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Chromogenic formaldehyde adsorption material and method for preparing same

A formaldehyde adsorption and formaldehyde technology, applied in chemical instruments and methods, other chemical processes, etc., can solve the problems of secondary pollution, limited effect of removing formaldehyde, etc., and achieve the effect of simple production process, easy industrial production, and simple color change

Inactive Publication Date: 2012-07-04
邯郸派瑞电器有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent application number is 03104742.4, and the name is "adsorption and decomposition agent for indoor harmful gas formaldehyde". It discloses a formaldehyde adsorption and decomposition agent that uses methyl yellow, magenta, etc. as indicators to indicate the degree of formaldehyde reaction, but the patent is a liquid preparation. , directly sprayed indoors when used, the effect of removing formaldehyde is limited, and the oxides contained in the liquid will cause secondary pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Fully mix 200g of polyethylene polyamine and 8g of polyethylene glycol (400), then add 50mg of the mixture of MBTH and ferric salt, the mixing molar ratio of MBTH and ferric salt is 1:1.5, mix well, add Dilute 1L of deionized water to make a reaction solution, spray the liquid evenly on the surface of a 2m×2m coarse filter, and dry it at 80°C to make a color-developing formaldehyde adsorption filter, which can be used as an air purifier component.

Embodiment 2

[0024] Mix 50g of polyethylene glycol with 3g of polypropylene glycol, then add 20mg of MBTH and ferric salt mixture, the mixing molar ratio of MBTH and ferric salt is 1:20, mix well, add 200ml of deionized water to dilute Prepare a reaction solution. Take 200g of adsorption resin and impregnate it in the above mixed liquid, stir, and then vacuum-dry at 45°C to obtain a color-changing formaldehyde adsorption resin material. The saturated adsorption capacity of the resin to formaldehyde is 1.2mmol / g.

Embodiment 3

[0026] Fully mix 50g of polyaziridine and 3g of polypropylene glycol, then add 20mg of AHMT, mix evenly, add 200ml of deionized water to dilute to make a reaction solution. Take 100 g of pretreated acrylic staple fiber, spray the above mixed reaction solution on the surface of the fiber, and vacuum-dry at 65°C to obtain a color-changing formaldehyde adsorption fiber material. The saturated adsorption capacity of the fiber to formaldehyde is 0.7 mmol / g.

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PUM

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Abstract

The invention discloses a chromogenic formaldehyde adsorption material and a method for preparing the chromogenic formaldehyde adsorption material. The chromogenic formaldehyde adsorption material is prepared from a substrate, an active component for formaldehyde, an auxiliary agent and a chromogenic agent of formaldehyde; the mass ratio of the active component for formaldehyde to the auxiliary agent is 1:0.03 to 1:0.2; the use amount of the chromogenic agent for formaldehyde is 0.1-1 per mill of the mass of the mixture of the active component for formaldehyde and the auxiliary agent; the active component of formaldehyde is polyethyleneimine or polyethylene polyamine; the chromogenic agent of formaldehyde is a mixture of 3-methyl-2-benzothiazolinonehydrazone hydrochloride hydrate (MBTH) and a ferric iron salt or 4-amino-3-hydrazine-5-mercapto-1,2,4-triazole (AHMT); and the mixed molar ratio of MBTH to the ferric iron salt is 1:1-1:20. The chromogenic formaldehyde adsorbent cannot cause secondary pollution, is safe to use and easy to prepare, is environmental friendly, and can be produced industrially easily.

Description

technical field [0001] The invention relates to a color-developing formaldehyde adsorbing material and a preparation method thereof. The color-developing formaldehyde adsorbing material shows the reaction degree of formaldehyde through color change, and is suitable for controlling formaldehyde pollution in the air. Background technique [0002] With the development of the economy and the improvement of people's living standards, a large number of new houses have been built, and the interior decoration has become more and more exquisite. my country's "Indoor Air Quality Standards" stipulates that the maximum allowable concentration of formaldehyde in the living room is 0.10mg / m 3 , the vast majority of newly renovated homes have indoor formaldehyde concentrations that exceed the standard by several to ten times within 5-10 months after the completion of the renovation. Residents usually adopt relatively passive methods such as opening windows for ventilation or waiting for a ...

Claims

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Application Information

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IPC IPC(8): B01J20/22B01J20/30
Inventor 张琴陈兆文范海明路玮徐伟周钧
Owner 邯郸派瑞电器有限公司
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