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Low-odor scraping-resistant polypropylene material and preparation method thereof

A polypropylene material, scratch-resistant technology, applied in the field of polypropylene materials, can solve the problems of not being able to remove odor well, adding more fluorine-containing polymers, increasing production costs, etc., to achieve superior product performance and good product performance , reduce the effect of sporadic

Inactive Publication Date: 2012-07-04
浙江明江新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the odor of the modified polypropylene material is the result of the interaction of odors of various components; only by adding an adsorbent that absorbs a single odor to reduce the odor, the actual effect is limited, and the odor cannot be removed well; at the same time , the amount of fluoropolymer added is too much, which increases the production cost

Method used

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  • Low-odor scraping-resistant polypropylene material and preparation method thereof
  • Low-odor scraping-resistant polypropylene material and preparation method thereof
  • Low-odor scraping-resistant polypropylene material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0032] Prepare materials according to the following weight percentages:

[0033] Polypropylene resin: 67.5%; Nano silica: 3%; Ultrafine talc: 27%; Deodorant: 1%; Dispersed lubricant: 1%; Antioxidant: 0.3%; Hindered amine light stabilizer : 0.2%, wherein the nano-silicon dioxide is modified nano-silicon dioxide, which is obtained by surface treatment of nano-silicon dioxide with hexamethyldisilazane, and the modified nano-silicon dioxide The particle size of silicon is 16nm; the deodorant is organosilicon microporous zeolite, the dispersion lubricant is a mixture of polysiloxane and erucamide, and the molecular weight of the polysiloxane is greater than 1000, wherein polysiloxane The weight ratio of siloxane and erucamide is 1: 1; Above-mentioned antioxidant comprises main antioxidant and auxiliary antioxidant, and the weight ratio of main antioxidant and auxiliary antioxidant is 1: 2, The primary antioxidant is phenolic antioxidant 1010, the secondary antioxidant is phosphite...

Embodiment 2

[0038] Prepare materials according to the following weight percentages:

[0039] Polypropylene resin: 67.5%; Nano silica: 4%; Ultrafine talc: 26%; Deodorant: 1%; Dispersed lubricant: 1%; Antioxidant: 0.3%; Hindered amine light stabilizer : 0.2%, wherein the nano-silica is modified nano-silica, modified nano-silica adopts hexamethyldisilazane to surface treat nano-silica, modified nano-silica The particle size is 8nm; the deodorant is composed of organosilicon microporous zeolite and porous silica, wherein the weight ratio of organosilicon microporous zeolite to porous silica is 2:3, and the dispersion lubricant is poly A mixture of siloxane and stearic acid, the molecular weight of the polysiloxane is greater than 1000, wherein the weight ratio of polysiloxane to stearic acid is 2:1; the above-mentioned antioxidant includes the main antioxidant And auxiliary antioxidant, the weight ratio of main antioxidant and auxiliary antioxidant is 1: 2, and described main antioxidant is ...

Embodiment 3

[0044] Prepare materials according to the following weight percentages:

[0045] Polypropylene resin: 67.5%; Nano silica: 5%; Ultrafine talc: 25%; Deodorant: 1%; Dispersed lubricant: 1%; Antioxidant: 0.3%; Hindered amine light stabilizer : 0.2%, wherein the nano-silica is modified nano-silica, modified nano-silica adopts hexamethyldisilazane to surface treat nano-silica, modified nano-silica The particle size is 1nm; the deodorant is composed of organosilicon microporous zeolite and porous silica, wherein the weight ratio of organosilicon microporous zeolite to porous silica is 3:2, and the dispersion lubricant is poly A mixture of siloxane, erucamide and stearic acid, the molecular weight of the polysiloxane is greater than 1000, wherein the weight ratio of polysiloxane, erucamide and stearic acid is polysiloxane:mustard Acid amide: stearic acid is 2: 1: 1; Above-mentioned antioxidant comprises main antioxidant and auxiliary antioxidant, and the weight ratio of main antioxid...

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Abstract

The invention relates to a low-odor scraping-resistant polypropylene material and a preparation method of the low-odor scraping-resistant polypropylene material and belongs to the technical field of polypropylene materials. In order to solve the technical problems that the odor of the polypropylene material in the prior art is difficult to eliminate, the odor can be eliminated only through aiming at a certain single ingredient, the scraping resistance is poor, and the production cost is high when fluorine-containing polymers are adopted for production. The invention provides the low-odor scraping-resistant polypropylene material and also provides the preparation method of the polypropylene material, wherein the polypropylene material comprises acrylic resin, nanometer silicon dioxide, ultra-fine talcum powder, odor eliminating agents, disperse lubricating agents, antioxidants and hindered amine light stabilizers, the method comprises material mixing and squeezing granulation steps, and the low-odor scraping-resistant polypropylene material is obtained. The polypropylene material provided by the invention has the advantages of low odor and scraping resistance. The product obtained from the material has the advantage that the performance such as tensile strength, bending strength, cantilever beam notch impact strength and delta L is high. The method has the advantages that the process is simple, the operation is easy, raw materials are easy to obtain, and the industrial production is favorably realized.

Description

technical field [0001] The invention relates to a polypropylene material, in particular to a low-odor and scratch-resistant polypropylene material and a preparation method thereof, belonging to the technical field of polypropylene materials. Background technique [0002] At present, with the rapid development of the automobile industry, the lightweight, safety, comfort and environmental protection of automobiles have become the main development trend of the world automobile industry. On the other hand, due to the application of plastics and their composite materials in automobile materials more and more widely. In automotive plastic materials, especially because of its low density, high cost performance, excellent heat resistance, rigidity, chemical corrosion resistance, and easy processing and recycling, polypropylene has become the most popular among automotive plastics. It is used in the largest amount, has the fastest development speed and has varieties, and is favored ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/14C08K9/06C08K7/26C08K7/28C08K3/36C08K3/34B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/92B29C2948/92704B29C2948/92895
Inventor 陈留群韩琛金江彬陈静
Owner 浙江明江新材料科技股份有限公司
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