Method for preparing thin-film positive electrode for thermal batteries

A thin-film positive electrode and thermal battery technology, applied to the electrodes of primary batteries, etc., can solve the problems of difficult control of mixing uniformity, cumbersome preparation process, and low productivity of thermal batteries, so as to achieve great military and industrial application value, simplify the preparation process, The effect of improving stability

Inactive Publication Date: 2012-02-01
SHENYANG LIGONG UNIV
View PDF2 Cites 49 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the production of thermal batteries is generally labor-intensive, and the electrodes are prepared by powder pressing process. In this process, the positive electrode sheet, electrolyte diaphragm, and negative electrode sheet of each thermal battery cell need to be powder pressed three times, and finally stacked and pressed into a single cell. At the same time, due to the small batch demand for each type of thermal battery, the feasibility of automatic transformation of the powder tablet preparation process is very low, which will inevitably lead to low productivity of thermal batteries, and it is difficult to meet the needs of the development of modern advanced weapons
[0006] There are many shortcomings in the current powder tableting preparation process: 1. The preparation process is cumbersome, the personnel are redundant, and the production cost remains high; 2. It is difficult to press large...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing thin-film positive electrode for thermal batteries
  • Method for preparing thin-film positive electrode for thermal batteries
  • Method for preparing thin-film positive electrode for thermal batteries

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] In the positive electrode active material FeS 2 Add 10% LiCl-KCl electrolyte (mass ratio LiCl:KCl=45:55) and 3% carbon nanotubes, mix evenly, add 10ml distilled water, continue stirring for 10min, adjust the viscosity of the mixture to make it a paste with a certain Viscosity, then use a 100-mesh screen printing machine to evenly distribute the paste mixture onto the surface of the porous conductive material, put the substrate covered with the active material into a vacuum drying oven and dry it in vacuum at 250°C for 4 hours to obtain a large-area thermal battery film positive electrode. Under the protection of a dry gas with a relative humidity of 1%, the positive electrode sheet was flat-pressed with an electrode tablet press at 20 MPa, and then punched with an electrode punching machine to obtain several positive electrode sheets with a thickness of 0.4 mm and a diameter of 17 mm.

[0024] Under the protection of dry gas with a relative humidity of 1%, the thermal ...

Embodiment 2

[0027] In the positive electrode active material NiS 2 Add 20% LiCl-KCl electrolyte (mass ratio LiCl:KCl=45:55) and 3% carbon nanotubes, mix evenly, add 3ml distilled water, continue stirring for 10min, adjust the viscosity of the mixture to make it a paste with a certain Viscosity, then use a 100-mesh screen printing machine to evenly distribute the paste mixture onto the surface of the porous conductive material, put the substrate covered with the active material into a vacuum drying oven and dry it in vacuum at 250°C for 4 hours to obtain a large-area thermal battery film positive electrode. Under the protection of a dry gas with a relative humidity of 1%, the positive electrode sheet was flat-pressed with an electrode tablet press at 20 MPa, and then punched with an electrode punching machine to obtain several positive electrode sheets with a thickness of 0.2 mm and a diameter of 17 mm.

[0028] Under the protection of a dry gas with a relative humidity of 1%, the thermal...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Diameteraaaaaaaaaa
Thicknessaaaaaaaaaa
Login to view more

Abstract

The invention discloses a method for preparing a thin-film positive electrode for thermal batteries and belongs to the technical field of thin-film electrodes for thermal batteries. The method comprises the following steps: uniformly mixing active substances for positive electrodes, an electrolyte and carbon nano tubes in a certain mass ratio; then, adding a certain amount of distilled water, and adjusting the viscosity of the obtained mixture, so that the mixture becomes a pasty mixture and has certain viscosity; and enabling the pasty mixture to be uniformly adsorbed to the surface of a substrate by using a screen process press, and putting the substrate coated with the active substances into a vacuum drying oven to carry out vacuum drying, then obtaining the thin-film positive electrode for the thermal batteries. The thin-film positive electrode disclosed by the invention has the advantages of overcoming multiple defects caused by the existing powder compressing preparation process for the thermal battery electrodes, easily realizing the preparation of large-area or irregularly-shaped electrode plates, simplifying the electrode preparation process, improving the productivity, reducing the cost, and improving the stability and discharge performance of the batteries, therefore, the thin-film positive electrode has greater military and industrial application values.

Description

[0001] technical field [0002] The invention belongs to the technical field of thermal battery film electrodes, and in particular relates to a preparation method of a porous conductive material or a flexible conductive material matrix thermal battery thin film battery positive electrode. The invention mainly aims at solving the problems of low labor rate, high cost and poor performance in the current thermal battery production, and provides a feasible technical solution for the automatic high-quality production of the thermal battery. Background technique [0003] Thermal battery is also called molten salt battery. It uses molten salt as electrolyte, and uses mechanical activation device or electric activation device to melt the electrolyte instantly and output current to the outside. It is composed of single battery, ignition element, heating element, stack, insulating sheet, insulation layer, shell and so on. The single battery is composed of electrode sheets, electroly...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): H01M4/08
CPCY02E60/12
Inventor 杨少华陈威宏孟锦宏曹晓晖
Owner SHENYANG LIGONG UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products