Phosphorescent heavy metal iridium complex, multicolor nano material with adjustable phosphorescent emission and preparation method thereof
A technology of iridium complexes and nano-materials, applied in the field of organic nano-phosphorescent materials, can solve the problem of luminous quantum efficiency decline, emission peak broadening and red shift, limit the practical application of organic solid-state materials, and it is difficult to control the long-term color balance of multi-color light-emitting devices, etc. question
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[0031] (1) Take 0.35mmol of 2,4-difluorophenylpyridine iridium dichloro bridge complex and 1.5mmol of 4-pyridinecarboxylic acid and place it in a three-necked flask, vacuumize it with a double-row tube, protect it with nitrogen, and add a volume ratio of 1 : 1 mixed solvent of dichloromethane and methanol 80mL, heated to reflux at 60°C for 2h, added 10mL of saturated methanol solution of sodium acetate, continued to reflux for 1h, stopped heating, waited for the reaction solution to cool to room temperature, added saturated NH 4 PF 6 10 mL of methanol solution, continue stirring for 0.5 h, spin the reaction solution, add 50 mL of 1M HCl, stir for 10 minutes and filter, wash the filter residue with water, then dissolve the filter residue in methanol, add 50 mL of saturated NH 4 PF 6 methanol solution, stirred for 2h, spin-dried, then dissolved in dichloromethane, filtered, the filtrate was spin-dried, separated and purified by column chromatography to obtain pure phosphorescen...
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