Toughening color master batch for high impact polystyrene, composite board and liner of refrigeration equipment

A polystyrene, high-impact technology, applied in the field of high-impact polystyrene toughening color masterbatch, high-impact polystyrene composite plate, refrigeration equipment liner, can solve the problem of increasing the thickness of the plate and increasing the cost , liner cracking and other problems, to achieve the effect of reducing the amount of materials, reducing the thickness of the plate, and solving the problem of cracking

Inactive Publication Date: 2011-08-17
HEFEI MIDEA REFRIGERATOR CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the cost of the ABS liner is relatively high, and the ordinary ABS liner is not resistant to hydrogenated fluoroalkane (HFC) foaming agents (for example, HFC-365mffc, HFC-245fa, HFC-134a, HFC-227ea, HFC-236fa, HFC- 152a, HFC-125, etc.) or the mixed foaming system containing HFC foaming agent is corroded, which is easy to cause defects such as cracking, and there is a high quality risk
On the other hand, ordinary HIPS extruded board grade materials, although the resistance to the above-mentioned foaming agents has been improved, there is still a certain degree of risk of inner liner cracking
In addition, HIPS extruded board materials are usually composed of HIPS natural color materials, masterbatches, and recycled materials. Due to the influence of a large amount of fillers in recycled materials and color masterbatches, the mechanical properties of the board, such as impact strength and elongation at break, are reduced, so the risk of cracking is relatively high.
In order to reduce the risk of cracking, the thickness of the sheet needs to be increased, and the proportion of recycled material needs to be properly controlled, which will lead to an increase in cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] 1) Preparation of HIPS Toughened White Masterbatch I

[0031] composition

[0032] SBS-1301 (produced by Yueyang Baling Jiayun Petrochemical Co., Ltd.) 38 parts by weight

[0033] HIPS 2710 (produced by Yangzi Baqifu) 20 parts by weight

[0034] White naphthenic oil KG16C (Xinjiang Karamay Refinery) 20 parts by weight

[0035] Titanium dioxide (R type) 18 parts by weight

[0036] Antioxidant (1010:DLTP=1:2) 1.5 parts by weight

[0037] Coupling agent (titanates) 1.0 parts by weight

[0038] 1.5 parts by weight of lubricant (stearate)

[0039] According to the formula requirements, first weigh the SBS material and add it to the mixer. Then weigh the white naphthenic oil, add it into the blender while stirring, and mix with SBS evenly. Finally, add the weighed other materials into the mixer and mix them evenly. Thereafter, use a co-rotating twin-screw extruder to granulate, and cut into pellets in the form of water-cooled strands to obtain toughened white masterba...

Embodiment 2

[0044] 1) Preparation of toughening masterbatch

[0045] composition

[0046] SBS1401 60 parts by weight

[0047]White naphthenic oil KN4010 30 parts by weight

[0048] 10 parts by weight of white oil

[0049] Weigh the SBS according to the formula and add it to the mixer, then weigh the naphthenic oil and white oil, add them to the SBS while stirring and mix evenly, wait for the liquid materials such as naphthenic oil and white oil to be fully absorbed by the SBS, then use the same Pellet to the twin-screw extruder, grind the surface and hot-cut the pellets to obtain the toughened masterbatch.

[0050] 2) Preparation of toughened white masterbatch II for HIPS

[0051] composition

[0052] Toughening masterbatch 50 parts by weight

[0053] HIPS 2710 (produced by Yangzi Baqifu) 25 parts by weight

[0054] Titanium dioxide (R type) 19 parts by weight

[0055] White naphthenic oil KG16C 1 part by weight

[0056] Antioxidant (1010:DLTP=1:2) 1.5 parts by weight

[0057] C...

Embodiment 3

[0064] 1) Toughened black masterbatch III for HIPS

[0065] composition

[0066] SBS1401 40 parts by weight

[0067] HIPS2710 (Yangzi Baqifu) 20 parts by weight

[0068] 20 parts by weight of dark naphthenic oil

[0069] Carbon black 15 parts by weight

[0070] Antioxidant (1010:DLTP=1:2) 1.5 parts by weight

[0071] Coupling agent (titanates) 1.0 parts by weight

[0072] 2.5 parts by weight of lubricant (stearate)

[0073] The above composition was prepared in the same manner as in Example 1 to obtain toughened black masterbatch III for HIPS.

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PUM

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Abstract

The invention discloses a toughening color master batch for high impact polystyrene, a composite board and a liner of refrigeration equipment. The toughening color master batch for the high impact polystyrene comprises the following components in part by weight: 25 to 85 parts of toughening agent, 10 to 50 parts of softener, 10 to 50 parts of base material and 5 to 35 parts of toner. According to the toughening color master batch for the high impact polystyrene, a carrier in a conventional color batch is replaced by the toughening agent, so that the toughening color master batch has the effect of toughening the high impact polystyrene in the process of dying the high impact polystyrene. According to the high impact polystyrene composite board, the strength is obviously improved, so that the thickness of the board can be reduced and the using amount of materials can be reduced; return material proportion in an extruded board material can be obviously improved, even the composite board can totally adopt a return material; by controlling the addition ratio of the toughening color master batch, the performance of the board can be regulated so as to meet different requirements; due to low density of the toughening color master batch, the weight of the liner formed by the composite board with the same size can be reduced.

Description

technical field [0001] The invention relates to the field of refrigeration equipment manufacturing, in particular to a toughened color masterbatch for high-impact polystyrene, a high-impact polystyrene composite plate, and a refrigeration equipment inner vessel for preparing the inner vessel of the refrigeration equipment. Background technique [0002] The main materials for refrigerator liners are acrylonitrile-styrene-butadiene copolymer (ABS) and high-impact polystyrene (HIPS). Among them, the cost of the ABS liner is relatively high, and the ordinary ABS liner is not resistant to hydrogenated fluoroalkane (HFC) foaming agents (for example, HFC-365mffc, HFC-245fa, HFC-134a, HFC-227ea, HFC-236fa, HFC- 152a, HFC-125, etc.) or the mixed foaming system containing HFC foaming agent is corroded, which is easy to cause defects such as cracking, and there is a high quality risk. On the other hand, ordinary HIPS extruded board grade materials have improved resistance to the above...

Claims

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Application Information

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IPC IPC(8): C08L51/00C08L53/02C08K5/01C08K3/22C08K3/04F25D23/08
Inventor 曹家汉项灵芝任媛媛王海超文坚隋银国江敏张世国
Owner HEFEI MIDEA REFRIGERATOR CO LTD
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