protection. .

[0019] Synthesis of resin: When the amount of separated water reaches 5 parts, stop heating. When the temperature in the kettle drops to 140°C, add 160 parts of high-boiling point aromatic hydrocarbons, and continue stirring to room temperature to obtain alkyd resin.

[0020] Preparation of curing agent: Add 100 parts of xylene diisocyanate to 25 parts of high-boiling point aromatic hydrocarbons, and mix homogeneously to obtain the curing agent.

[0021] The raw material purity of above-mentioned composition resin and curing agent all adopts industrial grade.

[0022] Use of the binder of the present invention: Add 1 part of the above-mentioned resin to 100 parts of foundry sand, stir in a sand mixer for one minute to make it evenly mixed, and add 0.8 parts to the mixed res...

Embodiment 2-7

[0024] The preparation method and conditions of resin and curing agent are the same as in Example 1. The ratio of each component is shown in the table below: Data results of Example 2: The usable time is 120 minutes, the demoulding time is 7 hours, the whole is cured, and the final strength is 1.88MPa.

Embodiment 3

[0025] Data results of Example 3: The usable time is 150 minutes, the demoulding time is 8 hours, the whole is cured, and the final strength is 1.82 MPa.

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PUM

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Abstract

The invention relates to a bonding agent for casting, in particular to a self-hardening sand bonding agent for casting and a preparation method and a using method thereof. The self-hardening sand bonding agent for the casting comprises resin and a curing agent, wherein the resin consists of the following components in part by weight: 100 parts of castor oil, 40 to 90 parts of glycerol, 0.1 to 0.2part of calcium oxide, 50 to 90 parts of phthalic anhydride, 5 to 9 parts of dimethylbenzene, 120 to 200 parts of high-boiling point arylhydrocarbon; and the curing agent is prepared by mixing 100 weight parts of isocyanate and 20 to 40 weight parts of high-boiling point arylhydrocarbon. The bonding agent has readily available raw materials and is environment-friendly, equipment required by a synthetic process is simple, and a process condition is easy to control; the bonding agent has high sand mulling flowability, low gas forming amount, high gas forming speed, stable sizes of sand cores / sand molds and smooth surfaces, is convenient to store, and has the excellent effects of resisting sand burning and deformation; and the sand molds are hardened integrally and uniformly, castings have high size accuracy, and sand can be recycled, so the bonding agent is suitable for the production of large-scale steel-casting sand molds.

Description

technical field [0001] The present invention relates to a kind of foundry binder, especially relates to foundry self-setting sand binder and its preparation and use method. Background technique [0002] One of the main methods of the foundry industry for the preparation of metal parts is sand casting, in which disposable patterns are made by mixing, shaping and curing sand with an inorganic or organic binder, which is Used to reinforce molds and cores. The two main methods used to prepare molds and cores are (1) the cold box core method and (2) the no-bake method. Most cold box coremaking methods are based on polyurethane forming binders. See eg US 3,409,579 and 3,676,392. These systems are cured with gaseous quaternary amine catalysts. The polyurethane forming binder system typically consists of a phenolic resin component and a polyisocyanate component which are mixed with sand and cured to form a cured mix prior to compaction. The component phenolic resin in the binde...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22C1/22C08G18/68
Inventor 周惠良胡奇林
Owner NINGXIA UNIVERSITY
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